科科斯脊玄武岩斜长石矿物化学及地质意义

综合大洋钻探计划(IODP) 334和344航次在U1381站位处的两个钻孔(A孔和C孔)获得了中美洲西海岸外科科斯脊基底拉斑玄武岩，对其岩浆过程开展研究可为理解其岩石成因提供重要依据。本文对科科斯脊玄武岩中斜长石斑晶和微晶进行了详细的原位主微量元素分析，结果表明，斜长石种属为培长石、拉长石及少量中长石。部分斜长石斑晶具有正环带结构；但多数斜长石斑晶不具有明显环带，仅从核部到边部存在微弱的成分变化。斜长石斑晶与微晶的微量元素差别较大:斜长石斑晶富集轻稀土和大离子亲石元素、亏损高场强元素，且具有明显的Eu正异常；斜长石微晶不相容元素含量通常高于斜长石斑晶。根据斜长石温度计计算获得斜长石斑晶结晶温度为1 050～1 253℃，斜长石微晶结晶温度为866～1 033℃。基于以上特征，推测斜长石斑晶核部是相对原始岩浆的产物，而斑晶边部以及微晶是演化岩浆的结晶产物。斜长石斑晶的成分变化及熔蚀麻点结构是由于岩浆补给及岩浆减压上升造成的。最后，本研究推测科科斯脊基底玄武岩来自于开放的岩浆房，且岩浆房内可能存在原始岩浆的不断注入及岩浆对流。     

南大西洋洋中脊玄武岩中斜长石特征及其岩石学意义

本文利用电子探针技术分析了南大西洋洋中脊玄武岩中斜长石的结构构造和物质组成特征,讨论了该区岩浆过程在斜长石中的记录。按粒径大小可将研究区玄武岩中的斜长石分为斑晶、微晶和基质三类,斑晶斜长石核部平均An值为74,属于培长石,而边部平均An值为69,属于拉长石,呈正环带构造,微晶斜长石平均An值为67,与斑晶斜长石边部成分近似,且其粒径与斑晶斜长石边部宽度接近,约在30μm,极可能是同一时期形成。基质斜长石平均An值为63,略小于微晶斜长石。利用马西兹修改后的斜长石结晶温度计算公式,估算出斑晶斜长石核部结晶温度约为1 214℃,斑晶斜长石边部结晶温度约为1 085℃,微晶斜长石的结晶温度约为1 081℃,而基质斜长石的结晶温度约为1 056℃。由此推测,高An值(78~80)的斑晶斜长石的核部可能是形成于岩浆源区的捕掳晶。斑晶斜长石的边部、微晶斜长石及基质斜长石的结晶温度相近,说明三者可能近乎同时结晶;但由于它们的颗粒大小变化范围较大,很可能分别形成于岩浆房、岩浆通道及喷出洋壳表面后等环境中。与冲绳海槽玄武岩中斜长石比较,本区斜长石平均An值跨度以及结晶温度跨度均比冲绳海槽小,本区An值为74~63,结晶温度为1 214~1 056℃,而冲绳海槽An值为86~47,结晶温度为1 250~950℃。这表明相对于岩浆物理化学环境曾经历快速变化的弧后盆地来说,慢速洋中脊的岩浆活动的物理化学环境则相对稳定。     

