吉林省绿色矿山建设存在问题及建议

我国在快速工业化进程和崛起的过程中,矿业持续快速发展,对生态环境造成了一定负面影响,随着生态文明建设思想的不断深入,绿色低碳转型已势在必行.绿色矿山建设是矿业绿色发展、生态文明建设的基础.本文通过梳理吉林省绿色矿山和绿色矿业发展示范区建设现状,对比全国绿色矿山建设情况,总结导致我省绿色矿山建设进程缓慢的原因,找出存在的问题和不足,提出吉林省绿色矿山建设的建议和具体措施.     

油气资源勘探开发中的环保策略

随着国家级绿色矿山建设的推动,形成了绿色矿山建设的4种典型模式初步架构：油气资源高效开采新模式、煤炭资源绿色开采新模式、金属资源高效综合利用和化工及建材非金属矿山的绿色发展。其中的油气资源高效开采新模式重点围绕低渗透、超低渗透等难利用油气资源、非常规油气资源的高效利用,开展绿色矿山建设工作,形成一批典型经验和模式,盘活了一批资源储量。     

江苏省矿山地质环境区划研究

随着矿业经济发展由“资源开发”向“资源开发与环境保护并重”的转变,矿山地质环境保护与治理已成为生态省建设的主要内容之一。因此,合理划定矿山地质环境保护与治理区域,对改善生态环境意义重大。本文以江苏矿山地质环境调查成果为基础,基于矿山地质环境的自然属性和社会属性,建立了由2个目标层、5个约束层和12个指标层构成的江苏矿山地质环境区划评价指标体系。在MAPGIS技术支持下,采用综合指数模型,将各区划因子按其权重进行空间代数叠加,根据叠加的结果并结合矿山开采现状,将关闭矿区划定为矿山地质环境重点治理区和一般治理区;将开采矿区划定为矿山地质环境重点防治区和一般防治区。     

北京矿山固体废弃物资源化利用现状及展望

北京地区矿产主要有铁矿、石灰石矿、煤矿和黄金矿,历年开采过程中堆积了大量的矿山固体废弃物.自2005年以来,北京市政府对境内矿产资源的开采进行限制,关闭了大量矿山,开展固体废弃物资源化利用已经成为了矿山的接续产业.在国家资源综合利用政策和北京地区限采河道砂石、禁止使用粘土砖等政策的推动下,矿山固体废弃物资源化利用技术得到了深入研究和广泛推广,取得了很好的经济和社会效益.     

吉林省不同类型矿山地质环境问题及恢复治理对策初探

吉林省矿业活动引发的矿山地质环境问题主要是地面塌陷、地下水资源污染破坏、地形地貌景观破坏和压占、毁损土地资源.根据吉林省不同类型矿山引发的地质环境问题的特点,探讨各类矿山宜采取的地质环境保护与恢复治理对策,为今后实施矿山地质环境保护工程提出可行性建议.     

走绿色矿业之路

矿产资源为国家经济建设提供了物质基础，是人类社会可持续发展的重要保障。然而随着经济的快速增长，对矿产资源的需求不断增大，由矿业开发所导致的环境污染和生态破坏问题也与日俱增。本文阐述了矿业开发对大气、水体、土壤及人类健康的影响以及矿山开采引发的地质灾害问题，探讨了矿山环境恢复的途径，并提出应加强矿山环境保护和矿区生态重建，走可持续发展的绿色矿业之路。     

甘肃夏河—合作成矿带早子沟金矿绿色矿山建设分析

建设绿色矿山是新形势下保证矿业可持续健康发展的必由之路,是在恢复生态系统基础上实现自然、经济和社会系统共同发展的必然选择。早子沟金矿是甘南藏族自治州第一个国家级绿色矿山。在绿色矿山建设过程中,树立了绿色发展理念,在采矿、选矿、资源高效综合利用、节能减排、安全生产等方面均进行了科技创新,确保了矿山开发、生态环境、地方群众的和谐统一,形成了具有开采方式科学化、生产工艺环保化、资源利用高效化、企业管理规范化、矿山及社区环境生态化的高标准绿色矿山企业,可为区域绿色矿业发展提供参考。     

基于生态保护优先的青藏高原矿产资源勘查开发的对策

青藏高原矿产资源开发在地区经济社会发展中具有支柱性地位,是中国重要的矿产资源后备开发及战略基地,但同时又是中国重要的生态环境屏障,资源开发与生态环境保护成为重大的资源环境问题。通过矿山地质环境调查发现,由于以往环境保护意识不足等多种因素的综合影响,矿产资源勘查开发对高原植被生态影响严重,高山草甸植被保护与修复成为青藏高原矿山最主要、最突出的环境问题。基于寒冷、缺氧、少土、交通不便等制约性自然因素,提出了源头优先保护生态的矿产资源勘查开发的对策建议:提高青藏高原矿山准入条件、构建基于源头生态保护的机制、制定开发利用规划、基于矿山地质环境承载力评价的矿山布局、建立勘查及合理开发的矿产资源储备基地、建立矿山生态环境长期监测网、推广高原植被生态修复技术体系等,为政府科学决策矿产资源绿色勘查开发提供地质依据。     

