Pb,Sr,Nd同位素与辽河油田源对比

对辽河油田源油、有机质的Ｐｂ,Ｓｒ,Ｎｄ同位素进行了研究。原油、有机质的Ｐｂ,Ｓｒ,Ｎｄ同位素资料的分析表明：在辽河油田,仅有极少部分原油与老乡经三系有机质热解有关,大部部分原油为地幔流体与古生界、震旦系海相碳酸盐岩壳－幔相互作用而生成,另一大部分则为地幔流体的ＣＯ,ＣＯ２与Ｈ２的费托合成反应生成。油源对比表明：老第三纪以下的古生代前陆盆地有更大的油气前景。     

Rb‐Sr geochronology and Sr isotopic composition of Devonian granitoids,eastern Tasmania

Biotite igneous ages and well‐defined isochron ages of plutons from the composite Blue Tier Batholith and the Coles Bay area in northeastern Tasmania range from 395 to 370 Ma. The older limit of this range, for the George River granodiorite, is considerably older than any age previously recorded for NE Tasmania. The ages of the youngest plutons (Mt Paris and Anchor granites), which host cassiterite ores, record pervasive hydrothermal alteration events. The initial ⁸⁷Sr/⁸⁰Sr ratios of the granitoids range from 0.7061 to 0.7136 and suggest different protolith compositions, consistent with mineralogical and geochemical characteristics of each pluton. The S‐type garnetbiotite granites (Ansons Bay and Booby alia granites) have initial ratios greater than 0.7119, indicative of enriched, high Rb/Sr ratio, crustal source‐rocks of Proterozoic age (1700–800 Ma). The S‐type biotite granites (Poimena and Pearson granites) have relatively high initial ⁸⁷Sr/⁸⁶Sr ratios (0.7070, 0.7105) but overlap with those of the I‐type granodiorites (George River, Scamander Tier, Pyengana and Coles Bay granodiorites) which are in the range of 0.7061 to 0.7073. The initial ratios of the enriched altered plutons are poorly constrained, and on both hand‐specimen and thin‐section scales, reveal open‐system Sr isotopic patterns.

Isochron ages for the arenite‐lutite and lutite sedimentary associations of the Mathinna Beds, which are intruded by the granitoids, reflect an approach to Sr isotopic equilibrium during regional metamorphism. The metamorphic age (401 ± 7 Ma) of the early Pragian arenite‐lutite association indicates a relatively small time interval between deposition, regional metamorphism and granitoid intrusion. The isotopic age for the lutite sedimentary association (423 ± 22 Ma) is tentatively correlated with a Benambran‐age burial metamorphic event that has not previously been recorded in Tasmania.     

Chemical and strontium isotopic characteristics of shallow groundwater in the Ordos Desert Plateau,North China: Implications for the dissolved Sr source and water–rock interactions

In this study, the chemical and Sr isotopic compositions of shallow groundwater and rainwater in the Ordos Desert Plateau, North China, and river water from the nearby Yellow River, are investigated to determine the dissolved Sr source and water–rock interactions, and quantify the relative Sr contribution from each end-member. Three groundwater systems have been identified, namely, GWS-1, GWS-2 and GWS-3 according to the watershed distribution in the Ordos Desert Plateau. Ca²⁺ and Mg²⁺ are the most dominant cations in GWS-1, while Na⁺ is dominant in GWS-3. In addition, there is more SO₄²⁻ and less Cl⁻ in GWS-1 than in GWS-3. The shallow groundwater in GWS-2 seems to be geochemically between that in GWS-1 and GWS-3. The ⁸⁷Sr/⁸⁶Sr ratios of the shallow groundwater are high in GWS-1 and GWS-2 and are low in GWS-3. By geochemically comparing the nearby Yellow River, local precipitation and deep groundwater, the shallow groundwater is recharged only by local precipitation. The ionic and isotopic ratios indicate that carbonate dissolution is an important process controlling the chemistry of the shallow groundwater. The intensity of the water–rock interactions varies among the three groundwater systems and even within each groundwater system. Three end-members controlling the groundwater chemistry are isotopically identified: (1) precipitation infiltration, (2) carbonate dissolution and (3) silicate weathering. The relative Sr contributions of the three end-members show that precipitation infiltration and carbonate dissolution are the primary sources of the shallow groundwater Sr in GWS-3 whereas only carbonate dissolution is responsible for the shallow groundwater Sr in GWS-1 and GWS-2. Silicate weathering seems insignificant towards the shallow groundwater's chemistry in the Ordos Desert Plateau. This study is helpful for understanding groundwater chemistry and managing water resources.     