马里亚纳海槽玄武岩中斜长石矿物化学及意义

玄武岩中的斜长石矿物记录了岩浆过程的重要信息,可为揭示岩浆活动规律提供重要线索。马里亚纳海槽玄武岩中斜长石矿物具有两种产出类型:斑晶和微晶。岩相学特征指示,斜长石斑晶常具有聚片双晶结构、环带结构,偶见熔蚀结构和冷凝边;斜长石微晶呈半定向或杂乱分布在火山玻璃中,其中空骸晶结构表明斜长石微晶石在淬冷的条件下迅速形成。海槽18°N附近不同玄武岩样品中环带斜长石斑晶环带数与其寄主岩石Mg#值呈负相关,指示了在马里亚纳海槽扩张中心轴部地堑很小范围内获得的玄武岩样品经历的岩浆滞留时间以及岩浆混合作用周期存在一定程度的差异。海槽18°N,17°N和15°30′N附近3个位置的斜长石斑晶边部及斜长石微晶的An值接近,表明这3个位置的岩浆活动具有相似的岩浆上涌喷发通道结构及海底淬冷环境。与冲绳海槽相比,马里亚纳海槽玄武岩具有更深的产出水深;同时,研究区斜长石微晶An值总体上略高于前两者,这可能反映了水深对斜长石微晶An值的影响。研究区斜长石斑晶的形成温度范围比冲绳海槽更窄,暗示与冲绳海槽(陆缘弧后盆地)相比,马里亚纳海槽(洋内弧后盆地)岩浆过程所经历的物理化学环境可能相对更稳定。此外,微晶斜长石结晶温度略高于冲绳海槽,反映出两个弧后扩张区域岩浆喷出淬冷结晶时的水深的差异。     

马努斯海盆东部裂谷岩浆演化过程——火山岩中斜长石斑晶的启示

岩浆岩中斜长石矿物的结构、成分特征记录了岩浆演化过程的重要信息。本文对马努斯海盆东部裂谷(East Rift, ER)火山岩中的斜长石斑晶进行了详细的矿物学研究,结果表明:在玄武质安山岩中,斜长石斑晶具正环带结构,核-幔部属高An值(斜长石中钙长石分子百分数)斜长石(An值大于80,最大为87),而边缘的An值骤降(最小为63);而在英安岩中,大多数斜长石斑晶的成分从核部到边部变化较小, An值逐渐缓慢降低,呈现正环带结构,少量为韵律环带。结合火山岩斑晶矿物形成的温压条件计算结果,ER地区岩浆演化过程为:地幔源区发生部分熔融产生玄武质岩浆(温度～1300℃);在岩浆活动早期,由于岩浆供应充足,岩浆上升过程中速度较快,仅发生很小程度的分离结晶,形成少量斑晶矿物,并以较高的速度、温度(～1 100℃)直接喷出海底后形成玄武岩-玄武质安山岩;至岩浆活动晚期,岩浆供应量减少,岩浆在岩浆房(3～10km)停留较长时间,岩浆温度已经明显下降(960～1 020℃),发生强烈的分离结晶作用,岩浆喷出海底形成酸性火山岩;而在整个岩浆演化过程中,未有明显的岩浆混合作用发生。     

西沙群岛东岛浮岩矿物地球化学特征及成因探讨

本文对采自西沙群岛东岛的2件浮岩样品进行了岩石学和矿物地球化学研究,研究表明,东岛浮岩样品属于中性火山岩,SiO_2含量在60%左右,化学组成相当于粗面岩,斑状结构,斑晶主要为斜长石、单斜辉石和少量橄榄石,基质为玻璃质。斜长石及辉石斑晶矿物具有中心熔蚀结构,斜长石形成温度为1030℃-1080℃;单斜辉石属均为普通辉石,斑晶Al_2O_3含量较低;橄榄石属于透铁橄榄石,橄榄石斑晶Fo值为55.40-60.53,从核部到边部各化学成分略有降低,且具有轻微的化学成分环带。从核部到边部Fo值略有降低。东岛浮岩岩浆是西沙地块受到拉张作用,中地壳物质减压熔融形成粗面质岩浆,并经历短暂的岩浆房冷凝时期,拉张减薄作用形成裂谷后,由于压力突然释放,粗面质岩浆沿裂谷快速上升在水下喷发形成浮岩。     