甘肃省地方标准“绿色矿山建设规范”编制说明

论述了甘肃省地方标准《绿色矿山建设规范》（煤矿、金属矿、非金属矿、石油天然气、砂石粘土矿5个部分）的编制背景、编制过程、编制原则、主要内容、主要特点、使用《规范》的几点说明。重点从基本条件、资源开发利用、节能减排、科技创新与智能化建设、矿区环境、企业管理与企业形象等绿色矿山建设的6个主要方面进行简要论述;与行业标准进行对比分析,总结《规范》的共性特点和各部分特点。     

矿产资源开发与泥石流灾害及其防治对策

由于掠夺式开采以及环境保护滞后于经济发展,我国矿产资源开发利用产生了比较严重的环境问题。本文在分析我国矿山人为泥石流灾害状况的基础上,提出了改善生态环境保护与重建的法治建设环境,加大矿山生态环境保护的监督管理力度,并具体提出了矿山人为泥石流灾害预防和工程治理的措施。     

Hydrogen and carbon in solid solution in oxides and silicates

The dissolution of H₂O and CO₂ in structurally dense, nominally anhydrous and non-carbonate oxide matrices such as MgO and CaO is reviewed. H₂O and CO₂ are treated as gaseous oxide components which enter into solid solution with the refractory oxide hosts. They form anion complexes associated with cation vacancy sites. Evidence is presented that OH^? pairs which derive from the dissolution of H₂O are subject to a charge transfer (CT) conversion into peroxy moieties and molecular hydrogen, O ₂ ^2? ... H₂. Because the O ₂ ^2? moiety is small (O^?-O^? distance ≈ 1.5 Å) high pressure probably favors the CT conversion. Mass spectroscopic studies show that molecular H₂ may be lost from the solid which retains excess oxygen in the form of O ₂ ^2? , leading to the release of atomic O. The dissociation of O ₂ ^2? moieties into a vacancy-bound O^? state and an unbound O^? state can be followed by measuring the internal redox reactions involving transition metal impurities, the transient paramagnetism of the O^? and their effect on the d.c. conductivity. Evidence is presented that CO₂ molecules dissolve dissociatively in the structurally dense oxide matrix, as if they were first to dissociate into CO+O and then to form separate solute moieties CO ₂ ^2? and O ₂ ^2? , both associated with cation vacancy sites. In the CO ₂ ^2? moiety (C-O^? distance 1.2–1.3 Å, OCO angle ≈ 130°) the C atom probably sits off center. The transition of the C atom into interstitial sites is accompanied by dissociation of the CO ₂ ^2? moiety into CO^? and O^?. This transition can be followed by infrared spectroscopy, using OH^? as local probes. Further support derives from magnetic susceptibility, thermal expansion, low frequency dielectric loss and low temperature deformation measurements. The recently observed emission of O and Mg atoms besides a variety of molecules such as CO, CO₂, CH₄, HCN and other hydrocarbons during impact fracture of MgO single crystals is presented and discussed in the light of the other experimental data.     

Comparative urbanization in Ghana and Kenya in time and space

There are few inter-African country urban analyses because of the continent’s enormous size and socioeconomic diversity, language barriers, and wide variations in national and regional urban research capacity. Nevertheless, comparative urban studies are critical in understanding contemporary African urbanization. In this comparative spatial and temporal analysis of Ghana and Kenya’s urbanization, we find that both countries are urbanizing rapidly and are faced with many common urban problems. Moreover, Ghana is more urbanized than Kenya and has a larger indigenous urban imprint and a more widely dispersed urban pattern. Besides their physiographic and population conditions, we trace these countries’ convergent and divergent urban trends to their shared but unique experiences of colonialism, nationalism and globalization.     

