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1.
Mohsen Chekani Moghadam Zahra Tahmasbi Ahmad Ahmadi-Khalaji José Francisco Santos 《Chemie der Erde / Geochemistry》2018,78(1):58-77
The Urumieh-Dokhtar magmatic arc (UDMA) of Central Iran has been formed during Neotethyan Ocean subduction underneath Eurasia. The Rabor-Lalehzar magmatic complex (RLMC), covers an area ~1000?km2 in the Kerman magmatic belt (KMB), SE of UDMA. RLMC magmatic rocks include both granitoids and volcanic rocks with calc-alkaline and adakitic signatures but with different ages.Miocene adakitic rocks are characterd by relatively enrichmented in incompatible elements, high (Sr/Y)(N) (>40), and (La/Yb)(N) (>10) ratios with slightly negative Eu anomalies (EuN/Eu*≈ 0.9), depletion in HFSEs, and relatively non-radiogenic Sr isotope signatures (87Sr/86Sr?=?0.7048–0.7049). In contrast, the Oligocene granitoids exhibit low Sr/Y (<20) and La/Yb (<9) ratios, negative Eu anomalies (EuN/Eu*?≈?0.5), and enrichment in HFSEs and radiogenic Sr isotope signatures (87Sr/86Sr?=?0.7050–0.7052), showing affinity to the island arc rocks. Eocene volcanic rocks which crusscut the younger granitoid rocks comprise andesites and dacites. Geochemically, lavas show calc-alkaline character without any Eu anomaly (EuN/Eu*?≈?1.0). Based on the geochemical and isotopic data we propose that melt source for both calc-alkaline and adakitic rocks from the RLMC can be related to the melting of a sub-continental lithospheric mantle (SCLM). Basaltic melts derived from a metasomatized mantle wedge might be emplaced at the mantle-crust boundary and formed the juvenile mafic lower crust. However, some melts fractionated in the shallow magma chambers and continued to rise forming the volcanic intermediate-mafic rocks at the surface. On the other hand, the assimilation and fractional crystallization in the shallow magma chambers of may have been responsible for the development of Oligocene granitoids with calc-alkaline affinity. In the mid-Late Miocene, following the collision between Afro-Arabia and Iranian block the juvenile mafic crust of UDMA underwent thickening and metamorphosed into garnet-amphibolites. Subsequent upwelling of a hot asthenosphere during Miocene was responsible for partial melting of thickened juvenile crust of the SE UDMA (RLM complex). The adakitic melts ascended to the shallow crust to form the adakitic rocks in the KMB. 相似文献
2.
L. Melluso S. F. Sethna M. D’Antonio P. Javeri L. Bennio 《Mineralogy and Petrology》2002,74(2-4):323-342
Summary Major element, trace element, Sr- and Nd-isotopes and mineral chemical data are reported for alkaline rocks (lamprophyres,
tephrites, melanephelinites, nephelinites and nepheline syenites) cross-cutting the Deccan Trap lava flows south (Murud-Janjira
area) and north of Mumbai (Bassein). These rocks range from sodic to potassic and have a large span in MgO (12–2 wt%). The
lamprophyres have high content of incompatible elements (e.g., TiO2 > 3.8 wt%, Nb > 130 ppm, Zr > 380 ppm, Ba > 1200 ppm), and relatively high initial (at 65 Ma) 143Nd/144Nd (0.5128) and low 87Sr/86Sr (0.7038–0.7042). They are likely to be small-degree melts (2–3%) of volatile- and incompatible element-enriched mantle
sources, similar to other alkaline rocks in the northern Deccan, though slightly more potassium-rich. The nepheline-rich rocks
have highly porphyritic textures (up to 57% phenocrysts of diopside ± olivine), and anomalously low contents of incompatible
elements (e.g., TiO2 < 1.3 wt%, Nb < 24 ppm, Zr < 100 ppm) indicating that they could not represent liquid compositions. Moreover, their very
low initial 143Nd/144Nd ratios (0.5116–0.5120), at 87Sr/86Sr = 0.7045–0.7049, are unusual in the rocks related to the Deccan Traps and identify a new end-member in this province, that
could be identified as “Lewisian-type” lower crust and/or enriched mantle. The melting episode that generated these alkaline
rocks likely occurred close to the base of the ca. 100 km-thick Indian lithosphere, very shortly after the main eruption of
the Deccan tholeiites.
Received January 14, 2000; revised version accepted September 28, 2001 相似文献
3.
Geochemical signature of porphyries in the Baogutu porphyry copper belt, western Junggar, NW China 总被引:11,自引:0,他引:11
Ping Shen Yuanchao Shen Tiebing Liu Lei Meng Huawu Dai Yueheng Yang 《Gondwana Research》2009,16(2):227
The Baogutu porphyry copper belt lies in the Darbut transitional island arc of the western Junggar, in the western section of the Central Asian Orogenic Belt in NW China. Our new petrographic results for the ore-bearing porphyry stocks in the Baogutu porphyry copper belt recognize them as diorite porphyry stocks rather than the granodiorite porphyry stocks as previously identified. The copper mineralization is hosted in the diorite, diorite porphyries and related breccias of the diorite porphyry stocks.Geochemical data indicate that the ore-bearing porphyries have a predominantly intermediate composition with a transitional character from tholeiite to calc-alkaline, and are enriched in large ion lithophile elements (LILE) and depleted in high field strength elements (HFSE) with a clear negative Nb anomaly. REE patterns show distinct enrichments in LREE relative to HREE. The rocks also exhibit high initial εNd(t) (+ 2.7 to + 6.3) ratios and low initial 87Sr/86Sr values (0.70359–0.70397). Many samples are chemically similar to adakites (e. g. Yb < 1.9 ppm, Y < 18 ppm, Sr/Yb > 20, 87Sr/86Sr < 0.7045). These data are consistent with a transitional island arc from immature arc to mature arc and suggest that the ore-bearing porphyry system was derived from the partial melting of multiple sources including oceanic crust and a subduction-modified mantle wedge, with melts undergoing significant crystal fractionation during convergence between the paleo-Junggar ocean and the Darbut arc. 相似文献
4.
