Sedimentary cover deformations in the equatorial Atlantic and their comparison with geophysical fields

The deformations of the sedimentary cover at near-latitudinal geotraverses west and east of the Mid-Atlantic Ridge in the equatorial part of ocean are compared with potential fields and variations of the V _p/V _s attribute at a depth of ~470 km. The features of sedimentary cover deformations in abyssal basins are formulated, as well as their differences from the undisturbed bedding of sediments. The elements of chain of phenomena with common spatial manifestations and cause-and-effect relationships have been established, including heterogeneous horizontal movements, which make up macrojointing above “cold” mantle blocks at a depth of ~470 km; serpentinization of upper-mantle rocks; the formation of superposed magnetic anomalies; the release of the fluids, which acoustically bleach out the sedimentary sequence in seismic imaging; and decompaction of rocks leading to vertical motions and forced folding. The origin of the Atlantic marginal dislocation zone is explained. The coincidence of the deformation boundary in the equatorial Atlantic with the zero contour line of the V _p/V _s attribute is revealed. This coincidence is an indicator of the rheological state of the upper mantle.     

Geochronological and geochemical constraints on the origin of the Southeast Anatolian ophiolites,Turkey

The Southeast Anatolian ophiolites outcropping in the Southeast Anatolian Orogenic Belt (Southeast of Turkey) mark the closure of the southern branch of the Neotethys Ocean associated with the collision between the Arabian Plate and Anatolian microplate. We present new geochemical, zircon U–Pb age, zircon Lu–Hf, and Sr-Nd isotopic data on the Southeast Anatolian Ophiolites to understand their formation ages, magma genesis, and geotectonic implications. The ophiolites, which are related to island arc igneous rocks, consist of mantle peridotites and crustal rocks (less dunite, gabbros, sheeted dykes, massive, and pillow basalts). The flat rare-earth element (REE) patterns, depletion in Nb and Ta, and enrichment in LILEs (Ba, Rb, Th, Sr, Pb) of gabbros suggest close similarities with very low Ti (boninitic) lavas found in the forearc regions. Using laser ablation inductively coupled plasma–mass spectrometry, zircon separated from leucogabbros, diabase dykes, and plagiogranites yield U-Pb ages of 92 and 83 Ma, which are interpreted to represent the formation ages of the ophiolites. The zircons in the gabbros and plagiogranites are dominated by positive εHf(t) values (between +3.1 and +?17.45) with a few negative εHf(t) values. High εHf(t) features are consistent with derivation from Mid-oceanic Ridge Basalt (MORB)-source mantle. The negative εHf(t) values of the zircons suggest the involvement of subducted sedimentary rocks. The southeast Anatolian ophiolites represent an SSZ-type ophiolite and are part of the Late Cretaceous oceanic lithosphere of the southern branch of the Neotethys Ocean that opened during the Late Triassic and closed during the Late Cretaceous.     

H<Subscript>2</Subscript>O masers and protoplanetary disk dynamics in IC 1396 N

We report H₂O maser line observations of the bright-rimmed globule IC 1396 N using a ground-space interferometer with the 10-m RadioAstron radio telescope as the space-based element. The source was not detected on projected baselines >2.3. Earth diameters, which indicates a lower limit on the maser size of L > 0.03 AU and an upper limit on the brightness temperature of 6.25 × 10¹² K. Fringe-rate maps are prepared based on data from ground-ground baselines. Positions, velocities and flux densities of maser spots were determined. Multiple low-velocity features from ?4.5 km/s to +0.7 km/s are seen, and two high-velocity features of V _LSR = ?9.4 km/s and V _LSR = +4.4 km/s are found at projected distances of 157 AU and 70 AU, respectively, from the strongest low-velocity feature at V _LSR = ~+0.3 km/s. Maser components from the central part of the spectrum fall into four velocity groups but into three spatial groups. Three spatial groups of low-velocity features detected in the 2014 observations are arranged in a linear structure about ~200 AU in length. Two of these groups were not detected in 1996 and possibly are jets which formed between 1996 and 2014. The putative jet seems to have changed direction in 18 years, which we explain by the precession of the jet under the influence of the gravity of material surrounding the globule. The jet collimation can be provided by a circumstellar protoplanetary disk. There is a straight line orientation in the “V _LSR-Right Ascension” diagram between the jet and the maser group at V _LSR = ~+0.3 km/s. However, the central group with the same position but at the velocity V _LSR ~ ?3.4 km/s falls on a straight line between two high-velocity components detected in 2014. Comparison of the low-velocity positions from 2014 and 1996, based on the same V _LSR-Right Ascension diagram for low-velocity features, shows that the majority of the masers maintain their positions near the central velocity V _LSR = ~0.3 km/s during the 18 year period.     