Pb,Sr,Nd同位素与辽河油田油源对比

对辽河油田原油、有机质的Pb ,Sr,Nd同位素进行了研究。原油、有机质的Pb ,Sr ,Nd同位素资料和分析表明 :在辽河油田 ,仅有极少部分原油与老第三系有机质热解有关 ,大部分原油为地幔流体与古生界、震旦系海相碳酸盐岩壳幔相互作用而生成 ,另一大部分则为地幔流体的CO ,CO2 与H2 的费托合成反应生成。油源对比表明 :老第三纪以下的古生代前陆盆地有更大的油气前景。     

Age and strontium‐isotope geochemistry of differentiated rocks from the newer Volcanics,MT Macedon Area,Victoria, Australia

The Newer Volcanics Province of Victoria and South Australia consists of a major region of mainly alkaline basalts within which are two restricted areas containing strongly differentiated flow‐rocks. Typical alkalic basalts from this widespread province have K‐Ar ages from 4.5 to 0.5 m.y. and initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7038 to 0.7045. Contrastingly, in the Macedon area of differentiated lavas, flow compositions range from limburgite to soda trachyte, with K‐Ar ages from 6.8 to 4.6 m.y. and initial ⁸⁷Sr/⁸⁶Sr ratios from 0.7052 to 0.7127. These differentiated rocks therefore are older, and some of them may have been contaminated by reaction with more radiogenic basement rocks during differentiation. Alternatively, the variation in initial Sr‐isotope composition may have resulted from varying isotopic composition of partial melts from the immediate source rocks. The most felsic of the differentiated rocks, soda trachyte, is extremely enriched with Rb relative to Sr; one of the three restricted outcrops of this rock (Camel's Hump) yields a total‐rock Rb‐Sr isochron age of 6.3 ± 0.6 m.y. with an initial ⁸⁷Sr/⁸⁶Sr ratio of 0.7127. K‐Ar sanidine ages reported for the three outcrops of trachyte are identical to each other and to the Rb‐Sr isochron result.     

大别山麻粒岩和TTG片麻岩的Sr,Nd,Pb同位素地球化学

北大别4个麻粒岩和4个TTG片麻岩样品的Sr,Nd同位素分析结果表明，样品普遍具有较高的锶同位素比值（^87Sr/^86Sr=0.7066-0.7461)，较低的Nd同位素比值（^143Nd/^144Nd=0.5108-0.5124)，表现出明显的壳源特征，结合铅同位素的组成来看，北大别麻粒岩及TTG片麻岩的同位素成分相当于－下地壳。岩石的特源为古老的地壳，大约在2－3Ga之间，少数样品的同位素特征可能暗示源区有年轻地壳物质的加入。     

Rubidium‐strontium geochronology of the encounter bay granite and adjacent Metasedimentary rocks,South Australia

Rubidium‐strontium and strontium isotope data for eight whole‐rock samples of granite varieties from the Encounter Bay area, South Australia, yield an isochron age of 487 ± 37 m.y. Two specimens of albitised granite, formed as a result of late‐stage metasomatic alteration of original megacrystic granite, conform to this isochron. These data support a genetic relation between granites and late‐stage metasomatic alteration as suspected from field, petrographical and geochemical studies. Eight samples from contiguous Kanmantoo Group metasedimentary rocks have an isochron age of 487 ± 60 m.y. Thus this metamorphic event is coincident with emplacement of the Encounter Bay Granite.

The initial Sr⁸⁷Sr⁸⁶ ratio for the Encounter Bay Granite (0.719) is significantly higher than initial ratios for the Palmer (0.709) and Anabama (0.705) Granites from the same region and can be attributed to either remobilisation or incorporation of strontium from older crustal material in the intrusion. The apparent initial Sr⁸⁷/Sr⁸⁶ ratio for the Kanmantoo Group metasedimentary rocks (0.722) can not be distinguished from that for the Encounter Bay Granite within the analytical uncertainties. Compatability of ages and high initial Sr⁸⁷Sr⁸⁶ ratios suggest that the granites formed by remobilisation of associated crustal rock.     