Garnet-bearing tonalitic porphyry from East Kunlun,Northeast Tibetan Plateau: implications for adakite and magmas from the MASH Zone 总被引:7,自引:0,他引:7
Chao Yuan Min Sun Wenjiao Xiao Simon Wilde Xianhua Li Xiaohan Liu Xiaoping Long Xiaoping Xia Kai Ye Jiliang Li 《International Journal of Earth Sciences》2009,98(6):1489-1510
A garnet-bearing tonalitic porphyry from the Achiq Kol area, northeast Tibetan Plateau has been dated by SHRIMP U-Pb zircon
techniques and gives a Late Triassic age of 213 ± 3 Ma. The porphyry contains phenocrysts of Ca-rich, Mn-poor garnet (CaO > 5 wt%;
MnO < 3 wt%), Al-rich hornblende (Al2O3 ~ 15.9 wt%), plagioclase and quartz, and pressure estimates for hornblende enclosing the garnet phenocrysts yield values
of 8–10 kbar, indicating a minimum pressure for the garnet. The rock has SiO2 of 60–63 wt%, low MgO (<2.0 wt%), K2O (<1.3 wt%), but high Al2O3 (>17 wt%) contents, and is metaluminous to slightly peraluminous (ACNK = 0.89–1.05). The rock samples are enriched in LILE
and LREE but depleted in Nb and Ti, showing typical features of subduction-related magmas. The relatively high Sr/Y (~38)
ratios and low HREE (Yb < 0.8 ppm) contents suggest that garnet is a residual phase, while suppressed crystallization of plagioclase
and lack of negative Eu anomalies indicate a high water fugacity in the magma. Nd–Sr isotope compositions of the rock (εNdT = −1.38 to −2.33; 87Sr/86Sri = 0.7065–0.7067) suggest that both mantle- and crust-derived materials were involved in the petrogenesis, which is consistent
with the reverse compositional zoning of plagioclase, interpreted to indicate magma mixing. Both garnet phenocrysts and their
ilmenite inclusions contain low MgO contents which, in combination with the oxygen isotope composition of garnet separates
(+6.23‰), suggests that these minerals formed in a lower crust-derived felsic melt probably in the MASH zone. Although the
rock samples are similar to adakitic rocks in many aspects, their moderate Sr contents (<260 ppm) and La/Yb ratios (mostly
16–21) are significantly lower than those of adakitic rocks. Because of high partition coefficients for Sr and LREE, fractionation
of apatite at an early stage in the evolution of the magma may have effectively decreased both Sr and LREE in the residual
melt. It is suggested that extensive crystallization of apatite as an early phase may prevent some arc magmas from evolving
into adakitic rocks even under high water fugacity. 相似文献
5.
The Pleistocene Incapillo Caldera and Dome Complex (5,570 m) marks the southernmost siliceous center of the Andean Central
Volcanic Zone (~28°S), where the steeply dipping (~30°) segment of the subducting Nazca plate transitions into the Chilean
“flatslab” to the south. The eruption of the Incapillo Caldera and Dome Complex began with a 3–1 Ma effusive phase characterized
by ~40 rhyodacitic dome eruptions. This effusive phase was terminated by an explosive “caldera-forming” event at 0.51 Ma that
produced the 14 km3 Incapillo ignimbrite. Distinctive and virtually identical chemical signatures of the domes and ignimbrites (SiO2 = 67–72 wt%; La/Yb = 37–56; Ba/La = 16–28; La/Ta = 30–50; 87Sr/86Sr = 0.70638–0.70669; ε
Nd = −4.2 to −4.6) indicate that all erupted lavas originated from the same magma chamber and that differentiation effects between
units were minor. The strong HREE depletion (Sm/Yb = 6–8) that distinguishes Incapillo magmas from most of the large ignimbrites
of the Altiplano–Puna plateau can be explained by the extent and degree of partial melting at lower crustal depths (>40 km)
in the presence of garnet. At upper crustal depths, this high-pressure residual geochemical signature, also common to adjacent
late Miocene/Pliocene Pircas Negras andesites, was partially overprinted by shallow-level assimilation and fractional crystallization
processes. Energy-constrained AFC modeling suggests that incorporation of anatectic upper crustal melts into a fractionated
“adakite-like” dacitic host best explains the petrogenesis of Incapillo magmas. The diminution of the sub-arc asthenospheric
wedge during Nazca plate shallowing left the Incapillo magma chamber unreplenished by both mafic mantle-derived and lower
crustal melts and thus stranded at shallow depths within the Andean crust. Based on its small size and distinctive high-pressure
chemical signature, the Incapillo Caldera and Dome Complex provides an endmember model for an Andean caldera erupting within
a waning magmatic arc over a shallowing subduction zone. 相似文献
6.
Jian-Wei Li Xin-Fu Zhao Mei-Fu Zhou Chang-Qian Ma Zorano Sérgio de Souza Paulo Vasconcelos 《Contributions to Mineralogy and Petrology》2009,157(3):383-409
Late Mesozoic dioritic and quartz dioritic plutons are widespread in the Daye region, eastern Yangtze craton, eastern China.