九州-帕劳脊南段基底玄武岩的单斜辉石矿物化学及成因意义

九州-帕劳脊是古伊豆-小笠原-马里亚纳弧的重要组成,对其上基底岩石开展矿物学和岩石学研究可为理解洋内岛弧演化早期的岩石成因和岩浆活动特点提供重要线索。本文对九州-帕劳脊南段基底玄武岩中的单斜辉石斑晶和微晶开展详细的岩相学和原位主微量元素分析,结果表明,单斜辉石斑晶与微晶整体上具有相似的化学组分,为普通辉石及透辉石等种属,且亏损轻稀土元素,Eu负异常不明显。多数单斜辉石斑晶具有环带结构,可划分为简单环带及韵律性环带两类;从辉石核部到边部,MgO、FeO、Al₂O₃、TiO₂含量与核部镁指数Mg#等呈现复杂的高低变化,指示了多期次的岩浆混合与补给事件。单斜辉石的结晶温度、压力分别为1 151～1 210℃和1.3×10⁸～4.2×10⁸ Pa。通过单斜辉石组分反演获得的母岩浆含水量为0.8%～2.3%(以湿质量计)。最后,我们提出,形成于典型的洋内岛弧背景下的九州-帕劳脊南段熔岩的母岩浆为亚碱性岛弧拉斑玄武质熔体,具有高温、中压、高氧逸度的特征,岩浆房深度较浅并存在多期次原始岩浆的...     

中太平洋海山玄武岩的岩石学特征与年代

玄武岩在中太平洋海山分布广泛, 且普遍存在风化蚀变现象.对测区内玄武岩样品的岩石学特征研究表明, 玄武岩具斑状结构, 基质以间粒结构为主.斑晶矿物为基性斜长石、单斜辉石和伊丁石化橄榄石.基质矿物为斜长石、辉石、橄榄石、铁矿物、磷灰石、玻璃及次生矿物等. 各海山玄武岩同属碱性玄武岩系列, 并为钾质类型玄武岩, 它们的形成基本上处于同一地质构造环境中.稀土元素分析结果为轻稀土富集型, 轻重稀土在岩石形成过程中发生了不同程度的分异作用.CM5海山玄武岩比其他海山年代相对较老（60 Ma）.     

西菲律宾海盆本哈姆隆起玄武岩岩浆作用条件

本哈姆隆起(Benham Rise)(形成时代为37～36 Ma)位于菲律宾海板块西侧的西菲律宾海盆内。此海底隆起靠近菲律宾海沟,水深2 000～3 000m,体积接近1×10~5 km~3,为一典型的海底高原。玄武岩样品中的橄榄石斑晶颗粒粒径为0.2～0.4mm,自形-半自形,部分橄榄石斑晶发生明显的伊丁石化,不具橄榄石捕虏晶所特有的环状裂隙和扭折结构;基质中的橄榄石微晶粒径为0.01～0.05mm。早期结晶出来的橄榄石斑晶被寄主岩浆携带向上运移到地表期间,与寄主岩浆相互作用有限,少数橄榄石颗粒出现弱的成分分带现象。利用橄榄石斑晶与寄主岩浆对本区域地幔潜在温度(Tp)进行了计算,结果显示本哈姆隆起之下的地幔潜在温度范围为1 660～1 683℃。与正常洋中脊之下的地幔潜在温度相比,本哈姆隆起高约185～230℃,表明本哈姆隆起之下的地幔可能存在热量异常。此外,本哈姆隆起玄武岩中斜长石斑晶的结晶温度平均为1 160℃,结合其具有较高的An值(100Ca/(Ca+Na),表明斜长石斑晶形成于快速上升的幔源岩浆中。本研究为本哈姆隆起为地幔柱成因的观点提供了证据。     

冲绳海槽碱性玄武岩浆的起源及演化

利用电子探针对冲绳海槽133站位玄武岩的斑晶矿物、基质以及斑晶矿物中关晶石包体和岩浆包裹体作了化学主成分分析,结果表明,该站位玄武岩属橄榄玄武岩,岩石中斑晶矿物由培长石、普通辉石、贵橄榄石和磁铁矿组成,尚见有少量外来的脉石英碎块,基质成分由拉长石微晶和玻璃组成。培长石和贵橄榄石中含有玻璃质岩浆包裹体和铬镁尖晶石或铬镁铁尖晶石包体。尖晶石的化学成分证明它是地幔部分熔融成因的。岩浆包裹体代表了一种原生的碱性橄榄玄武岩浆,其化学成分相当于橄榄辉长岩。该站位的玄武岩浆起源于上地幔尖晶二辉橄榄岩的部分熔融,并沿着“碱性橄榄玄武岩浆-粗面玄武岩浆-玄武质粗面岩浆-粗面岩浆”方向演化,每一阶段的岩浆在上升过程中都不同程度地受到地壳物质的同化和混染作用。     