Geochemistry,isotopic composition (δO, δH,Sr/Sr,Nd/Nd) in the groundwater of French Guiana as indicators of their origin,interrelations

The current use of untreated river water for drinking purposes by the population of French Guiana has important impacts on public health. Consequently, groundwater is of major importance as a possible alternative drinking water supply to reduce these impacts. Since French Guiana belongs to the Guyana Shield, sustainable water management can be expected to depend increasingly on water from fissured aquifers in hard rocks. Groundwater samples were collected from shallow drill holes in the densely populated coastal area, and deeper wells in the basement (around Cayenne and along the Maroni and Oyapock rivers). This study reports on major and trace elements for which Na⁺ and Ca²⁺ excess with regard to Cl reflect the role of water-rock interaction, as well as Sr and Nd isotopes that reflect the role of the different lithologies. δ¹⁸O and δD in waters give constraints on the water cycle (recharge and evaporation processes).     

安徽的地壳演化:Sr,Nd同位素证据

在地壳(幔)演化和板块构遣的框架内，评述了有关安徽南部(扬子地块东部，包括大别遣山带和江南遣山带)的同位素地质年代学和Nd，Sr同位素地球化学示踪研究的成果。该地区出露地表的中元古界溪口群浅变质岩代表皖南的基底，沿江地区和大别山区的基底包舍太古宇或／和古元古界古老岩石。此格局还影响到从震旦纪到古生代沉积岩的物源区，江南深断裂以北的沉积岩中有古老岩石的贡献，而以南的物源主要来自出露的中元古界岩石。扬子陆块南北缘(大别和江南遣山带)的晋宁期演化可能与罗迪尼亚超大陆演化有密切关系，但有关研究开展很少。三叠纪大陆深俯冲和超高压变质作用研究已成为国际地球科学的热点。晚中生代(120-140Ma)本区发生强烈的岩浆活动，并伴有重要矿床的形成。中酸性岩的形成是一种壳幔物质混合的过程。沿江地区陆下地幔具有富集特征，为扬子型岩石圈地幔与软流圈地幔混合的产物。从晚中生代到第四纪，基性岩指示其源区的地球化学性质有随时间变得越来越亏损的趋势。     

桂林地区岩溶水87Sr/86Sr特征

锶是岩石圈上部含量最大的微量元素，其元素及其同位素化学性质都比较稳定。不同水岩作用条件下，锶元素含量及其同位素值都不一样。本文通过对桂林地区的两个典型岩溶地下河系统不同类型地下水样87Sr/86Sr值和Sr含量的分析，得出；流经不同岩层的地下水其87Sr/86Sr值和Sr含量不同，同一地下河系统中不同类型地下水的87Sr/86Sr值Sr含量不同，其值的差异由岩性和水岩作用决定。说明87Sr/86Sr值能反映地下水的形成、径流和混合作用，是较理想的示踪剂，在岩溶水研究中具有很广阔的应用前景。     

长江,黄河流域泛滥平原细粒沉积物^87Sr＼^86Sr空间变异的制约因 …

黄河和长江流域泛滥平原细粒沉积物的Ｓｒ同位素组成存在较大差异。前者的＾８７Ｓｒ／＾８６Ｓｒ变化范围较小,为０．７１２８６８～０．７１８８６０,平均值为０．７１５４７４;后者变化范围较大,为０．７１３０３５～０．７３６５０２,平均值为０．７２１４３８。黄河流域中、上海细粒沉积物的＾８７Ｓｒ／８７Ｓｒ低于下游;而长江流域细粒沉积物的＾８７Ｓｒ／＾８６Ｓｒ中游高于上、下游,且南侧高于北侧。由ＮＷ向ＳＥ,     