Detailed geochronological, geochemical, and Sr–Nd isotopic studies have been undertaken for most of these plutons, in an attempt
to provide a comprehensive understanding in the age, genesis and geodynamical control of the extensive magmatism. SHRIMP and
LA-ICP-MS zircon U–Pb dating indicate that the plutons were emplaced in the range of latest Jurassic (ca. 152 Ma) to early
Cretaceous (ca. 132 Ma), which was followed by dyke emplacement between 127 and 121 Ma and volcanism during the 130–113 Ma
interval. Both diorites and quartz diorites are sodic, metaluminous, high-K calc-alkaline, and characterized by strongly fractionated,
sub-parallel REE patterns without obvious Eu anomalies. The rocks are enriched in highly incompatible elements and large ion
lithophile elements, but depleted in high field strength elements. Samples of diorite and quartz diorite have similar Sr–Nd
isotopic compositions that are consistent with the early Cretaceous basalts and mafic intrusions throughout the eastern Yangtze
craton. The geochemical and isotopic data, together with results of geochemical modeling, indicate an enriched mantle source
for the plutonic rocks. The quartz diorites have geochemical signatures resembling adakites, such as high Al2O3 (15–19 wt.%), Sr (630–2,080 ppm), Na2O (>3.5 wt.%), negative Nb–Ta anomalies, low Y (7–19 ppm), Yb (0.5–1.8 ppm), Sc (5–15 ppm), and resultant high Sr/Y (45–200)
and La/Yb (31–63) ratios. Genesis of the adakitic quartz diorites is best explained in terms of low-pressure intracrustal
fractional crystallization of cumulates consisting of hornblende, plagioclase, K-feldspar, magnetite, and apatite from mantle-derived
dioritic magmas. Mantle-derived magmatism broadly coeval with that of the Daye region also is widespread in other regions
of the eastern Yangtze craton, reflecting large-scale melting of the lithospheric mantle during the Late Mesozoic. The large-scale
magmatism was most likely driven by lithospheric extension associated with thinning of lithospheric mantle beneath the eastern
China continent. 相似文献
7.
Jiang-Feng Qin Shao-Cong Lai Chun-Rong Diwu Yin-Juan Ju Yong-Fei Li 《Contributions to Mineralogy and Petrology》2010,159(3):389-409
Petrogenesis of high Mg# adakitic rocks in intracontinental settings is still a matter of debate. This paper reports major
and trace element, whole-rock Sr–Nd isotope, zircon U–Pb and Hf isotope data for a suite of adakitic monzogranite and its
mafic microgranular enclaves (MMEs) at Yangba in the northwestern margin of the South China Block. These geochemical data
suggest that magma mixing between felsic adakitic magma derived from thickened lower continental crust and mafic magma derived
from subcontinental lithospheric mantle (SCLM) may account for the origin of high Mg# adakitic rocks in the intracontinental
setting. The host monzogranite and MMEs from the Yangba pluton have zircon U–Pb ages of 207 ± 2 and 208 ± 2 Ma, respectively.
The MMEs show igneous textures and contain abundant acicular apatite that suggests quenching process. Their trace element
and evolved Sr–Nd isotopic compositions [(87Sr/86Sr)i = 0.707069–0.707138, and εNd(t) = −6.5] indicate an origin from SCLM. Some zircon grains from the MMEs have positive εHf(t) values of 2.3–8.2 with single-stage Hf model ages of 531–764 Ma. Thus, the MMEs would be derived from partial melts of the
Neoproterozoic SCLM that formed during rift magmatism in response to breakup of supercontinent Rodinia, and experience subsequent
fractional crystallization and magma mixing process. The host monzogranite exhibits typical geochemical characteristics of
adakite, i.e., high La/Yb and Sr/Y ratios, low contents of Y (9.5–14.5 ppm) and Yb, no significant Eu anomalies (Eu/Eu* = 0.81–0.90),
suggesting that garnet was stable in their source during partial melting. Its evolved Sr–Nd isotopic compositions [(87Sr/86Sr)i = 0.7041–0.7061, and εNd(t) = −3.1 to −4.3] and high contents of K2O (3.22–3.84%) and Th (13.7–19.0 ppm) clearly indicate an origin from the continental crust. In addition, its high Mg# (51–55),
Cr and Ni contents may result from mixing with the SCLM-derived mafic magma. Most of the zircon grains from the adakitic monzogranite
show negative εHf(t) values of −9.4 to −0.1 with two-stage Hf model ages of 1,043–1,517 Ma; some zircon grains display positive εHf(t) of 0.1–3.9 with single-stage Hf ages of 704–856 Ma. These indicate that the source region of adakitic monzogranite contains
the Neoproterozoic juvenile crust that has the positive εHf(t) values in the Triassic. Thus, the high-Mg adakitic granites in the intracontinental setting would form by mixing between
the crustal-derived adakitic magma and the SCLM-derived mafic magma. The mafic and adakitic magmas were generated coevally
at Late Triassic, temporally consistent with the exhumation of deeply subducted continental crust in the northern margin of
the South China Block. This bimodal magmatism postdates slab breakoff at mantle depths and therefore is suggested as a geodynamic
response to lithospheric extension subsequent to the continental collision between the South China and North China Blocks. 相似文献
8.