Peculiarities and variations in the optical spectrum of the post-AGB star V448 Lac = IRAS 22223+4327

Multi-epoch observations with high spectral resolution acquired in 1998–2008 are used to study the time behavior of the spectral-line profiles and velocity fields in the atmosphere and circumstellar shell of the post-AGB star V448 Lac. Asymmetry of the profiles of the strongest absorption lines with lower-level excitation potentials χ _low < 1 eV and time variations of these profiles have been detected, most prominently the profiles of the resonance lines of BaII, YII, LaII, SiII. The peculiarities of these profiles can be explained using a superposition of stellar absorption line and shell emission lines. Emission in the (0; 1) 5635 Å Swan system band of the C₂ molecule has been detected in the spectrum of V448 Lac for the first time. The core of the Hα line displays radial-velocity variations with an amplitude of ΔV _r ≈ 8 km/s. Radial-velocity variations displayed by weak metallic lines with lower amplitudes, ΔV _r ≈ 1–2 km/s, may be due to atmospheric pulsations. Differential line shifts, ΔV _r = 0–8 km/s have been detected on various dates. The position of the molecular spectrum is stationary in time, indicating a constant expansion velocity of the circumstellar shell, V _exp = 15.2 km/s, as derived from the C₂ and NaI lines.     

Genesis of the Paleoproterozoic Rare-Metal Granites of the Katugin Massif

We studied the petrography, mineralogy, and geochemistry of the Paleoproterozoic (2.06 Ga) granites of the Katugin massif (Stanovoy suture zone), which hosts the combined rare-metal Katugin deposit. Three groups of granites were distinguished: (1) biotite (Bt) and biotite–riebeckite (Bt–Rbk) granites of the western block of the massif; (2) biotite–arfvedsonite (Bt–Arf) granites of the eastern block; and (3) arfvedsonite (Arf), aegirine–arfvedsonite (Aeg–Arf), and aegirine (Aeg) granites of the eastern block. The Bt and Bt–Rbk granites of the first group are mainly metaluminous and peraluminous rocks with rather high CaO contents and the minimum F contents among the granites described here. It was suggested that the granites of this group could be derived from a source dominated by crustal rocks with a small addition of mantle materials. These granites probably crystallized from a metaluminous–peraluminous melt with elevated CaO and moderate F contents. Melts of such compositions are least favorable for the crystallization of ore minerals. The Bt–Arf granites of the second group are mainly peralkaline and show high contents of CaO and Y and low contents of Na₂O and F. A mixed mantle–crust source was proposed for the Bt–Arf granites. The initial melt of the Bt–Arf granites could have a peralkaline composition with elevated CaO content and moderate to high F content. The Arf, Aeg–Arf, and Aeg granites of the third group are enriched in ore mineral and were classified as peralkaline granites with very low CaO contents, elevated Na2O and F contents, and usually very high contents of Zr, Hf, Nb, and Ta. Based on the geochemical and isotopic data, it was supposed that the source of the granites of the third group could be derivatives of basaltic magmas produced in an OIB-type source with a minor addition of crustal material to the magma generation zone. It was suggested that the primary melt of this granite group could be a peralkaline CaO-poor and F-rich silicic melt, which is most favorable for the crystallization of ore minerals. Based on the analysis of the geochemical characteristics of the three granite groups and their relationships within the Katugin massif, a qualitative model of its formation was proposed. According to this model, the Bt and Bt–Rbk granites of the western block crystallized first, followed by the Bt–Arf granites of the eastern block and, eventually, the Arf, Aeg–Arf, and Aeg granites enriched in ore minerals.     

