Anomalous variations in the structure of the ionospheric <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript> region at geomagnetic midlatitudes of the Southern and Northern hemispheres in going from summer to winter conditions at high solar activity

The structure and dynamics of the ionosphere and plasmasphere at high solar activity under quiet geomagnetic conditions of June 2–3, 1979, and January 5–6, 1980, over Millstone Hill station and Argentine Islands ionosonde, the locations of which are approximately magnetically conjugate, have been theoretically calculated. The plasma drift velocity, determined by comparing the calculated and measured heights of the F ₂ layer maximum (hmF2), and the correction of [N₂] and [O₂], found in the NRLMSISE-00 model, make it possible to coordinate the electron densities (NmF2) calculated at the hmF2 height and the measured anomalous variations in NmF2 over the Argentine Islands ionosonde as well as the calculated and measured NmF2 and electron temperature at the hmF2 height over Millstone Hill station. It has been shown that, if the interference of the diffusion velocities of O⁺(⁴S) and H⁺ ions is taken into account, the additional heating of plasmaspheric electrons leads to an increase in the flux of O⁺(⁴S) ions from the topside ionosphere to lower F ₂ layer altitudes, as a result of which an anomalous nighttime increase in NmF2 6, observed on January 6, 1980, over Millstone Hill station, is mainly produced. The second component of the formation of anomalous night-time NmF2 is the plasma drift along the magnetic field caused by the neutral wind, which shifts O⁺(⁴S) ions to higher altitudes where the recombination rate of O⁺(⁴S) with N₂ and O₂ is lower and slows down a decrease in NmF2 in the course of time. It has been shown that the influence of electronically excited O⁺ ions and vibrationally excited N₂ and O₂ molecules on electron density (N _e ) considerably differs under winter and summer conditions. This difference forms significant part of the winter anomaly in N _e at heights of the F ₂ region and topside ionosphere over Millstone Hill station.     

Anomalous variations in the ionospheric <Emphasis Type="Italic">F</Emphasis><Subscript>2</Subscript>-layer structure at geomagnetic midlatitudes of the Southern and Northern hemispheres at the transition from summer to winter conditions under low solar activity

The structure and dynamics of the ionosphere and plasmasphere at low solar activity under quiet geomagnetic conditions on January 15–17, 1985, and July 10–13, 1986, over Millstone Hill station and Argentine Islands ionosonde, the locations of which are approximately magnetically conjugate, have been theoretically calculated. The detected correction of the model input parameters makes it possible to coordinate the measured and calculated anomalous variations in the electron density NmF2 at the height hmF2 of the ionospheric F2 layer over Argentine Islands ionosonde as well as the calculated and measured values of NmF2 and electron temperature at the hmF2 height over Millstone Hill station. It has been shown that vibrationally excited N₂ and O₂ molecules almost do not influence the formation of the winter anomaly under the conditions of low solar activity. A difference between the influence of electronically excited O⁺ on N _e ions under winter and summer conditions forms not more than 11% of the N _e winter anomaly event in the F ₂ layer and topside ionosphere. The model without electronically excited O⁺ ions reduces the duration of the N _e winter anomaly event. It has been shown that the seasonal variations in the composition of the neutral atmosphere form mainly the NmF2 winter anomaly event over the Millstone Hill radar at low solar activity.     

Long-term changes in the relation between <Emphasis Type="Italic">foF</Emphasis>2 and <Emphasis Type="Italic">hmF</Emphasis>2

The change in the dependence of the F2-layer critical frequency on its height hmF2 is considered based on two sources of initial data used earlier by the authors. It is found that the slope k of the foF2 dependence on hmF2 systematically decreases from the earlier (“etalon”) period, 1958–1980, to the later periods of 1988–2010, 1998–2010, and 1998–2014. Since the foF2 value depends on the atomic oxygen concentration in the F region much more strongly than hmF2, the found decrease in k confirms the concept of a decrease in the atomic oxygen concentration in the thermosphere with time previously formulated by the authors.     