Shuan-Hong Zhang Yue Zhao Alfred Kröner Xiao-Ming Liu Lie-Wen Xie Fu-Kun Chen 《International Journal of Earth Sciences》2009,98(6):1441-1467
Recent zircon dating identified several late Carboniferous to early Permian hornblende gabbro–diorite–quartz diorite–granodiorite–tonalite–granite
plutons in lithological assemblages at the northern margin of the North China Block (NCB) that were previously regarded as
Archaean to Palaeoproterozoic. Our geochronological results indicate that emplacement of these plutons was a continuous process
during the late Carboniferous to early Permian, from 324 ± 6 to 274 ± 6 Ma, and lasted for at least 50 Ma. In this paper,
the early Permian components with compositions from gabbro to granite within the intrusive complex were studied. The early
Permian plutons exhibit calc-alkaline or high-K calc-alkaline, metaluminous geochemical features and highly variable SiO2 contents. They have no significant Eu anomaly in their REE patterns, and in primitive-mantle-normalized spidergrams they
display depletion in Th, U, Nb, Ta, P and Ti, and enrichment in Ba, K, Pb and Sr. The granitoid bodies within these plutons
display I-type and adakitic geochemical signatures. The early Permian rocks exhibit low whole-rock initial 87Sr/86Sr ratios from 0.70520 to 0.70615 and have negative whole-rock ε
Nd(t) values ranging from −17.4 to −9.3 and zircon ε
Hf(t) values of −23.2 to −10.5. The gabbros exhibit higher ε
Nd(t) values from −11.1 to −9.3 and ε
Hf(t) values from −16.5 to −10.5, and one granodiorite exhibits an even lower ε
Nd(t) value of −17.4 and zircon ε
Hf(t) values of −23.2 to −15.1. Geochemical, Sr–Nd and in situ zircon Hf isotopic compositions suggest that the hornblende gabbros
were derived from a metasomatized lithospheric mantle, and the diorite and quartz diorite were generated from a gabbroic magma
by fractional crystallization, coupled with differential assimilation of ancient lower crustal material. The granodiorite
was likely derived from partial melting of ancient lower crust with involvement of some mantle components. Involvement of
both lithospheric mantle and ancient lower crust in the generation of the early Permian plutons indicates strong crust–mantle
interaction in the northern NCB. Petrological associations as well as geochemical and Sr–Nd–Hf isotopic results show that
the early Permian plutons were emplaced along an Andean-type active continental margin during southward subduction of the
Palaeo-Asian oceanic plate beneath the NCB. Integration of our results with previously published data for late Carboniferous
and late Permian to middle Triassic intrusions suggests that the continental arc on the northern margin of the NCB existed
for at least 50 Ma during the late Palaeozoic, and final amalgamation of the Mongolian arc terranes with the northern NCB
likely occurred during a period from ~270 to ~250 Ma, i.e, in the late Permian to earliest Triassic. 相似文献
9.
Carbonatite metasomatized peridotite xenoliths from southern Patagonia: implications for lithospheric processes and Neogene plateau magmatism 总被引:10,自引:0,他引:10
The mineral chemistry, major and trace element, and Sr–Nd isotopic composition of Cr-diopside, spinel peridotite xenoliths
from the Estancia Lote 17 locality in southern Patagonia document a strong carbonatitic metasomatism of the backarc continental
lithosphere. The Lote 17 peridotite xenolith suite consists of hydrous spinel lherzolite, wehrlite, and olivine websterite,
and anhydrous harzburgite and lherzolite. Two-pyroxene thermometry indicates equilibration temperatures ranging from 870 to
1015 °C and the lack of plagioclase or garnet suggests the xenoliths originated from between ˜40 and 60 km depth. All of the
xenoliths are LILE- and LREE-enriched, but have relatively low 87Sr/86Sr (0.70294 to 0.70342) and high ɛNd (+3.0 to +6.6), indicating recent trace element enrichment (∼25 Ma, based on the low 87Sr/86Sr and high Rb concentrations of phlogopite separates) in the long-term, melt-depleted Patagonian lithosphere. Lote 17 peridotite
xenoliths are divided into two basic groups. Group 1 xenoliths consist of fertile peridotites that contain hydrous phases
(amphibole ± phlogopite ± apatite). Group 1 xenoliths are further subdivided into three groups (a, b, and c) based on distinctive
textures and whole-rock chemistry. Group 1 xenolith mineralogy and chemistry are consistent with a complex metasomatic history
involving variable extents of recent carbonatite metasomatism (high Ca/Al, Nb/La, Zr/Hf, low Ti/Eu) that has overprinted earlier
metasomatic events. Group 2 xenoliths consist of infertile, anhydrous harzburgites and record cryptic metasomatism that is
attributed to CO2-rich fluids liberated from Group 1 carbonatite metasomatic reactions. Extremely variable incompatible trace element ratios
and depleted Sr–Nd isotopic compositions of Lote 17 peridotite xenoliths indicate that the continental lithosphere was neither
the primary source nor an enriched lithospheric contaminant for Neogene Patagonian plateau lavas. Neogene plateau magmatism
associated with formation of asthenospheric slab windows may have triggered this occurrence of “intraplate-type” carbonatite
metasomatism in an active continental backarc setting.
Received: 26 January 2000 / Accepted: 1 March 2000 相似文献
10.