冲绳海槽西南部火山岩熔体包裹体的均一温度及对岩浆混合的指示意义

冲绳海槽西南部流纹岩和安山岩斜长石中发育大量玻璃质熔体包裹体,安山岩斜长石中熔体包裹体的均一温度较高（1050-1200℃）,而流纹岩斜长石中熔体包裹体有两个明显不同的均一温度峰值段（900-1000℃,1150-1200℃）,呈“双峰”式均一温度特征。熔体包裹体的均一温度特征与流纹岩和安山岩中斜长石的环带结构及An值变化特征一致,说明安山岩中斜长石主要在高温阶段结晶,而流纹岩中斜长石经历了两个不同的结晶阶段。结合流纹岩斜长石存在明显的环带结构及两种差异较大的An值特征,作者认为熔体包裹体的“双峰”式均一温度特征指示该地区发生了不同期次岩浆的混合作用。岩浆携带早期高温阶段结晶（1150-1200℃）的高An值偏基性斜长石向上运移,注入浅部较低温酸性岩浆房（900-1000℃）,发生混合作用,偏基性的斜长石在进入酸性岩浆房后被重新吸收,形成包含有较高均一温度熔体包裹体的核部（高An）,然后继续结晶生长形成包含有较低均一温度熔体包裹体的边部（低An）,表明冲绳海槽西南部地区下部岩浆房内存在复杂的岩浆混合作用。     

冲绳海槽浮岩包裹体的测温试验

对浮岩中斜长石斑晶中的包裹体及玻璃基质中的包裹体首先进行双面光薄片的镜下观察，然后进行了系统的均化法与爆裂法测温试验。观察与试验结果表明：(1)斜长石中的包裹体均为玻璃质+气泡的两相包裹体，未发现气—液包裹体。固化包裹体为玻璃质，非晶质的固化包裹体外即是大量的气泡，特别是基质当中气泡更为发育，说明熔浆中含有丰富的挥发性组分，同时也说明包裹体形成于较浅的地质条件下。(2)长石中包裹体的均化温度不受包裹体特征不同的影响，均化温度分布范围从910—1250℃，峰值明显，计算的均化温度为Tz=(1081.4±177.9)℃，但还存在有高于1250℃的均化温度峰。包裹体均化法测试结果说明浮岩中斜长石的形成过程至少有两个阶段：第一阶段的岩浆温度在1200—1300℃左右，在此温度下形成的是An值较高的基性斜长石，同时结晶的还有辉石等矿物，斜长石结晶第二个阶段时的熔浆温度在1100℃以下，这一阶段持续的时间长，跨越的温度范围大，应是岩浆在近地表和岩浆喷出过程中的岩浆快速冷却期，同时伴随有矿物大规模晶出。(3)包裹体中的气相部分均聚合成圆形或近圆形，说明温度下降速度较快。斑晶斜长石中部分包裹体与基质玻璃中包裹体的形成温度是连续变化的，这一事实应该与冲绳海槽特殊的地质条件有关     

Mineral chemistry of Carlsberg Ridge basalts at 3°35′–3°41′N

Mineral chemical analyses of transitional basalts from the Carlsberg Ridge show plagioclase (An ~ 87 mole %), phenocrysts, and microphenocrysts have a K₂O depletion as compared to the laths (An ~ 79 mole %). Olivine (Fo ~ 91 mole %) are few and rarely zoned. The composition of plagioclase and olivine indicate low pressure equilibrium crystallization. The basalts were probably derived through fractional crystallization at shallow depths under low partial melting conditions. Morphology of plagioclase phenocrysts and bulk rock chemistry suggest magma mixing and fractional crystallization for the origin of these basalts. (Detailed chemical analyses can be obtained from the authors.)     