Effect of zonal E × B plasma drift on electron density in the low-latitude ionospheric <Emphasis Type="Italic">F</Emphasis> region at a solar activity maximum near vernal equinox

The variations in the density of the ionospheric F2 layer maximum (NmF2) under the action of the zonal plasma drift perpendicularly to the magnetic (B) and electric (E) fields in the direction geomagnetic west-geomagnetic east have been studied using the three-dimensional nonstationary theoretical model of electron and ion densities (N _e and N _i ) and temperatures (T _e and T _i ) in the low-latitude and midlatitude ionospheric F region and plasmasphere. The method of numerical calculations of N _e , N _i , T _e , and T _i , including the advantages of the Lagrangian and Eulerian methods, is used in the model. A dipole approximation of the geomagnetic field (B), taking into account the non-coincidence of the geographic and geomagnetic poles and differences between the positions of the Earth’s and geomagnetic dipole centers, is accepted in the calculations. The calculated NmF2 and altitudes of the F2 layer maximum (hmF2) have been compared with these quantities measured at 16 low-latitude ionospheric sounding stations during the geomagnetically quiet period October 11–12, 1958. This comparison made it possible to correct the input model parameters: the NRLMSISE-00 model [O], the meridional component of the neutral wind velocity according to the HWW90 model, and the meridional component of the equatorial plasma drift due to the electric field specified by the empirical model. It has been indicated that the effect of the zonal E × B plasma drift on NmF2 can be neglected under daytime conditions and changes in NmF2 and hmF2 under the action of this drift are insignificant under nighttime conditions north of 25° and south of ?26° geomagnetic latitude. The effect of the zonal E × B plasma drift on NmF2 and hmF2 is most substantial in the nightside ionosphere approximately from ?20° to 20° geomagnetic latitude, and the neglect of this drift results in an up to 2.4-fold underestimation of NmF2. The found dependence of the effect of the zonal E × B plasma drift on NmF2 and hmF2 on geomagnetic latitude is related to the longitudinal asymmetry of B, asymmetry of the neutral wind about the geomagnetic equator, and changes in the meridional E × B plasma drift at a change in geomagnetic longitude.     

Properties of solar activity and ionosphere for solar cycle 25

Based on the known forecast of solar cycle 25 amplitude (Rz _max ≈ 50), the first assessments of the shape and amplitude of this cycle in the index of solar activity F10.7 (the magnitude of solar radio flux at the 10.7 cm wavelength) are given. It has been found that (F10.7)_max ≈ 115, which means that it is the lowest solar cycle ever encountered in the history of regular ionospheric measurements. For this reason, many ionospheric parameters for cycle 25, including the F2-layer peak height and critical frequency (hmF2 and foF2), will be extremely low. For example, at middle latitudes, typical foF2 values will not exceed 8–10 MHz, which makes ionospheric heating ineffective in the area of upper hybrid resonance at frequencies higher than 10 MHz. The density of the atmosphere will also be extremely low, which significantly extends the lifetime of low-orbit satellites. The probability of F-spread will be increased, especially during night hours.     

Behavior of Parameters of Enhancements in the Nighttime Electron Concentration in the Ionospheric <Emphasis Type="Italic">F</Emphasis>2 Layer

We have analyzed the behavior of the F2 layer parameters during nighttime periods of enhanced electron concentration by the results of vertical sounding of the ionosphere carried out with five-minute periodicity in Almaty (76°55′ E, 43°15′ N) in 2001–2012. The results are obtained within the frameworks of the unified concept of different types of ionospheric plasma disturbances manifested as variations in the height and half-thickness of the layer accompanied by an increase and decrease of N _m F2 at the moments of maximum compression and expansion of the layer. A good correlation is found between height h _Am , which corresponds to the maximum increase, and layer peak height h _m F, while h _Am is always less than h _m F. The difference between h _Am and h _m F linearly increases with increasing h _m F. Whereas the difference is ~38 km for h _m F = 280 km, it is ~54 km for h _m F = 380 km. Additionally, the correlation is good between the increase in the electron concentration in the layer maximum ΔN _m and the maximum enhancement at the fixed height ΔN; the electron concentration enhancement in the layer maximum is about two to three times lower than its maximum enhancement at the fixed height.     