Yan-Jie Tang Hong-Fu Zhang Eizo Nakamura Ji-Feng Ying 《Contributions to Mineralogy and Petrology》2011,161(6):845-861
Elemental and Li–Sr–Nd isotopic data of minerals in spinel peridotites hosted by Cenozoic basalts allow us to refine the existing
models for Li isotopic fractionation in mantle peridotites and constrain the melt/fluid-peridotite interaction in the lithospheric
mantle beneath the North China Craton. Highly elevated Li concentrations in cpx (up to 24 ppm) relative to coexisting opx
and olivine (<4 ppm) indicate that the peridotites experienced metasomatism by mafic silicate melts and/or fluids. The mineral
δ7Li vary greatly, with olivine (+0.7 to +5.4‰) being isotopically heavier than coexisting opx (−4.4 to −25.9‰) and cpx (−3.3
to −21.4‰) in most samples. The δ7Li in pyroxenes are considerably lower than the normal mantle values and show negative correlation with their Li abundances,
likely due to recent Li ingress attended by diffusive fractionation of Li isotopes. Two exceptional samples have olivine δ7Li of −3.0 and −7.9‰, indicating the existence of low δ7Li domains in the mantle, which could be transient and generated by meter-scale diffusion of Li during melt/fluid-peridotite
interaction. The 143Nd/144Nd (0.5123–0.5139) and 87Sr/86Sr (0.7018–0.7062) in the pyroxenes also show a large variation, in which the cpx are apparently lower in 87Sr/86Sr and slightly higher in 143Nd/144Nd than coexisting opx, implying an intermineral Sr–Nd isotopic disequilibrium. This is observed more apparently in peridotites
having low 87Sr/86Sr and high 143Nd/144Nd ratios than in those with high 87Sr/86Sr and low 143Nd/144Nd, suggesting that a relatively recent interaction existed between an ancient metasomatized lithospheric mantle and asthenospheric
melt, which transformed the refractory peridotites with highly radiogenic Sr and unradiogenic Nd isotopic compositions to
the fertile lherzolites with unradiogenic Sr and radiogenic Nd isotopic compositions. Therefore, we argue that the lithospheric
mantle represented by the peridotites has been heterogeneously refertilized by multistage melt/fluid-peridotite interactions. 相似文献
11.
Jian-Wei Li Xin-Fu Zhao Mei-Fu Zhou Paulo Vasconcelos Chang-Qian Ma Xiao-Dong Deng Zorano Sérgio de Souza Yong-Xin Zhao Gang Wu 《Mineralium Deposita》2008,43(3):315-336
The Tongshankou Cu–Mo deposit, located in the westernmost Daye district of the Late Mesozoic Metallogenic Belt along the Middle-Lower
reaches of the Yangtze River, eastern China, consists mainly of porphyry and skarn ores hosted in the Tongshankou granodiorite
and along the contact with the Lower Triassic marine carbonates, respectively. Sensitive high-resolution ion microprobe zircon
U–Pb dating constrains the crystallization of the granodiorite at 140.6 ± 2.4 Ma (1σ). Six molybdenite samples from the porphyry ores yield Re–Os isochron age of 143.8 ± 2.6 Ma (2σ), while a phlogopite sample from the skarn ores yields an 40Ar/39Ar plateau age of 143.0 ± 0.3 Ma and an isochron age of 143.8 ± 0.8 Ma (2σ), indicating an earliest Cretaceous mineralization event. The Tongshankou granodiorite has geochemical features resembling
slab-derived adakites, such as high Sr (740–1,300 ppm) and enrichment in light rare earth elements (REE), low Sc (<10 ppm),
Y (<13.3 ppm), and depletion in heavy REE (<1.2 ppm Yb), and resultant high Sr/Y (60–92) and La/Yb (26–75) ratios. However,
they differ from typical subduction-related adakites by high K, low MgO and Mg#, and radiogenic Sr–Nd–Hf isotopic compositions,
with (87Sr/86Sr)
t
= 0.7062–0.7067, ɛ
Nd(t) = −4.37 to −4.63, (176Hf/177Hf)
t
= 0.282469–0.282590, and ɛ
Hf(t) = −3.3 to −7.6. The geochemical and isotopic data, coupled with geological analysis, indicate that the Tongshankou granodiorite
was most likely generated by partial melting of enriched lithospheric mantle that was previously metasomitized by slab melts
related to an ancient subduction system. Magmas derived from such a source could have acquired a high oxidation state, as
indicated by the assemblage of quartz–magnetite–titanite–amphibole–Mg-rich biotite in the Tongshankou granodiorite and the
compositions of magmatic biotite that fall in the field between the NiNiO and magnetite–hematite buffers in the Fe3+–Fe2+–Mg diagram. Sulfur would have been present as sulfates in such highly oxidized magmas, so that chalcophile elements Cu and
Mo were retained as incompatible elements in the melt, contributing to subsequent mineralization. A compilation of existing
data reveals that porphyry and porphyry-related Cu–Fe–Au–Mo mineralization from Daye and other districts of the Metallogenic
Belt along the Middle-Lower reaches of the Yangtze River took place coevally in the Early Cretaceous and was related to an
intracontinental extensional environment, distinctly different from the arc-compressive setting of the Cenozoic age that has
been responsible for the emplacement of most porphyry Cu deposits of the Pacific Rim. 相似文献
12.