The H<Subscript>2</Subscript>O supermaser region in Orion KL: Epoch 1982.9

Radio interferometric observations of an H₂O maser flare in the Orion Nebula at epoch 1982.9 have been used to determine the flare’s spatial structure. Antennas in the Crimea, Effelsberg, and Onsala were used. The emission region consists of three groups of components. The angular sizes of the components are 0.2–0.9 mas, and the widths of the emitted lines are 0.2–0.7 km/s. The velocities of the components are correlated with their relative positions, which correspond to expanding concentric rings. Assuming a 1 M_⊙ protostar in a Keplerian approximation, the radius of the inner ring R is 15 AU, the velocity of its rotation V_rot is 8.98 km/s, and the radial component of the velocity V_rad is 1.79 km/s. For the outer ring, R=15.7 AU, V_rot=8.79 km/s, and V_rad=2.61 km/s.     

Sources of fluids and material for gold and antimony mineralization in the Adychanskii ore region (East Yakutia,Russia)

The peculiarities of fluid inclusions; the O and C isotope composition of host rocks, vein minerals, and inclusions; and the S and Pb isotope composition of sulfides allowed us to distinguish two groups of fluids with a similar temperature, salinity, and source of the aqueous part produced upon metagenesis and mobilized during collisional events. Quartz-A precipitates from the CO₂–H₂O hydrocarbonate–Na fluid with a salinity of 7–10 wt % eq. NaCl at a depth of ～6 km (290–340°C, 1550 bar). Regeneration of quartz (quartz-C), precipitation of quartz-B, and quartz-AB with carbonate and chlorite occurred at a depth from 3.5 to 1.5 km (250–380°C, 1250–900–350 bar) from CO₂–CH₄–N hydrous sulfate–hydrocarbonate Na–Mg fluids with Cl^–, Ca, and K and a salinity of 5–10 wt % eq. NaCl, and a wide variety of impurities. The localization of veins in sinistral shear dislocations and strong heterogeneity in the P–T conditions allow us to explain the formation of fluid-2 by the postcollisional events.     

Devonian volcanics in the Voronezh Crystalline Massif,East European Platform: Evolution of the melts and characteristics of crustal contamination

The rift system of the Dnieper–Donets trough (DDT) is the largest magmatic area in the East European Platform. Basalts of the Voronezh Crystalline Massif (VCM) are spatially constrained to the eastern shoulder of DDT and occur far away (at a distance of 150–200 km) from the rift axis. The rocks are hosted in the Paleoproterozoic Vorontsovskii terrane and are grouped in a few fields within an area of 200 × 100 km. Basalts at most of the fields were erupted at the boundary between mid- and late Frasnian time in the Late Devonian and can be studied exclusively in core material recovered by boreholes. Newly obtained mineralogical, geochemical, and isotopic-geochemical data show that the Devonian volcanic rocks in VCM are tholeiites (Bas) and basaltic andesites/andesites (ABas). The geological section was examined most exhaustively in the Novokhopersk area (Borehole 175). The bottom of the vertical section is made up of basaltic andesites and andesites (ABas) (thickness 34 m), which rest on an eroded surface of late Frasnian sandstones. The rocks are overlain by a thin (8 m thick) tholeiite sheet (Bas2), which gives way to ABas (13 m) upsection. The top portion of the vertical section is composed of tholeiites with petrography and geochemical evidence of crustal contamination (Bas1) (apparent thickness 5 m). Geochemical parameters of Bas (mg# 42–52 at SiO₂ 47–51 wt %) are typical of continental tholeiites. The rocks have (⁸⁷Sr/⁸⁶Sr)₀ = 0.7043–0.7048 and ε_Nd(372) = 2.1–3.5. ABas (mg# 28–31 at SiO₂ 52–60 wt %) are enriched in Y (48 ppm), and possess Nb/Nb* = 0.7–0.8 and high Zn/Cu = 1.9–2.3. The rocks have (⁸⁷Sr/⁸⁶Sr)₀ = 0.7034–0.7048 and Nd–ε_Nd(372) = 0.1. Some portions of Bas melts assimilated the upper crustal material, which was similar to Paleoproterozoic granites, and ABas are contaminated in the lower crust with derivatives of Early Cambrian alkaline mafic melts. Petrographic data and simulations of fractional crystallization show that olivine and high-Mg clinopyroxene were the first to crystallize from the melt. After this, clinopyroxene and plagioclase simultaneously crystallized at temperatures from 1070 to 1020°C in Bas and at 1040–900°C at f _O2 below QFM + 1 in ABas. The source of ABas was likely a network of hornblendite or amphibole pyroxenite veins in peridotite in the lithospheric mantle or amphibolized peridotite cumulate in an underplating zone; and Bas were derived from spinel peridotites of an asthenospheric diapir. The setting of the basalts relative to the DDT axis and the asymmetric zoning of magmatism in DDT (with kimberlites and other deep rocks constrained to the western shoulder and tholeiites occurring in the axial part of the rift and its eastern shoulder) can be explained by the model of an asymmetric rift structure with a translithospheric detachment gently dipping beneath VCM.     