Rb‐Sr systematics of the Coolgarra Batholith,North Queensland

The Coolgarra Batholith in north‐east Queensland is composed of the Go Sam and Nettle granite suites which were emplaced approximately 314 Ma ago. Initial ⁸⁷Sr/⁸⁶Sr ratios of the Nettle Suite appear to be marginally above 0.710, a value characteristic of a wide range of Late Palaeozoic felsic igneous rocks in the region. This suite appears to have been derived from an extensive isotopically homogeneous crustal source distinct from rocks which crop out in the Palaeozoic Hodgkinson Basin or Precambrian Georgetown Inlier. Higher and more variable initial ⁸⁷Sr/⁸⁶Sr ratios (0.727–0.744) of the Go Sam Suite are attributed to a combination of magmatic and hydrothermal processes. Isotopic data, thus, cannot be used to constrain the nature of the Go Sam source rocks. Tungsten (with or without tin) mineralization is associated with the Nettle Suite plutons, with which it shares a common age, whereas the Go Sam Suite is characterized by prominent tin mineralization. One tin occurrence is the same age as, or only slightly younger than, the Nettle Suite tungsten (with or without tin) mineralization. Another tin deposit yields an age of 301 Ma, suggesting the presence of a significantly younger granite at depth.     

The rubidium‐strontium ages of some Tasmanian igneous rocks

Rb‐Sr isotopic age measurements relate emplacement of the Pieman and Meredith Granites (356 ± 9 and 353 ± 7 m.y., respectively), and the Bischoff and Renison Bell Porphyries (349 ±4 and 355 ± 4 m.y., respectively) to the Tabberabberan Orogeny. The genetic relationship of the Bischoff Porphyry to mineralization and the agreement between the age of this porphyry and the age of the adjacent Meredith Granite, strongly suggests that the Bischoff mineralization resulted from granite intrusion.

The Pieman Granite is closely similar to the white Heemskirk Granite in displaying a high initial ⁸⁷Sr/⁸⁶Sr ratio (0.7354 ± 0.0018), feldspar discordance patterns and open system total‐rock behaviour. The high initial ⁸⁷Sr/⁸⁶Sr ratio is attributed to contamination during intrusion by Precambrian metasediments containing appreciable radiogenic strontium.

A basic intrusion (McIvors Hill Gabbro) gave a pre‐Tabberabberan age (518 ±133 m.y.) and a high initial ⁸⁷Sr/⁸⁶Sr ratio (0.7132 ± 0.0031).     

Zinc,copper, and strontium isotopic variability in the Baiyangping Cu–Pb–Zn–Ag polymetallic ore field,Lanping Basin,Southwest China

Acta Geochimica - The Baiyangping Cu–Ag polymetallic ore district is located in the northern part of the Lanping-Simao foreland fold belt, between the Jinshajiang-Ailaoshan and Lancangjiang...     

Sr, C and O isotope systematics in the Pucará basin, central Peru

A combined Sr, O and C isotope study has been carried out in the Pucará basin, central Peru, to compare local isotopic trends of the San Vicente and Shalipayco Zn-Pb Mississippi Valley-type (MVT) deposits with regional geochemical patterns of the sedimentary host basin. Gypsum, limestone and regional replacement dolomite yield ⁸⁷Sr/⁸⁶Sr ratios that fall within or slightly below the published range of seawater ⁸⁷Sr/⁸⁶Sr values for the Lower Jurassic and the Upper Triassic. Our data indicate that the Sr isotopic composition of seawater between the Hettangian and the Toarcian may extend to lower ⁸⁷Sr/⁸⁶Sr ratios than previously published values. An ⁸⁷Sr-enrichment is noted in (1) carbonate rocks from the lowermost part of the Pucará basin, and (2) different carbonate generations at the MVT deposits. This indicates that host rocks at MVT deposits and in the lower-most part of the carbonate sequence interacted with ⁸⁷Srenriched fluids. The fluids acquired their radiogenic nature by interaction with lithologies underlying the carbonate rocks of the Pucará basin. The San Ramón granite, similar Permo-Triassic intrusions and their clastic derivatives in the Mitu Group are likely sources of radiogenic ⁸⁷Sr. The Brazilian shield and its erosion products are an additional potential source of radiogenic ⁸⁷Sr. Volcanic rocks of the Mitu Group are not a significant source for radiogenic ⁸⁷Sr; however, molasse-type sedimentary rocks and volcaniclastic rocks cannot be ruled out as a possible source of radiogenic ⁸⁷Sr. The marked enrichment in ⁸⁷Sr of carbonates toward the lower part of the Pucará Group is accompanied by only a slight decrease in ¹⁸O values and essentially no change in ¹³C values, whereas replacement dolomite and sparry carbonates at the MVT deposits display a coherent trend of progressive ⁸⁷Sr-enrichment, and ¹⁸O- and ¹³C-depletion. The depletion in ¹⁸O in carbonates from the MVT deposits are likely related to a temperature increase, possibly coupled with a ¹⁸O-enrichment of the ore-forming fluids. Progressively lower ¹³C values throughout the paragenetic sequence at the MVT deposits are interpreted as a gradually more important contribution from organically derived carbon. Quantitative calculations show that a single fluid-rock interaction model satisfactorily reproduces the marked ⁸⁷Sr-enrichment and the slight decrease in ¹⁸O values in carbonate rocks from the lower part of the Pucará Group. By contrast, the isotopic covariation trends of the MVT deposits are better reproduced by a model combining fluid mixing and fluid-rock interaction. The modelled ore-bearing fluids have a range of compositions between a hot, saline, radiogenic brine that had interacted with lithologies underlying the Pucará sequence and cooler, dilute brines possibly representing local fluids within the Pucará sequence. The composition of the local fluids varies according to the nature of the lithologies present in the neighborhood of the different MVT deposits. The proportion of the radiogenic fluid in the modelled fluid mixtures interacting with the carbonate host rocks at the MVT deposits decreases as one moves up in the stratigraphic sequence of the Pucará Group.     