Origin of a Mesozoic granite with A-type characteristics from the North China craton: highly fractionated from I-type magmas? 总被引:2,自引:0,他引:2
Neng Jiang Shuangquan Zhang Wenge Zhou Yongsheng Liu 《Contributions to Mineralogy and Petrology》2009,158(1):113-130
We report geochronological, geochemical and isotopic data for the Mesozoic Shangshuiquan granite from the northern margin
of the North China craton. The granite is highly fractionated, with SiO2 > 74%. Occurrence of annitic biotite, high contents of alkalis (K2O + Na2O), Rb, Y, Nb and heavy rare earth elements, high FeOt/MgO, low contents of CaO, Al2O3, Ba, and Sr, and large negative Eu anomalies, makes it indistinguishable from typical A-type granites. A mantle-derived origin
for the rocks of the granite is not favored because their high initial 87Sr/86Sr (≥0.706) and low εNd (t) (<−15) are completely different from either those of the lithospheric or asthenospheric mantle. In fact, their Sr–Nd isotopes
fall within the range of Sr–Nd isotopic compositions of the Archean granulite terrains and are comparable to those of Mesozoic
crustal-derived I-type granitoids in the region. Therefore, the Shangshuiquan granite is considered to be dominantly derived
from partial melting of the ancient lower crust. Its parental magmas prove to be similar to I-type magmas and to have undergone
extensive fractionation during its ascent. This is supported by the fact that some of the nearby Hannuoba feldspar-rich granulite
xenoliths can be indeed regarded as the early cumulates in terms of their mineralogy, chemistry, Sr–Nd isotopes and zircon
U–Pb ages and Hf isotopes. It is furthermore argued that some of highly fractionated granites worldwide, especially those
with A-type characteristics and lacking close relationship with unfractionated rocks, may in fact be fractionated I-type granites.
This suggestion can explain their close temporal and spatial associations as well as similar Sr–Nd isotopes with I-type granites.
Our study also sheds new light on the petrogenesis of deep crustal xenoliths. 相似文献
13.
The molybdenite deposit of the Alpeinerscharte (Austria) is situated in Variscan greenschist- to amphibolite-facies metamorphosed
granodiorites and granites of the western Tauern Window. These granitoids represent strongly fractionated calc-alkaline I-type
magmas with minor S-type components and reveal post-orogenic affinities. Molybdenum contents (average 4.3 ppm) are slightly
above the general background of average granites. Molybdenite mineralization is restricted to narrow quartz veins and quartz
vein selvages which are presently composed of biotite and (almandine-grossular) garnet. These selvages show geochemical features
typical of intermediate argillic alteration in a hydrothermal system postdating granite intrusion: instability of plagioclase
causes removal of Na, Ba, Sr, Pb and Eu, while K and Ca remain nearly constant. Rare earth elements (apart from Eu) and metals
are extremely enriched. Application of Fe-Mg exchange (garnet-biotite) and oxygen isotope (quartz-garnet, quartz-plagioclase)
geothermometers to vein selvage mineral assemblages reveals temperatures of the late-Alpine (35–55 Ma) metamorphic overprint
(∼540 °C, 7–10 kbar). Leucocratic rocks composed of mainly orthoclase and plagioclase are occasionally spatially related to molybdenite-bearing
veins; they are interpreted as episyenites formed by hydrothermal alteration of the host granite. This episyenitic alteration
is characterized by a mass loss of ca. 30%, relative enrichment of plagioclase components, extreme depletion of Si, and minor
depletion of Fe, Zn, Cu and Mo.
Received: 5 December 1993/Accepted: 24 October 1995 相似文献
14.
Pietro Mosca Riccardo Polino Sergio Rogledi Massimo Rossi 《International Journal of Earth Sciences》2010,99(4):833-849
Alps and Apennines are juxtaposed within an approximately 100 km-wide area covered by the Upper Eocene to Miocene successions
of the Tertiary Piedmont Basin. The Upper Eocene–Oligocene evolution of this area was characterized to the north and west
by the propagation of the SE-verging Southalpine thrust-fold belt that can be traced from the Po Plain subsurface until the
Torino Hill-Saluzzese area, and to the south by a high-angle, broadly E–W oriented megashear zone that led to the juxtaposition
of different crustal levels and controlled the development of a mosaic of partly independent sub-basins. Since the latest
Oligocene the N-verging Apenninic tectonics prevailed in the collisional system and the Tertiary Piedmont Basin evolved as
a wide thrust-top basin, bounded to the north by the N-verging Monferrato arc and characterized by a tectono-sedimentary evolution
recording changes of subsidence and shift of depocentres in relation to crustal structures. 相似文献
15.
Gianfilippo De Astis Angelo Peccerillo Pamela D. Kempton Luigi La Volpe Tsai W. Wu 《Contributions to Mineralogy and Petrology》2000,139(6):684-703
The problem of mantle metasomatism vs. crustal contamination in the genesis of arc magmas with different potassium contents
has been investigated using new trace element and Sr–Nd–Pb isotopic data on the island of Vulcano, Aeolian arc. The analysed
rocks range in age from 120 ka to the present day, and cover a compositional range from basalt to rhyolite of the high-K calc-alkaline
(HKCA) to shoshonitic (SHO) and potassic (KS) series. Older Vulcano products (>30 ka) consist of HKCA–SHO rocks with SiO2=48–56%. They show lower contents of K2O, Rb and of several other incompatible trace element abundances and ratios than younger rocks with comparable degree of evolution.