Precursor times of abnormal <Emphasis Type="Italic">b</Emphasis>-values prior to mainshocks

Seismic observations exhibit the presence of abnormal b-values prior to numerous earthquakes. The time interval from the appearance of abnormal b-values to the occurrence of mainshock is called the precursor time. There are two kinds of precursor times in use: the first one denoted by T is the time interval from the moment when the b-value starts to increase from the normal one to the abnormal one to the occurrence time of the forthcoming mainshock, and the second one denoted by T _p is the time interval from the moment when the abnormal b-value reaches the peak one to the occurrence time of the forthcoming mainshock. Let T* be the waiting time from the moment when the abnormal b-value returned to the normal one to the occurrence time of the forthcoming mainshock. The precursor time, T (usually in days), has been found to be related to the magnitude, M, of the mainshock expected in a linear form as log(T)?=?q?+?rM where q and r are the coefficient and slope, respectively. In this study, the values of T, T _p , and T* of 45 earthquakes with 3?≤?M?≤?9 occurred in various tectonic regions are compiled from or measured from the temporal variations in b-values given in numerous source materials. The relationships of T and T _p , respectively, versus M are inferred from compiled data. The difference between the values of T and T _p decreases with increasing M. In addition, the plots of T*/T versus M, T* versus T, and T* versus T-T* will be made and related equations between two quantities will be inferred from given data.     

Dependence of geomagnetic disturbances on extreme values of the solar wind <Emphasis Type="Italic">E</Emphasis><Subscript><Emphasis Type="Italic">y</Emphasis></Subscript> component

The dependence of the zonal geomagnetic indices (AE, Ap, Kp, Kn, and Dst) on the solar wind parameters (the electric field E _y component, dynamic pressure P _d and IMF irregularity σB) has been studied for two types of events: magnetic clouds and high-speed streams. Based on the empirical relationships, it has been established that the AE, Ap, Kp, and Kn indices are directly proportional to the E _y value at E _y < 12 mV m^?1 and are inversely proportional to this value at E _y > 12 mV m^?1 for the first-type events. On the contrary, the dependence of Dst on E _y is monotonous nonlinear. A linear dependence of all geomagnetic indices on E _y is typical of the second-type events. It has been indicated that the specific features of geoeffectiveness of magnetic clouds and high-speed solar wind streams are caused by the dependence of the electric field potential across the polar cap on the electric field, solar wind dynamic pressure, and IMF fluctuations.     

Dynamics of the midlatitude ionospheric <Emphasis Type="Italic">F</Emphasis> region at sunrise

The behavior of the F2 layer at sunrise has been studied based on vertical-incidence ionospheric sounding data in Almaty (76°55′E, 43°15′N). Records with small amplitudes of electron density background fluctuations were selected in order to exactly estimate the onsets of a pronounced increase in the electron density at different altitudes. It has been indicated that the electron density growth rate is a function of altitude; in this case, the growth rate at the F2 layer maximum is much lower than such values at fixed altitudes of ～30–55 km below the layer maximum. The solar zenith angle (χ) and the blanketing layer thickness (h ₀) at the beginning of a pronounced increase in the electron density at altitude h are linearly related to the h value, and these quantities vary within ～90° < χ < 100° and 180 km < h ₀ < 260 km, respectively.     

Sampling uncertainties and source <Emphasis Type="Italic">b</Emphasis> likelihood for the Gutenberg-Richter <Emphasis Type="Italic">b</Emphasis> value from the Aki-Utsu method

The Aki-Utsu method of Gutenberg-Richter (G-R) b value estimation is often misapplied so that estimations not using the G-R histogram are often meaningless because they are not based on adequate samples. We propose a method to estimate the likelihood Pr(b?b _m , N, M ₁, M ₂) that an observed b _m estimate, based on a sample of N magnitudes within an [M ₁????≤?ΔM/2,?M ₂?+?ΔM/2) range, where ΔM?=?0.1 is the usual rounding applied to magnitudes, is due to a “true” source b value, b, and use these likelihoods to estimate source b ranges corresponding to various confidence levels. As an example of application of the method, we estimate the b values before and after the occurrence of a 7.4-magnitude earthquake in the Mexican subduction zone, and find a difference of 0.82 between them with 100% confidence that the b values are different.     