Si and O self-diffusion in hydrous forsterite and iron-bearing olivine from the perspective of defect chemistry

We discuss the experimental results of silicon and oxygen self-diffusion coefficients in forsterite and iron-bearing olivine from the perspective of defect chemistry. Silicon diffusion is dominated by V_O ^··-associated V_Si″″, whereas oxygen diffusion is dominated by hopping of V_O ^·· under anhydrous conditions, and by (OH)_O ^· under hydrous conditions. By considering the charge neutrality condition of [(OH)_O ^·] = 2[V_Me″] in hydrous forsterite and iron-bearing olivine, we get D _Si ∝ (\(C_{{{\text{H}}_{2} {\text{O}}}}\))^1/3 and D _O ∝ (\(C_{{{\text{H}}_{2} {\text{O}}}}\))⁰, which explains the experimental results of water effects on oxygen and silicon self-diffusion rates (Fei et al. in Nature 498:213–215, 2013; J Geophys Res 119:7598–7606, 2014). The \(C_{{{\text{H}}_{2} {\text{O}}}}\) dependence of creep rate in the Earth’s mantle should be close to that given by Si and O self-diffusion coefficients obtained under water unsaturated conditions.     

<Emphasis Type="Italic">P</Emphasis>–<Emphasis Type="Italic">V</Emphasis>–<Emphasis Type="Italic">T</Emphasis> equation of state of CaAl<Subscript>4</Subscript>Si<Subscript>2</Subscript>O<Subscript>11</Subscript> CAS phase

The thermoelastic parameters of the CAS phase (CaAl₄Si₂O₁₁) were examined by in situ high-pressure (up to 23.7 GPa) and high-temperature (up to 2,100 K) synchrotron X-ray diffraction, using a Kawai-type multi-anvil press. P–V data at room temperature fitted to a third-order Birch–Murnaghan equation of state (BM EOS) yielded: V _0,300 = 324.2 ± 0.2 Å³ and K _0,300 = 164 ± 6 GPa for K′ _0,300 = 6.2 ± 0.8. With K′ _0,300 fixed to 4.0, we obtained: V _0,300 = 324.0 ± 0.1 Å³ and K _0,300 = 180 ± 1 GPa. Fitting our P–V–T data with a modified high-temperature BM EOS, we obtained: V _0,300 = 324.2 ± 0.1 Å³, K _0,300 = 171 ± 5 GPa, K′ _0,300 = 5.1 ± 0.6 (?K _0,T /?T) _P  = ?0.023 ± 0.006 GPa K^?1, and α_0,T  = 3.09 ± 0.25 × 10^?5 K^?1. Using the equation of state parameters of the CAS phase determined in the present study, we calculated a density profile of a hypothetical continental crust that would contain ~10 vol% of CaAl₄Si₂O₁₁. Because of the higher density compared with the coexisting minerals, the CAS phase is expected to be a plunging agent for continental crust subducted in the transition zone. On the other hand, because of the lower density compared with lower mantle minerals, the CAS phase is expected to remain buoyant in the lowermost part of the transition zone.     