Chemical composition and petrogenesis of plagioclases in plagioclase-phyric basalts from the Southwest Indian Ridge(51°E)

Electron microprobe analysis was conducted on plagioclase from the plagioclase ultraphyric basalts(PUBs)erupted on the Southwest Indian Ridge(SWIR)(51°E) to investigate the geochemical changes in order to better understand the magmatic processes occurring under ultraslow spreading ridges and to provide insights into the thermal and dynamic regimes of the magmatic reservoirs and conduit systems. The phenocryst cores are generally calcic(An_(74–82)) and are depleted in FeO and MgO. Whereas the phenocryst rims(An_(67–71)) and the plagioclase in the groundmass(An_(58–63)) are more sodic and have higher FeO and MgO contents than the phenocryst cores. The crystallization temperatures of the phenocryst cores and the calculation of the equilibrium between the phenocrysts and the matrix suggest that the plagioclase cores are unlikely to have crystallized from the host basaltic melt, but are likely to have crystallized from a more calcic melt. The enrichment in incompatible elements(FeO and MgO), as well as the higher FeO/MgO ratios of the outermost phenocryst rims and the groundmass, are the result of plagioclase-melt disequilibrium diffusion during the short residence time in which the plagioclase crystallized. Our results indicate that an evolved melt replenishing under the SWIR(51°E) drives the eruption over a short period of time.     

印度洋Carlsberg洋脊玄武岩岩石地球化学特征及其地质意义

本文对采自印度洋Carlsberg脊14个站位的新鲜玄武岩样品进行了常量和微量元素组成分析,旨在研究岩浆源区地幔的性质以及岩浆作用过程。研究结果表明:该区玄武岩为典型的源于亏损型地幔的大洋中脊玄武岩,不同样品经历了不同程度的结晶分异作用,演化过程主要受控于橄榄石的结晶分异作用,部分样品中有单斜辉石结晶分异作用的影响,斜长石的结晶分异作用不显著;玄武岩岩浆来源于亏损型尖晶石二辉橄榄岩地幔的熔融,主微量元素组成中尚未见到富集型组分混入的证据;源区地幔不同比例的熔融作用及其后岩浆演化过程的差异是造成不同样品间地球化学性质差异的主要原因,彼此独立的局部岩浆作用过程是岩浆作用差异的主控制因素。Carlsberg脊玄武岩整体与全球标准大洋中脊玄武岩(N-MORB)平均组分相近,不同脊段间岩浆源区地幔的组成、熔融程度(比例)和熔融深度等无明显差异,这种特征向南直到CIR的北段。     

Rocks from the Gibbs fracture zone and the Minia seamount near 53°N in the Atlantic Ocean

Rocks dredged and drilled from both the rift mountains of the Mid-Atlantic Ridge (Minia seamount) and from the northern wall and the median ridge of the adjacent Gibbs fracture zone near 53°N include tholeiites, serpentinized and mylonitized peridoties, and gabbroic rock.The tholeiites include: (1) pyroxene-tholeiites, commonly without phenocrysts and containing less than 15% Al₂O₃; (2) plagioclase-tholeiites with small (1.1–2.2 mm length) plagioclase phenocrysts and an Al₂O₃ content varying between 14–17%; and (3) high-alumina plagioclase tholeiites with large (> 2.5 mm length) plagioclase phenocrysts and more than 17% Al₂O₃. The apparently transitional differences among the three groups support the possibility that differentiation by crystal fractionation of the high-alumina plagioclase-tholeiites gave rise to the plagioclase-tholeiites with less Al₂O₃ and smaller phenocrysts and to the pyroxene-tholeiites. A small portion of the basalts ampled show effects of low-grade metamorphism. The peridotites may represent evidence of intrusive emplacement of peridotitic material beneath the tholeiitic rocks.     