Attenuation coefficients of Rayleigh and <Emphasis Type="Italic">Lg</Emphasis> waves

Analysis of the frequency dependence of the attenuation coefficient leads to significant changes in interpretation of seismic attenuation data. Here, several published surface-wave attenuation studies are revisited from a uniform viewpoint of the temporal attenuation coefficient, denoted by χ. Theoretically, χ( f) is expected to be linear in frequency, with a generally non-zero intercept γ?=?χ(0) related to the variations of geometrical spreading, and slope dχ/df = π/Q _e caused by the effective attenuation of the medium. This phenomenological model allows a simple classification of χ( f) dependences as combinations of linear segments within several frequency bands. Such linear patterns are indeed observed for Rayleigh waves at 500–100-s and 100–10-s periods, and also for Lg from ~2 s to ~1.5 Hz. The Lg χ( f) branch overlaps with similar linear branches of body, Pn, and coda waves, which were described earlier and extend to ~100 Hz. For surface waves shorter than ~100 s, γ values recorded in areas of stable and active tectonics are separated by the levels of \(\gamma _{D} \approx 0.2 \times 10^{-3}\) s^???1 (for Rayleigh waves) and 8 ×10^???3 s^???1 (for Lg). The recently recognized discrepancy between the values of Q measured from long-period surface waves and normal-mode oscillations could also be explained by a slight positive bias in the geometrical spreading of surface waves. Similarly to the apparent χ, the corresponding linear variation with frequency is inferred for the intrinsic attenuation coefficient, χ _i , which combines the effects of geometrical spreading and dissipation within the medium. Frequency-dependent rheological or scattering Q is not required for explaining any of the attenuation observations considered in this study. The often-interpreted increase of Q with frequency may be apparent and caused by using the Q-based model of attenuation and following preferred Q( f) dependences while ignoring the true χ( f) trends within the individual frequency bands.     

Estimation of storm-time level of day-side wave geomagnetic activity using a new <Emphasis Type="Italic">ULF</Emphasis> index

The level of wave geomagnetic activity in the morning and daytime sectors of auroral latitudes during strong magnetic storms with Dst _min varying from ?100 to ?150 nT in 1995–2002 have been studied using a new ULF index of wave activity proposed in [Kozyreva et al., 2007]. It has been detected that daytime Pc5 pulsations (2–6 mHz) are most intense during the main phase of a magnetic storm rather than during the recovery phase as was considered previously. It has been indicated that morning geomagnetic pulsations during the substorm recovery phase mainly contribute to daytime wave activity. The appearance of individual intervals with the southward IMF B _z component during the magnetic storm recovery phase results in increases in the ULF index values.     

Differential physiological responses of the coastal cyanobacterium <Emphasis Type="Italic">Synechococcus</Emphasis> sp. PCC7002 to elevated <Emphasis Type="Italic">p</Emphasis>CO<Subscript>2</Subscript> at lag,exponential, and stationary growth phases

We studied the effects of expected end-of-the-century pCO₂ (1000 ppm) on the photosynthetic performance of a coastal marine cyanobacterium Synechococcus sp. PCC7002 during the lag, exponential, and stationary growth phases. Elevated pCO₂ significantly stimulated growth, and enhanced the maximum cell density during the stationary phase. Under ambient pCO₂ conditions, the lag phase lasted for 6 days, while elevated pCO₂ shortened the lag phase to two days and extended the exponential phase by four days. The elevated pCO₂ increased photosynthesis levels during the lag and exponential phases, but reduced them during the stationary phase. Moreover, the elevated pCO₂ reduced the saturated growth light (Ik) and increased the light utilization efficiency (α) during the exponential and stationary phases, and elevated the phycobilisome:chlorophyll a (Chl a) ratio. Furthermore, the elevated pCO₂ reduced the particulate organic carbon (POC):Chl a and particulate organic nitrogen (PON):Chl a ratios during the lag and stationary phases, but enhanced them during the exponential phase. Overall, Synechococcus showed differential physiological responses to elevated pCO₂ during different growth phases, thus providing insight into previous studies that focused on only the exponential phase, which may have biased the results relative to the effects of elevated pCO₂ in ecology or aquaculture.     