Testing Study of Subcritical Crack Growth Mechanism During Water Rock Interaction

Subcritical crack growth plays an important role in evaluating the long-term stability of structures in rocks. By applying the constant-displacement-relax method, two groups of test specimens that one immersed in groundwater and the other in air were tested to get the parameters of subcritical crack growth in double torsion test. The relations of the stress intensity factor K _I versus the subcritical crack growth velocity V were obtained under the two different environments, and the behavior of subcritical crack growth was also analyzed. The results showed: the relations of lg K _I  ? lg V accorded with linear rules, which is in good agreement with Charles theory; Compared with specimens in nature state, the lg K _I  ? lg V curves of saturated water specimens locate top left comer of those of air specimens. The slope of curve is smaller, and the intercept is bigger, which shows that the water–rock interaction speeds up the subcritical crack growth. And A increases 2.9 × 10¹⁸ folds but n decreases from 85.12 to 40.83 because of the water–rock interaction. Meanwhile, the fracture toughness K _IC also decreases obviously from 2.55 in air to 2.26 in water due to water rock interaction. The testing results provide a basis for time-dependence of rock engineering stability.     

The Sr,Nd, and Hf isotopic geochemistry of rocks of the gabbro–diorite–tonalite association from the Eastern Segment of the Middle Urals as an indicator of the age of the continental crust in this area

According to isotopic analysis of rocks of the Reft gabbro–diorite–tonalite complex (Middle Urals), gabbro and related diorite and dikes and vein-shaped bodies of plagiogranitoids, crosscutting gabbro, are similar to the depleted mantle substance in ε_Nd(T) = 8.6–9.7 and ε_Hf(T) = 15.9–17.9. Their model Hf ages are correlated with the time of crystallization. Here, the tonalites and quartz diorites constituting most of the Reft massif are characterized by lower values: ε_Nd(T) = 3.7–6.0, ε_Hf(T) = 11.1–12.7, and T _DM values significantly exceeding the age datings. This is evidence that Neoproterozoic crustal rocks were a source of parental magma for these rocks. The primary ⁸⁷Sr/⁸⁶Sr ratio in rocks of both groups is highly variable (0.70348–0.70495). The data obtained allow us to reach the conclusion that the Reft gabbro–diorite–tonalite complex was formed as a result of nearly synchronous processes occurring in the crust and the mantle within a limited area.     

Shock tracers in the molecular cloud G1.6-0.025

Observations of the molecular cloud G1.6-0.025 in the 2_K-1_K and J₀-J_?1E series and 5_?1-4₀E line of CH₃OH, the (2-1) and (3-2) lines of SiO, and the 7_?7-6_?6 line of HNCO are described. Maps of the previously observed extended cloud with V_lsr～50 km/s and high-velocity clump with V_lsr～160 km/s, as well as a newly detected clump with V_lsr～0 km/s, have been obtained. The extended cloud and high-velocity clump have a nonuniform structure. The linewidths associated with all the objects are between 20 and 35 km/s, as is typical of clouds of the Galactic center. In some directions, emission at velocities from 40 to 160 km/s and from ?10 to +75 km/s is observed at the clump boundaries, testifying to a connection between the extended cloud and the high-velocity clump and clump at V_lsr～0 km/s. Compact maser sources are probaby contributing appreciably to the emission of the extended cloud in the 5_?1-4₀E CH₃OH line. Non-LTE modeling of the methanol emission shows that the extended cloud and high-velocity clump have a relatively low hydrogen density (<10⁴ cm^?3). The specific column density of methanol in the extended cloud exceeds 6×10⁸ cm^?3s, and is 4×10⁸?6×10⁹ cm^?3s in the high-velocity clump. The kinetic temperatures of the extended cloud and high-velocity clump are estimated to be <80 K and 150–200 K, respectively. Possible mechanisms that can explain the link between the extended cloud with V_lsr～50 km/s and the clumps with V_lsr～0 km/s and ～160 km/s are briefly discussed.     