87Sr/86Sr ranges from 0.70417 to 0.70504 and increases with decreasing MgO and compatible element contents. 206Pb/204Pb ratios display significant variations (19.31 to 19.76) and are positively correlated with MgO, 143Nd/144Nd (0.512532–0.512768), 207Pb/204Pb (15.66–15.71) and 208Pb/204Pb (39.21–39.49). Overall, geochemical and isotopic data suggest that the evolution of the older series was dominated by assimilation–fractional
crystallisation (AFC) with an important role for continuous mixing with mafic liquids. Magmas erupted within the last 30 ka
consist mostly of SHO and KS intermediate and acid rocks, with minor mafic products. Except for a few acid rocks, they display
moderate isotopic variations (e.g. 87Sr/86Sr=0.70457–0.70484; 206Pb/204Pb=19.28–19.55, but 207Pb/204Pb=15.66–15.82), which suggest an evolution by fractional crystallisation, or in some cases by mixing, with little interaction
with crustal material. The higher Sr isotopic ratios (87Sr/86Sr=0.70494–0.70587) of a few, low-volume, intermediate to acid rocks support differentiation by AFC at shallow depths for
some magma batches. New radiogenic isotope data on the Aeolian islands of Alicudi and Stromboli, as well as new data for lamproites
from central Italy, are also reported in order to discuss along-arc compositional variations and to evaluate the role of mantle
metasomatism. Geochemical and petrological data demonstrate that the younger K-rich mafic magmas from Vulcano cannot be related
to the older HKCA and SHO ones by intra-crustal evolutionary processes and point to a derivation from different mantle sources.
The data from Alicudi and Stromboli suggest that, even though interaction between magma and wall rocks of the Calabrian basement
during shallow level magma evolution was an important process locally, a similar interpretation can be extended to the entire
Aeolian arc.
Received: 27 September 1999 / Accepted: 24 May 2000 相似文献
16.
The Tuwu–Yandong porphyry copper belt lies in the eastern Tianshan mountains, eastern section of the Central Asian orogenic belt. The copper mineralization is mainly hosted in plagiogranite porphyries intruded into early Carboniferous volcanic rocks of the Paleozoic Dananhu island arc between the Tarim and Siberian plates. The plagiogranite porphyries have contents of 65–73 wt% SiO2, 14–17 wt% Al2O3, 0.9–2.2 wt% MgO, 3–16 ppm Y, 0.4–1.40 ppm Yb, 347–920 ppm Sr, and positive Eu anomalies. The rocks also exhibit positive ɛ
Nd(t) values (+5.0 to +9.4) and low initial 87Sr/86Sr values (0.70316–0.70378). Such features are similar to those of adakites derived from partial melting of a subduction-related oceanic slab. The mineralization age is early Carboniferous (350–320 Ma), which is close to that of the porphyries. The close relationship between the Cu mineralization and the porphyry is also indicated by their similar Sr-Nd-Pb isotopic compositions. We suggest that the copper porphyry (magma) system in the Dananhu island arc was formed by direct melting of an obliquely subducting early Carboniferous oceanic slab. 相似文献
17.
The South Um Mongul prospect is a Cu-Mo-Au porphyry system. It is covered by porphyritic dacite and hornblende gabbro. Both units are intruded by monzogranite, which encloses xenoliths of both units. Using LA-ICP-MS U-Pb zircon method, the dacite is dated at ca. 773 ± 6.9 Ma, while the gabbro and the monzogranite are dated at 603 ± 3.5 and 558 ± 4.6 Ma, respectively. The dacite age is consistent with the mid-Cryogenian subduction-related magmatic stage and the gabbro-monzogranite age is comparable to the Ediacaran post-collisional magmatic stage during the evolution of the Arabian-Nubian Shield. The dacite is akin to high-K I-type granitoids and its primitive mantle-normalized trace element patterns show negative Nb anomalies and enrichment in LILE (large ion lithophile elements), Th and U over HFSE. These geochemical characteristics are similar to those of felsic magma formed in a subduction-related tectonic setting. The high La/Ybcn (7.2–30.9), Nb/Yb (2.63–4.41) and Th/Yb (2.07–3.04) ratios of the dacite are comparable to continental rather than oceanic arc systems. Its low Sm/Yb ratios (1.84–3.13) support the primitive nature of the crust beneath the continental arc and derivation from a garnet-free lower crustal source. The dacite has low Sr/Y ratios (5–9) and its Eu/Eu⁎ ratios range from 0.66 to 0.83. Similar to dacite, the primitive mantle-normalized trace element patterns of the post-collisional suite show a subduction-related geochemical signature. However, the gabbro is characterized by Th/Ta ratios (3.4–14.8), which are comparable with the within-plate tectonic setting. The subduction-related geochemical signature is inherited from long subduction history beneath the Arabian-Nubian Shield. Both the gabbro and monzogranite are characterized by high Ba (404–590 ppm and 936–1590 ppm, respectively) and Sr (611–708 ppm and 624–793 ppm, respectively) contents, which make them analogous to the Caledonian appinite-high Ba-Sr granite assemblage. The formation of these rocks is related to the Ediacaran lithospheric erosion accompanying slab break-off. This process induced asthenospheric upwelling, which led to partial melting of the lithosphere previously metasomatised by subducted sediments involving carbonates impregnated by hydrothermal barite. Melting of this lithosphere led to the formation of the hornblende gabbro. Underplating by the mafic magma led to melting of the lower crust and the formation of high Ba-Sr monzogranite in the area. The high Sm/Yb (2.94–4.19) and Sr/Y (52–74) ratios of the monzogranite may indicate the presence of garnet in the melted amphibolitic lower crust. The higher Sr/Y ratios, lower HFSE (high field strength elements) contents and the absence of pronounced Eu anomalies in monzogranite relative to dacite suggest the productive nature of the post-collisional magma relative to the continental arc magma in this prospect. 相似文献
18.