Magnitude <Emphasis Type="Italic">M</Emphasis><Subscript>w</Subscript> in metropolitan France

The recent seismicity catalogue of metropolitan France Sismicité Instrumentale de l’Hexagone (SI-Hex) covers the period 1962–2009. It is the outcome of a multipartner project conducted between 2010 and 2013. In this catalogue, moment magnitudes (M _w) are mainly determined from short-period velocimetric records, the same records as those used by the Laboratoire de Détection Géophysique (LDG) for issuing local magnitudes (M _L) since 1962. Two distinct procedures are used, whether M _L-LDG is larger or smaller than 4. For M _L-LDG >4, M _w is computed by fitting the coda-wave amplitude on the raw records. Station corrections and regional properties of coda-wave attenuation are taken into account in the computations. For M _L-LDG ≤4, M _w is converted from M _L-LDG through linear regression rules. In the smallest magnitude range M _L-LDG <3.1, special attention is paid to the non-unity slope of the relation between the local magnitudes and M _w. All M _w determined during the SI-Hex project is calibrated according to reference M _w of recent events. As for some small events, no M _L-LDG has been determined; local magnitudes issued by other French networks or LDG duration magnitude (M _D) are first converted into M _L-LDG before applying the conversion rules. This paper shows how the different sources of information and the different magnitude ranges are combined in order to determine an unbiased set of M _w for the whole 38,027 events of the catalogue.     

Critical frequencies <Emphasis Type="Italic">foF</Emphasis>2 as an indicator of trends in thermospheric dynamics

The time variations in three parameters during the last decades are considered. R(foF2) is the correlation coefficient between the nighttime and daytime values of foF2 for the same day. Stable trends are found for the minimum (R(foF2)(max)) and maximum (R(foF2)(min)) values of R(foF2) during a year. The foF2(night)/foF2(day) ratio demonstrates both, negative and positive trends, and the trend sign depends on the inclination I and declination D of the magnetic field. The correlation coefficient r(h, fo) between foF2 and the 100 hP level in the stratosphere demonstrates a decrease (in the years of maximum and minimum solar activity) from the 1980s to the 1990s. The trends in all three groups of data are considered under the assumption of long-term changes in the circulation in the upper atmosphere.     

Increase in the critical frequency of the ionospheric <Emphasis Type="Italic">F</Emphasis> region prior to the substorm expansion phase

Specific variations in the critical frequency of the ionospheric F ₂ layer during magnetospheric substorms have been found based on the data of vertical sounding stations in Europe and North America. Maximal attention has been paid to the positive peaks of ΔfoF2 with a duration of 6–8 h before the beginning of the substorm expansion phase (T ₀). The possible physical mechanisms by which these peaks are formed (related to the impact of fast particles in the foreshock region of the solar wind on the Earth’s magnetosphere and different for middle and high latitudes) have been considered. The positive peaks of ΔfoF2 can be used in a short-term prediction of the ionospheric disturbance onset and space weather on the whole.     

A study of Guptkashi,Uttarakhand earthquake of 6 February 2017 (<Emphasis Type="Italic">M</Emphasis><Subscript><Emphasis Type="Italic">w</Emphasis></Subscript>5.3) in the Himalayan arc and implications for ground motion estimation

The 2017 Guptkashi earthquake occurred in a segment of the Himalayan arc with high potential for a strong earthquake in the near future. In this context, a careful analysis of the earthquake is important as it may shed light on source and ground motion characteristics during future earthquakes. Using the earthquake recording on a single broadband strong-motion seismograph installed at the epicenter, we estimate the earthquake’s location (30.546° N, 79.063° E), depth (H?=?19 km), the seismic moment (M₀?=?1.12×10¹⁷ Nm, M _w 5.3), the focal mechanism (φ?=?280°, δ?=?14°, λ?=?84°), the source radius (a?=?1.3 km), and the static stress drop (Δσ _s ~22 MPa). The event occurred just above the Main Himalayan Thrust. S-wave spectra of the earthquake at hard sites in the arc are well approximated (assuming ω^?2 source model) by attenuation parameters Q(f)?=?500f^0.9, κ?=?0.04 s, and f_max?=?infinite, and a stress drop of Δσ?=?70 MPa. Observed and computed peak ground motions, using stochastic method along with parameters inferred from spectral analysis, agree well with each other. These attenuation parameters are also reasonable for the observed spectra and/or peak ground motion parameters in the arc at distances ≤?200 km during five other earthquakes in the region (4.6?≤?M _w ?≤?6.9). The estimated stress drop of the six events ranges from 20 to 120 MPa. Our analysis suggests that attenuation parameters given above may be used for ground motion estimation at hard sites in the Himalayan arc via the stochastic method.     