Experimental calibration of Forsterite–Anorthite–Ca-Tschermak–Enstatite (FACE) geobarometer for mantle peridotites

The crystallization of plagioclase-bearing assemblages in mantle rocks is witness of mantle exhumation at shallow depth. Previous experimental works on peridotites have found systematic compositional variations in coexisting minerals at decreasing pressure within the plagioclase stability field. In this experimental study we present new constraints on the stability of plagioclase as a function of different Na₂O/CaO bulk ratios, and we present a new geobarometer for mantle rocks. Experiments have been performed in a single-stage piston cylinder at 5–10 kbar, 1050–1150?°C at nominally anhydrous conditions using seeded gels of peridotite compositions (Na₂O/CaO?=?0.08–0.13; X _Cr = Cr/(Cr?+?Al)?=?0.07–0.10) as starting materials. As expected, the increase of the bulk Na₂O/CaO ratio extends the plagioclase stability to higher pressure; in the studied high-Na fertile lherzolite (HNa-FLZ), the plagioclase-spinel transition occurs at 1100?°C between 9 and 10 kbar; in a fertile lherzolite (FLZ) with Na₂O/CaO?=?0.08, it occurs between 8 and 9 kbar at 1100?°C. This study provides, together with previous experimental results, a consistent database, covering a wide range of P–T conditions (3–9 kbar, 1000–1150?°C) and variable bulk compositions to be used to define and calibrate a geobarometer for plagioclase-bearing mantle rocks. The pressure sensitive equilibrium:

$$\mathop {{\text{M}}{{\text{g}}_{\text{2}}}{\text{Si}}{{\text{O}}_{\text{4}}}^{{\text{Ol}}}}\limits_{{\text{Forsterite}}} +\mathop {{\text{CaA}}{{\text{l}}_{\text{2}}}{\text{S}}{{\text{i}}_{\text{2}}}{{\text{O}}_{\text{8}}}^{{\text{Pl}}}}\limits_{{\text{Anorthite}}~} =\mathop {{\text{CaA}}{{\text{l}}_{\text{2}}}{\text{Si}}{{\text{O}}_{\text{6}}}^{{\text{Cpx}}}}\limits_{{\text{Ca-Tschermak}}} +{\text{ }}\mathop {{\text{M}}{{\text{g}}_{\text{2}}}{\text{S}}{{\text{i}}_{\text{2}}}{{\text{O}}_{\text{6}}}^{{\text{Opx}}}}\limits_{{\text{Enstatite}}} ,$$

has been empirically calibrated by least squares regression analysis of experimental data combined with Monte Carlo simulation. The result of the fit gives the following equation:

$$P=7.2( \pm 2.9)+0.0078( \pm 0.0021)T{\text{ }}+0.0022( \pm 0.0001)T{\text{ }}\ln K,$$

$${R^2}=0.93,$$

where P is expressed in kbar and T in kelvin. K is the equilibrium constant K?=?a _CaTs × a _en/a _an × a _fo, where a _CaTs, a _en, a _an and a _fo are the activities of Ca-Tschermak in clinopyroxene, enstatite in orthopyroxene, anorthite in plagioclase and forsterite in olivine. The proposed geobarometer for plagioclase peridotites, coupled to detailed microstructural and mineral chemistry investigations, represents a valuable tool to track the exhumation of the lithospheric mantle at extensional environments.

     

The buffering capacity of lithospheric mantle: implications for diamond formation

Current models for the formation of natural diamond involve either oxidation of a methane-bearing fluid by reaction with oxidized mantle, or reduction of a carbonate-bearing fluid (or melt) by reaction with reduced mantle. Implicit in both models is the ability of the mantle with which the fluid equilibrates to act as an oxidizing or reducing agent, or more simply, to act as a source or sink of O₂. If only redox reactions involving iron are operating, the ability of mantle peridotite to fulfill this role in diamond formation may not be sufficient for either model to be viable. Using the recent experimental recalibration of olivine–orthopyroxene–garnet oxybarometers of Stagno et al. (2013), we re-evaluated the global database of ~200 garnet peridotite samples for which the requisite Fe³⁺/Fe²⁺ data for garnet exist. Relative to the previous calibration of Gudmundsson and Wood (1995), the new calibration yields somewhat more oxidized values of Δlog fO₂ (FMQ), with the divergence increasing from <0.5 units of log fO₂ at ~3 GPa to as much as 1.5 units at 5–6.5 GPa. Globally, there is a range of ~4 log units fO₂ for samples from the diamond stability field at any given pressure. Most samples are sufficiently reduced such that diamond, rather than carbonate, would be stable, and CHO fluids at these conditions would be H₂O-rich (>60 mol%), with CH₄ being the next most abundant species. To ascertain the capacity for mantle peridotite to act as a source or sink of O₂, we developed a new model to calculate the fO₂ for a peridotite at a given P, T, and Fe³⁺/Fe²⁺. The results from this model predict 50 ppm or less O₂ is required to shift a depleted mantle peridotite the observed four log units of fO₂. Coupled with the observed distribution of samples at values of fO₂ intermediate between the most reduced (metal-saturated) and most oxidized (carbonate-saturated) possible values for diamond stability, these results demonstrate that peridotites are very poor sinks or sources of O₂ for possible redox reactions to form diamond. A corollary of the poor redox buffering capacity of cratonic peridotites is that they can be employed as faithful indicators of the redox state of the last metasomatic fluid that passed through them. We propose that diamond formation from CHO fluids is a predictable consequence either of isobaric cooling or of combined cooling and decompression of the fluid as it migrates upward in the lithosphere. This establishes a petrological basis for the observed close connection between subcalcic garnet and diamond: based on high solidus temperatures of harzburgite and dunite effectively precluding dilution of CHO fluids through incipient melts, such highly depleted cratonic peridotites are the preferred locus of diamond formation. Due to a rapid increase in solidus temperature with increasing CH₄ content of the fluid, diamond formation related to reduced CHO fluids may also occur in some cratonic lherzolites.     