Re-Os and Pd-Ag systematics in Group IIIAB irons and in pallasites

Using improved analytical techniques, which reduce the Re blanks by factors of 8 to 10, we report new Re-Os data on low Re and low PGE pallasites (PAL-anom) and IIIAB irons. The new pallasite samples nearly double the observed range in Re/Os for pallasites and allow the determination of an isochron of slope 0.0775 ± 0.0008 (T = 4.50 ± 0.04 Ga, using the adjusted λ¹⁸⁷Re = 1.66 × 10⁻¹¹ a⁻¹) and initial (¹⁸⁷Os/¹⁸⁸Os)₀ = 0.09599 ± 0.00046. If the data on different groups of pallasites (including the “anomalous” pallasites) are considered to define a whole-rock isochron, their formation would appear to be distinctly younger than for the iron meteorites by ∼60 Ma. Five IIIAB irons (Acuna, Bella Roca, Chupaderos, Grant, and Bear Creek), with Re contents ranging from 0.9 to 2.8 ppb, show limited Re/Os fractionation and plot within errors on the IIAB iron meteorite isochron of slope 0.07848 ± 0.00018 (T = 4.56 ± 0.01 Ga) and initial (¹⁸⁷Os/¹⁸⁸Os)₀ = 0.09563 ± 0.00011. Many of the meteorites were analyzed also for Pd-Ag and show ¹⁰⁷Ag enrichments correlated with Pd/Ag, requiring early formation and fractionation of the FeNi metal, in a narrow time interval, after injection of live ¹⁰⁷Pd (t_1/2 = 6.5 Ma) into the solar nebula. Based on Pd-Ag, the typical range in relative ages of these meteorites is ≤10 Ma. The Pd-Ag results suggest early formation and preservation of the ¹⁰⁷Pd-¹⁰⁷Ag systematics, both for IIIAB irons and for pallasites, while the younger Re-Os apparent age for pallasites suggests that the Re-Os system in pallasites was subject to re-equilibration. The low Re and low PGE pallasites show significant Re/Os fractionation (higher Re/Os) as the Re and PGE contents decrease. By contrast, the IIIAB irons show a restricted range in Re/Os, even for samples with extremely low Re and PGE contents. There is a good correlation of Re and Ir contents. The correlation of Re and Os contents for IIIAB irons shows a similar complex pattern as observed for IIAB irons (Morgan et al., 1995), and neither can be ascribed to a continuous fractional crystallization process with uniform solid-metal/liquid-metal distribution coefficients.     

煤中气孔和镶嵌结构及其在煤变质研究中的意义

河南省禹县、新密和荥巩煤田山西组Ⅱ₁煤的贫煤和无烟煤中,气孔发育。气孔形态有椭圆状（图版1）、圆状及不规则状（图版2）,有的几个气孔连在一起呈大的朵状气孔(图版3)。此外,在荥巩煤田西部无烟煤中还发育有镀嵌结构(图版4)。      

岩溶地区现代土壤与洞穴石笋中单甲基支链烷烃与烷基环己烷对比研究

利用GC-MS（气相色谱—质谱仪）,对采自湖北清江流域和尚洞洞顶的土壤样品与洞内石笋样品进行分析,发现土壤中存在的七个系列单甲基支链烷烃在所有的石笋样品中均可以找到,呈现相似的分布模式,石笋中七个系列支链烷烃有可能来自洞穴滴水携带的土壤中的支链烷烃,但是也不能排除石笋原地生长的微生物的贡献。烷基环己烷的分布在土壤与石笋中呈现了相似的分布模式,但是主峰碳数有所变化,高碳数部分与低碳数部分的相对含量也发生了变化。主要原因可能是微生物选择性降解的结果,也有可能是土壤与石笋中微生物种类分布差异所造成的。本次研究初步显示了相对封闭稳定的洞穴沉积物与上覆土壤层中生物标志化合物的异同。      

Geogenic and anthropogenic zinc in epiphytic and terricolous lichens in Finland

At 31 sites in Finland the Zn content was determined of the epiphytic lichen Hypogymnia physodes (L.) Nyl. growing on pine and birch, the terricolous lichen Cladina spp. in pine bark, and the inner part of birch bark. The anomalous contents of Zn in H. physodes on pine and Cladina spp. in soil appeared to be strongly related to sulphide ore deposits. Anthropogenic Zn correlated closely with S and Fe in H. physodes on pine and with Fe in Cladina spp. The binding of geogenic Zn was related to iron hydroxides, and was attributed to the different uptake mechanism of S in these lichens. Elevated values of Zn in H. physodes on birch were due to both geogenic and anthropogenic sources. Zinc in pine bark increased with the Zn content in H. physodes and reached a limiting value.     

Amphibole and chlorite in mafic and ultramafic rocks in the lower crust and upper mantle

Stabilities of amphibole and chlorite in mafic and ultramafic compositions have been considered in the model system CaO+MgO+Al₂O₃+SiO₂+H₂O. From topological arguments two petrogenetic grids have been constructed. Although available experimental data in CMASH are compatible with the grid in which amphibole reacts out before chlorite in model ultramafic compositions for the pressure range 6 to 15 kbar, naturally observed mineral assemblages and some experimental data in more complex systems favour the other grid in which chlorite reacts out before amphibole at all pressures. This discrepancy between natural and model systems is due to differential movement of the dehydration equilibria of the two hydrates reflecting the variation of activity of H₂O or of components other than CMASH.     