M. Selman Aydoan Hakan oban Mustafa Bozcu
mer Aknc 《Journal of Asian Earth Sciences》2008,33(3-4):155-176
The (late syn)- post-collisional magmatic activities of western and northwestern Anatolia are characterized by intrusion of a great number of granitoids. Amongst them, Baklan Granite, located in the southern part of the Muratdağı Region from the Menderes Massif (Banaz, Uşak), has peculiar chemical and isotopic characteristics. The Baklan rocks are made up by K-feldspar, plagioclase, quartz, biotite and hornblende, with accessory apatite, titanite and magnetite, and include mafic microgranular enclaves (MME). Chemically, the Baklan intrusion is of sub-alkaline character, belongs to the high-K, calc-alkaline series and displays features of I-type affinity. It is typically metaluminous to mildly peraluminous, and classified predominantly as granodiorite in composition. The spider and REE patterns show that the rocks are fractionated and have small negative Eu anomalies (Eu/Eu* = 0.62–0.86), with the depletion of Nb, Ti, P and, to a lesser extent, Ba and Sr. The pluton was dated by the K–Ar method on the whole-rock, yielded ages between 17.8 ± 0.7 and 19.4 ± 0.9 Ma (Early Miocene). The intrusion possesses primitive low initial 87Sr/86Sr ratios (0.70331–0.70452) and negative εNd(t) values (−5.0 to −5.6). The chemical contrast between evolved Baklan rocks (SiO2, 62–71 wt.%; Cr, 7–27 ppm; Ni, 5–11 ppm; Mg#, 45–51) and more primitive clinopyroxene-bearing monzonitic enclaves (SiO2, 54–59 wt.%; Cr, 20–310 ppm; Ni, 10–70 ppm; Mg#, 50–61) signifies that there is no co-genetic link between host granite and enclaves. The chemical and isotopic characteristics of the Baklan intrusion argue for an important role of a juvenile component, such as underplated mantle-derived basalt, in the generation of the granitoids. Crustal contamination has not contributed significantly to their origin. However, with respect to those of the Baklan intrusion, the generation of the (late syn)- post-collisional intrusions with higher Nd(t) values from the western Anatolia require a much higher amount of juvenil component in their source domains. 相似文献
19.
The North Qiangtang continental block in central Tibet is a critical piece of the Pangea puzzle. This paper uses integrated geochronological and geochemical data for selected mafic dykes and dioritic enclaves in this block to evaluate its tectonic evolution in the Triassic. Zircons from two mafic dykes and the dioritic enclaves of a large arc granodiorite pluton in eastern North Qiangtang yield indistinguishable U-Pb ages from 248 ± 2 to 251 ± 3 Ma, contemporaneous with widespread arc basaltic andesites and crust-derived rhyolites in the region. The mafic dykes and coeval arc basaltic andesites have almost identical Sr-Nd isotopes (initial 87Sr/86Sr = 0.707 to 0.708, εNd = −4.4 to −3.6), and are all characterized by light REE enrichments and pronounced negative Nb-Ta anomalies. The dioritic enclaves and the hosts have indistinguishable zircon U-Pb ages, almost identical Sr-Nd isotopes (initial 87Sr/86Sr = 0.709 to 0.711, εNd = −7.4 to −5.9), and similar zircon εHf (−13.7 to −5.7), but contrasting chondrite-normalized REE patterns due to hornblende fractionation. The Sr-Nd isotope data indicate that the dioritic enclaves formed from the hybrid melts produced by mixing at depth between the arc basaltic andesites and the crust-derived rhyolites. We propose that the Early Triassic arc igneous suites are related to the northward subduction of the southern Paleo-Tethys beneath the North Qiangtang block from Early to Middle Triassic. The occurrence of several Late Triassic porphyry Cu deposits plus a VMS Ag-Pb-Zn deposit in the Yidun arc, which is the product of the southward subduction of the northern Paleo-Tethys beneath the North Qiangtang block in the Late Triassic, indicates that the arc magmas generated during the subduction of the Paleo-Tethys are fertile in ore metals. Therefore, exploration for Early–Middle Triassic porphyry Cu and VMS deposits in the southern part of the North Qiangtang block is warranted. 相似文献
20.
The Rotoiti (~120 km3) and Earthquake Flat (~10 km3) eruptions occurred in close succession from the Okataina Volcanic Centre at ~50 ka. While accessory mineral geochronology
points to long periods of crystallization prior to eruption (104–105 years) and separate thermal histories for the magmas, little was known about the rates and processes of the final melt production
and eruption. Crystal zoning patterns in plagioclase and quartz reveal the thermal and compositional history of the magmatic
system leading up to the eruption. The dominant modal phase, plagioclase, displays considerable within-crystal zonation: An37–74, ~40–227 ppm MgO, 45–227 ppm TiO2, 416–910 ppm Sr and 168–1164 ppm Ba. Resorption horizons in the crystals are marked by sharp increases (10–30%) in Sr, MgO
and XAn that reflect changes in melt composition and are consistent with open system processes. Melt inclusions display further evidence
for open system behaviour, some are depleted in Sr and Ba relative to accompanying matrix glass not consistent with crystallization
of modal assemblage. MI also display a wide range in XH2O that is consistent with volatile fluxing. Quartz CL images reveal zoning that is truncated by resorption, and accompanied
by abrupt increases in Ti concentration (30–80 ppm) that reflect temperature increases ~50–110°C. Diffusion across these resorption
horizons is restricted to zones of <20 μm, suggesting most crystallization within the magma occurred in <2000 years. These
episodes are brief compared to the longevity (104–105 year) of the crystal mush zones. All textural and compositional features observed within the quartz and plagioclase crystals
are best explained by periodic mafic intrusions repeatedly melting parts of a crystal-rich zone and recharging the system
with silicic melt. These periodic influxes of silicic melt would have accumulated to form the large volume of magma that fed
the caldera-forming Rotoiti eruption. 相似文献