Specifics of the Neoarchean Plume–Lithospheric Processes in the Kola–Norwegian Province of the Fennoscandian Shield: II. Petrology and Geodynamic Nature of Komatiite–Tholeiite Association

Numerical modeling of the generation and evolution of parental melts of the komatiite–tholeiite association of the Uraguba structure was carried out using previously obtained geochemical and isotope data. It was established that komatiite, komatiite and tholeiite basalts depleted in LREE and having ε_Nd(Т = 2.79) = +2.9…+3.2 were generated by equilibrium partial melting (F > 15%) of a depleted source (garnet-bearing Ol_0.63 + Opx_0.22 + Cpx_0.06 + Grt_0.09 mantle peridotite) at 4–8 GPa, while the genesis of primary melts of LREE-enriched komatiites (La_N/Sm_N ~ 1.2–1.6) with ε_Nd(Т = 2.79) = +2.5…+2.2 was related to the equilibrium partial melting (F > 20%) of an “enriched mantle peridotite” (EM–Ol_0.60 + Opx_0.20 + Cpx_0.08 + Grt_0.12) at pressure of 2.5–4 GPa. Coexistence in space and time of two types of melting products of mantle peridotites formed at different depths is explained by melting of different parts of adiabatically ascending mantle plume.     

The stress regime in a Rotliegend reservoir of the Northeast German Basin

In-situ stresses have significant impact, either positive or negative, on the short and long term behaviour of fractured reservoirs. The knowledge of the stress conditions are therefore important for planning and utilization of man-made geothermal reservoirs. The geothermal field Groß Schönebeck (40 km north of Berlin/Germany) belongs to the key sites in the northeastern German Basin. We present a stress state determination for this Lower Permian (Rotliegend) reservoir by an integrated approach of 3D structural modelling, 3D fault mapping, stress ratio definition based on frictional constraints, and slip-tendency analysis. The results indicate stress ratios of the minimum horizontal stress S _hmin being equal or increasing 0.55 times the amount of the vertical stress S _V (S _hmin ≥ 0.55S _V ) and of the maximum horizontal stress S _Hmax ≤ 0.78–1.00S _V in stress regimes from normal to strike slip faulting. Thus, acting stresses in the 4,100-m deep reservoir are S _V  = 100 MPa, S _hmin = 55 MPa and S _Hmax = 78?100 MPa. Values from hydraulic fracturing support these results. Various fault sets of the reservoir are characterized in terms of their potential to conduct geothermal fluids based on their slip and dilatation tendency. This combined approach can be adopted to any other geothermal site investigation.     