Sr,Nd,Pb Isotope Geochemistry and Magma Evolution of the Potassic Volcanic Rocks,Wudalianchi,Northeast China

Wudalianchi volcanic rocks are the most typical Cenozoic potassic volcanic rocks in easten China.Compositional comparisons between whole rocks and glasses of various occurrences indicate that the magma tends to become rich in silica and alkalis as a result of crystal differentiation in the course of evolu-tion.They are unique in isotopic composition with more radiogenic Sr but less radiogenic Pb.^87Sr/^86Sr is higher and ^143Nd/^144Nd is lower than the undifferentiated global values.In comparison to continental pot-ash volcanic rocks,Pb isotopes are apparently lower.These various threads of evidence indicate that the rocks were derived from a primary enriched mantle which had not been subjected to reworking and shows no sign of incorporation of crustal material.The correlation between Pb and Sr suggests the regional heterogeneity in the upper mantle in terms of chemical composition.     

Anticorrelated Rb−Sr and K−Ar age discordances,Leuchtenberg granite,NE Bavaria,Germany

The Leuchtenberg granite (Oberpfalz, NE Bavaria) displays a continuous differentiation trend ranging from mildy peraluminous, coarse-grained, porphyritic biotite granites (BG) to strongly peraluminous, medium- to fine-grained, garnet-bearing muscovite granites (GMG). The Rb–Sr and K–Ar age determinations of whole-rock and mineral samples from the granite and associated intermediate rocks (redwitzites) have revealed two divergent age gradients: Rb–Sr wholerock dates decrease and initial ⁸⁷Sr/⁸⁶Sr ratios increase for successively more evolved subsets of the granite. All BG samples (⁸⁷Rb/⁸⁶Sr=2–16) yield a date of 326±2 Ma with a low initial ⁸⁷Sr/⁸⁶Sr ratio of 0.70778±0.00013 (1), while all GMG samples (⁸⁷Rb/⁸⁶Sr=70 to 1000) yield a younger date of 317±2 Ma with an enhanced initial ⁸⁷Sr/⁸⁶Sr ratio of 0.7146±0.0039. The K–Ar measurements on biotites and muscovites give closely concordant dates for the GMG (326–323 Ma) and the southern lobe of the BG (324–320 Ma). The northern lobe of the BG, including the redwitzites, shows a well-defined trend of decreasing K–Ar dates from 320 Ma to 300 Ma towards the northwest. Critical consideration of both isotope systems leads to the conclusion that the Rb–Sr system of the GMG was disturbed by a later hydrothermal event. The ca. 326 Ma whole-rock Rb–Sr date for the BG is not in conflict with any of the K–Ar mineral dates and is taken as approaching the crystallization age of the Leuchtenberg granite. The K–Ar age progression within the northern lobe of the BG indicates that this part either cooled down over a protracted period of some 20 Ma or experienced reheating at ca. 300 Ma. The study highlights the potential of combined Rb–Sr and K–Ar dating in deciphering detailed chronology on the scale of a single igneous intrusion.