Water-extractable and exchangeable phosphate in Martian and carbonaceous chondrite meteorites and in planetary soil analogs

Aqueous extraction contributes to the formation and weathering of planetary materials and renders electrolytes such as phosphate available for biology. In this context, the solubility of phosphate is measured in planetary materials, represented by the Mars meteorites Nakhla, Dar al Gani 476 (DaG 476), Elephant Morraine 79001 (EETA 79001), and terrestrial analogs, and in the Murchison CM2 and Allende CV3 carbonaceous chondrites. The Mars meteorites contain high levels of phosphate that is readily extracted by water, up to 15 mg kg⁻¹ in Nakhla and DaG 476 and 38 mg kg⁻¹ in EETA 79001, while the terrestrial analogs and the carbonaceous chondrites contain 0.5 to 6 mg kg⁻¹. Correspondingly, high phosphate concentrations of 4 to >28 mg L⁻¹ are obtained in extracts of the Mars meteorites at high solid/solution ratios, exceeding the concentrations of 0.4 to 2.0 mg L⁻¹ in the extracts of the terrestrial analogs. A wide range of planetary conditions, including N₂ and CO₂ atmospheres, solid/solution ratios of 0.01 to 1.0 kg L⁻¹, extraction times of 1 to 21 d, and temperatures of 20 to 121°C affect the amounts of extractable phosphate by factors of only 2 to 5 in most materials. Phosphate-fixing capacity and exchangeable phosphate are assessed by the isotopic exchange kinetics (IEK) method, which quantifies the amount of P isotopically exchangeable within 1 min (E_1min) and between 1 min and 3 months (E_1min-3m) and the amount of P that cannot be exchanged within 3 months (E_>3m). The IEK results show that the DaG 476 Mars meteorite and terrestrial analogs have low P-fixing capacities, while the carbonaceous chondrites have high P-fixing capacities. Aqueous processing under early planetary CO₂ atmospheres has large effects on the available phosphate. For example, the fraction of total P that is exchangeable in 3 months increases from 1.6 to 11%, 13 to 51.6%, and 43.9 to 90.4% in the DaG 476 Mars meteorite, Allende, and Murchison, respectively. The results show that solutions with high phosphate concentrations can form in the pores of planetary lava ash and basalts and in carbonaceous asteroids and meteorites. These solutions can help prebiotic synthesis and early microbial nutrition. The Martian and carbonaceous chondrite materials contain sufficient phosphate for space-based agriculture.     

Orogenesis in time and space in Mexico

The evolution of the border region of part or all of a craton, on the basis of geological data gathered from Mexico, may best be described in terms of geotectonic cycles. These consist, in chronological order, of (1) an orthogeosynclinal phase (eu- and miogeosynclines) with or without initial magmatic activity, (2) an anatexitic phase consisting of batholith emplacement with attendant regional metamorphism in the eugeosyncline and deposition of a clastic or flysch wedge over the miogeosyncline, (3) an orogenic phase consisting principally of the folding and thrusting of the sediments of the miogeosyncline together with the clastic or flysch wedge against the foreland, and (4) a taphrogenic or block-faulting phase accompanied by (a) accumulation of post-orogenic debris or molasse, (b) subsequent magmatic activity consisting largely of igneous extrusions with fewer intrusions, and (c) final magmatic activity consisting of igneous extrusions. A region that has gone through the above phases of a geotectonic cycle may be termed a structural belt. In the post-Precambrian geologic history of Mexico, three geotectonic cycles are recognized: one occurred along the Pacific border of Mexico between Cambrian and middle Jurassic (?) time (Jaliscoan geotectonic cycle), the second occurred along the present Gulf of Mexico border of the country at the same time (Huastecan geotectonic cycle), and the third occurred over the entire country from the United States border to the Guatemalan border between Late Jurassic and Pliocene time (Mexican geotectonic cycle). The early Mesozoic clastic rocks in northwestern Mexico may signify a fourth geotectonic cycle in that region. In the three recognized geotectonic cycles, however, the geologic record shows only two orogenic phases, one of which occurred in late Paleozoic time in an arcuate belt along the eastern side of Mexico (Coahuilan orogeny), and the other in early Tertiary time in a belt traversing central Mexico from the United States border to the Guatemalan border (Hidalgoan orogeny).     

建立和完善公司法人治理结构的困难和对策

公司法人治理结构是公司制的核心。本文从分析上市公司、试点企业公司法人治理设立和运作现状入手，着重分析了公司法人治理结构存在的问题和困难所在，总结经验教训，提出了建立和完善公司法人治理结构的对策建议。