A middle Triassic extensional event in the Hainan Island: Geochronologic and geochemical evidence from igneous rocks from Dazhou Island

Hainan Island lies at the southern tip of the South China block that was affected by the opening and closure of the paleo-Tethys from Paleozoic to Mesozoic and subsequently by the subduction of the paleo- Pacific plate beneath the Euroasian plate since the late Mesozoic era. This study presents zircon U-Pb ages and geochemistry of granites and basic diabase veins in Dazhou Island located 5 km southeast of Hainan Island. The age for granites is 237.2 Ma (MSWD = 0.14, n = 14), suggesting that they were emplaced in the late middle Triassic and are products of magmatic-tectonic episodes during the closure of paleo-Tethys. The granites belong to the shoshonitic magmatic series and are metaluminous I-type granites. They are systematically depleted in Ba, Nb, Sr, P, and Ti, and have variable ranges of initial ⁸⁷Sr/⁸⁶Sr ratios (0.71005 ~ 0.71110), but relatively constant εNd(t) values (–6.4~–6.8). The two-stage depleted mantle Nd model ages (T_DM2 = 1531–1562 Ma) for these granites suggest that they may have originated from partial melting of the lower crust with a crustal residence age of early Middle Proterozoic Era. The zircon U-Pb ages for diabase veins can be divided into three groups. The age for Group I is 236.8 Ma (n = 4), which represents the crystallization age of the veins and somewhat younger than the accompanying granites. The ages for Group II and III are 1767 Ma (n = 6) and 2432 Ma (n = 3), respectively. These suggest that the veins have inherited some old zircons that possibly represent old geological events in the Hainan Islands. The diabase also belongs to the shoshonitic magmatic series and has arc-like trace element characteristics. The veins have high 87Sr/86Sr and low 143Nd/144Nd ratios, which suggest that they may have originated from an enriched mantle II type source or a mantle source metasomatized by aqueous fluids released from previously subducted slab. The new ages obtained for the Dazhou igneous rocks in the present study are similar to those for the Qiongzhong batholith in the Hainan Island, which implies that the Hainan Island had also regionally experienced a middle Triassic extension event after the Indosinian Orogeny.     

Galactic parameters derived from open-cluster data

The components U₀ and V₀ of the solar motion and the Oort constant A₀ are determined using the data of a homogeneous open-cluster catalog with corrected distance moduli. The results are based on a sample of 146 open clusters with known radial velocities located in the Galactic plane (b<7°) within 4 kpc of the Sun. The solar Galactocentric distance R₀ is determined using two kinematic methods. The following results are obtained: A₀=17.0±0.9 km/s kpc, U₀=10.5±1.0 km/s, V₀=11.5±1.1 km/s, R₀=8.3±0.3 pc.     

High-pressure behavior of natural single-crystal epidote and clinozoisite up to 40 GPa

The comparative compressibility and high-pressure stability of a natural epidote (0.79 Fe-total per formula unit, Fe_tot pfu) and clinozoisite (0.40 Fe_tot pfu) were investigated by single-crystal X-ray diffraction and Raman spectroscopy. The lattice parameters of both phases exhibit continuous compression behavior up to 30 GPa without evidence of phase transformation. Pressure–volume data for both phases were fitted to a third-order Birch–Murnaghan equation of state with V ₀ = 461.1(1) ų, K ₀ = 115(2) GPa, and \(K_{0}^{'}\) = 3.7(2) for epidote and V ₀ = 457.8(1) ų, K ₀ = 142(3) GPa, and \(K_{0}^{'}\) = 5.2(4) for clinozoisite. In both epidote and clinozoisite, the b-axis is the stiffest direction, and the ratios of axial compressibility are 1.19:1.00:1.15 for epidote and 1.82:1.00:1.19 for clinozoisite. Whereas the compressibility of the a-axis is nearly the same for both phases, the b- and c-axes of the epidote are about 1.5 times more compressible than in clinozoisite, consistent with epidote having a lower bulk modulus. Raman spectra collected up to 40.4 GPa also show no indication of phase transformation and were used to obtain mode Grüneisen parameters (γ _i) for Si–O vibrations, which were found to be 0.5–0.8, typical for hydrous silicate minerals. The average pressure coefficient of Raman frequency shifts for M–O modes in epidote, 2.61(6) cm^?1/GPa, is larger than found for clinozoisite, 2.40(6) cm^?1/GPa, mainly due to the different compressibility of FeO₆ and AlO₆ octahedra in M3 sites. Epidote and clinozoisite contain about 2 wt% H₂O are thus potentially important carriers of water in subducted slabs.