北冰洋Gakkel洋中脊的地幔熔融控制因素及非岩浆地壳增生

Spreading rate is a primary factor of mantle melting and tectonic behavior of the global mid-ocean ridges. The spreading rate of the Gakkel ridge decreases gradually from west to east. However, the Gakkel ridge can be divided into four thick-and-thin zones with varying crustal thicknesses along ridge axis. This phenomenon indicates that mantle melting of the Gakkel ridge is not a simple function of spreading rate. Mantle temperature, water content,mantle composition, and other factors are important in crustal accretion processes. Based on gravity-derived crustal thickness and wet melting model, we estimate that the mantle potential temperatures of the four zones are1 270, 1 220, 1 280, and 1 280°C(assuming that mantle water content equals to global average value), with corresponding mantle water contents of 210, 0, 340, and 280 mg/kg(assuming that mantle potential temperature is 1 260°C), respectivly. The western thinned crust zone is best modeled with low mantle temperature, whereas the other zones are mainly controlled by the enhanced conduction caused by the slower spreading rate. Along the Gakkel ridge, the crustal thickness is consistent with rock samples types. Predominated serpentinized peridotite and basalt are found in the area with crustal thickness 1.5 km and 2.5 km, respectively. The rock samples are including from basalt to peridotite in the area with crustal thickness between 1.5 and 2.5 km. Based on this consistency, the traditional magmatic accretion zone accounted for only 44% and amagmatic accretion accounted for 29% of the Gakkel ridge. The amagmatic accretion is a significant characteristic of the ultra-slow spreading ridge.     

西太平洋海山年龄及地球化学:地幔过程及岩石成因

Research on seamounts provides some of the best constraints for understanding intraplate volcanism, and samples from seamounts reveal crucial evidence about the geochemical makeup of the oceanic mantle. There are still many seamounts in the West Pacific Seamount Province(WPSP) that have not been studied, meaning their ages and geochemistry remain unknown. A better understanding of these seamount trails and their evolutionary history, investigated with age and geochemistry data, will enable better understanding of the geological processes operating underneath the Pacific Ocean Plate. Here, new ~(40)Ar/~(39) Ar ages and trace element and Sr-Nd-Pb isotopic data for seven basalt rocks from four seamounts in the WPSP are provided. Chemically, these rocks are all Oceanic Island Alkali basalt(OIA type); analysis of olivine phenocrysts shows that the magmas experienced strong olivine fractionation and changed from olivine + plagioclase to olivine + plagioclase + clinopyroxene cotectic during their evolution. Rare earth element(REE) patterns and a spider diagram of the samples in this study show OIB(Ocean Island Basalt) like behavior. The range of ~(87)Sr/~(86) Sr values is from 0.704 60 to 0.706 24, the range of ~(206)Pb/~(204) Pb values is from 18.241 to 18.599, and the range of ~(143)Nd/~(144) Nd values is from 0.512 646 to 0.512 826; together, these values indicate magma sources ranging from EMI to EMII. Finally, new ~(40)Ar/~(39) Ar age data show that these seamounts formed at ～97 and ～106 Ma, indicating that some may have undergone the same formation processes as seamounts in the eastern part of the Magellan Seamount Trail, but other seamounts likely have different origins.     

Evolution of the basalts from three back-arc basins of southwest Pacific

 Petrography, petrochemistry, and mineral chemistry of basalts from the Woodlark, Manus, and Lau basins from the southwest Pacific, have been studied to understand their magmatic evolution. Basalt from the western Woodlark Basin (Dobu Seamount) indicates mixing of a near-primitive magma with fractionated basaltic melt in shallow magma chambers. Basalts from Manus Basin and Central Lau Spreading Center (Lau Basin) are typical N-MORBs, and they exhibit olivine fractionation under high oxidizing conditions while basalts from Mangatolu Triple Junction (Lau Basin) are enriched in Al₂O₃, K₂O, and Zr indicative of a contribution from a subducting plate. Received: 4 August 1998 / Revision received: 19 February 1999     

Evolution of the basalts from three back-arc basins of southwest Pacific

Petrography, petrochemistry, and mineral chemistry of basalts from the Woodlark, Manus, and Lau basins from the southwest Pacific, have been studied to understand their magmatic evolution. Basalt from the western Woodlark Basin (Dobu Seamount) indicates mixing of a near-primitive magma with fractionated basaltic melt in shallow magma chambers. Basalts from Manus Basin and Central Lau Spreading Center (Lau Basin) are typical N-MORBs, and they exhibit olivine fractionation under high oxidizing conditions while basalts from Mangatolu Triple Junction (Lau Basin) are enriched in Al₂O₃, K₂O, and Zr indicative of a contribution from a subducting plate.