<Emphasis Type="Italic">Q</Emphasis><Subscript>c</Subscript> and <Emphasis Type="Italic">Q</Emphasis><Subscript>S</Subscript> wave attenuation of South African earthquakes

Quality factor Q, which describes the attenuation of seismic waves with distance, was determined for South Africa using data recorded by the South African National Seismograph Network. Because of an objective paucity of seismicity in South Africa and modernisation of the seismograph network only in 2007, I carried out a coda wave decay analysis on only 13 tectonic earthquakes and 7 mine-related events for the magnitude range 3.6?≤?M _L ?≤?4.4. Up to five seismograph stations were utilised to determine Q _c for frequencies at 2, 4, 8 and 16 Hz resulting in 84 individual measurements. The constants Q ₀ and α were determined for the attenuation relation Q _c(f)?=?Q ₀ f ^α . The result was Q ₀?=?396?±?29 and α?=?0.72?±?0.04 for a lapse time of 1.9*(t _s???t ₀) (time from origin time t ₀ to the start of coda analysis window is 1.9 times the S-travel time, t _s) and a coda window length of 80 s. This lapse time and coda window length were found to fit the most individual frequencies for a signal-to-noise ratio of at least 3 and a minimum absolute correlation coefficient for the envelope of 0.5. For a positive correlation coefficient, the envelope amplitude increases with time and Q _c was not calculated. The derived Q _c was verified using the spectral ratio method on a smaller data set consisting of nine earthquakes and one mine-related event recorded by up to four seismograph stations. Since the spectral ratio method requires absolute amplitudes in its calculations, site response tests were performed to select four appropriate stations without soil amplification and/or signal distortion. The result obtained for Q _S was Q ₀?=?391?±?130 and α?=?0.60?±?0.16, which agrees well with the coda Q _c result.     

A new <Emphasis Type="Italic">M</Emphasis><Subscript><Emphasis Type="Italic">w</Emphasis></Subscript> estimation parameter for use in earthquake early warning systems

We propose a method that employs the squared displacement integral (ID2) to estimate earthquake magnitudes in real time for use in earthquake early warning (EEW) systems. Moreover, using τ _c and P _d for comparison, we establish formulas for estimating the moment magnitudes of these three parameters based on the selected aftershocks (4.0 ≤ M _s  ≤ 6.5) of the 2008 Wenchuan earthquake. In this comparison, the proposed ID2 method displays the highest accuracy. Furthermore, we investigate the applicability of the initial parameters to large earthquakes by estimating the magnitude of the Wenchuan M _s 8.0 mainshock using a 3-s time window. Although these three parameters all display problems with saturation, the proposed ID2 parameter is relatively accurate. The evolutionary estimation of ID2 as a function of the time window shows that the estimation equation established with ID2 ^Ref determined from the first 8-s of P wave data can be directly applicable to predicate the magnitudes of 8.0. Therefore, the proposed ID2 parameter provides a robust estimator of earthquake moment magnitudes and can be used for EEW purposes.     

Solubilities of metallic sulfides and quartz in hydrothermal sulfide solutions

Thermal waters contain small amounts of dissolved sulfides which in places precipitate at or near the earth’s surface. Knowledge of the physical chemistry of hydrothermal solutions is needed at elevated temperatures and pressures. Therefore, solubilities of the epithermal minerals cinnabar, stibnite, quartz, and orpiment in aqueousNa ₂ S solutions was determined from 25–250° C, 1–2000 bars, and at severalNa ₂ S concentrations. All the minerals are appreciably soluble inNa ₂ S solutions. Pressure increase decreases solubilities of metallic sulfides but slightly increases quartz solubility. Temperature increase causes increased solubility at temperatures above 150° C, but at lower temperatures, cinnabar, orpiment and quartz show solubility decreases with increasing temperatures. Quartz and cinnabar are mutually soluble, but in the presence of stibnite only a small amount of cinnabar dissolves. The second ionization constant ofH ₂ S as calculated from the solubility data ranges from 10^?16,21 at 0°C to 10^?12,59 at 250°C. TheK ₂ ofH ₂ S is lower according to this study than any reported before, and the variation with temperature is several orders of magnitude greater than had been predicted.