Excess heat capacity and entropy of mixing along the chlorapatite–fluorapatite binary join

The heat capacity at constant pressure, C _p, of chlorapatite [Ca₅(PO₄)₃Cl – ClAp], and fluorapatite [Ca₅(PO₄)₃F – FAp], as well as of 12 compositions along the chlorapatite–fluorapatite join have been measured using relaxation calorimetry [heat capacity option of the physical properties measurement system (PPMS)] and differential scanning calorimetry (DSC) in the temperature range 5–764 K. The chlor-fluorapatites were synthesized at 1,375–1,220°C from Ca₃(PO₄)₂ using the CaF₂–CaCl₂ flux method. Most of the chlor-fluorapatite compositions could be measured directly as single crystals using the PPMS such that they were attached to the sample platform of the calorimeter by a crystal face. However, the crystals were too small for the crystal face to be polished. In such cases, where the sample coupling was not optimal, an empirical procedure was developed to smoothly connect the PPMS to the DSC heat capacities around ambient T. The heat capacity of the end-members above 298 K can be represented by the polynomials: C _p^ClAp = 613.21 − 2,313.90T ^−0.5 − 1.87964 × 10⁷ T ⁻² + 2.79925 × 10⁹ T ⁻³ and C _p^FAp = 681.24 − 4,621.73 × T ^−0.5 − 6.38134 × 10⁶ T ⁻² + 7.38088 × 10⁸ T ⁻³ (units, J mol⁻¹ K⁻¹). Their standard third-law entropy, derived from the low-temperature heat capacity measurements, is S° = 400.6 ± 1.6 J mol⁻¹ K⁻¹ for chlorapatite and S° = 383.2 ± 1.5 J mol⁻¹ K⁻¹ for fluorapatite. Positive excess heat capacities of mixing, ΔC _p^ex, occur in the chlorapatite–fluorapatite solid solution around 80 K (and to a lesser degree at 200 K) and are asymmetrically distributed over the join reaching a maximum of 1.3 ± 0.3 J mol⁻¹ K⁻¹ for F-rich compositions. They are significant at these conditions exceeding the 2σ-uncertainty of the data. The excess entropy of mixing, ΔS ^ex, at 298 K reaches positive values of 3–4 J mol⁻¹ K⁻¹ in the F-rich portion of the binary, is, however, not significantly different from zero across the join within its 2σ-uncertainty.     

Atlanta’s urban heat island under extreme heat conditions and potential mitigation strategies

The urban heat island (UHI), together with summertime heat waves, foster’s biophysical hazards such as heat stress, air pollution, and associated public health problems. Mitigation strategies such as increased vegetative cover and higher albedo surface materials have been proposed. Atlanta, Georgia, is often affected by extreme heat, and has recently been investigated to better understand its heat island and related weather modifications. The objectives of this research were to (1) characterize temporal variations in the magnitude of UHI around Metro Atlanta area, (2) identify climatological attributes of the UHI under extremely high temperature conditions during Atlanta’s summer (June, July, and August) period, and (3) conduct theoretical numerical simulations to quantify the first-order effects of proposed mitigation strategies. Over the period 1984–2007, the climatological mean UHI magnitude for Atlanta-Athens and Athens-Monticello was 1.31 and 1.71°C, respectively. There were statistically significant minimum temperature trends of 0.70°C per decade at Athens and −1.79°C per decade at Monticello while Atlanta’s minimum temperature remained unchanged. The largest (smallest) UHI magnitudes were in spring (summer) and may be coupled to cloud-radiative cycles. Heat waves in Atlanta occurred during 50% of the years spanning 1984–2007 and were exclusively summertime phenomena. The mean number of heat wave events in Atlanta during a given heat wave year was 1.83. On average, Atlanta heat waves lasted 14.18 days, although there was quite a bit of variability (standard deviation of 9.89). The mean maximum temperature during Atlanta’s heat waves was 35.85°C. The Atlanta-Athens UHI was not statistically larger during a heat wave although the Atlanta-Monticello UHI was. Model simulations captured daytime and nocturnal UHIs under heat wave conditions. Sensitivity results suggested that a 100% increase in Atlanta’s surface vegetation or a tripling of its albedo effectively reduced UHI surface temperature. However, from a mitigation and technological standpoint, there is low feasibility of tripling albedo in the foreseeable future. Increased vegetation seems to be a more likely choice for mitigating surface temperature.     

A compilation of Australian heat‐flow measurements

A map is presented based on all known Australian heat‐flow estimates, including five new ones. A second map, based on the first, also is presented, but excludes any determinations judged for any reason to be unreliable. The data show that heat flow over large areas of the continent is effectively uniform to within 0.5 heat flow units (i.e. to within 20 mW m^‐2), with perhaps three major regional heat‐flow provinces being defined in western, central, and eastern Australia.     

Phanerozoic tin and tungsten mineralization—Tectonic controls on the distribution of enriched protoliths and heat sources for crustal melting

Phanerozoic primary tin and tungsten deposits and lithium–cesium–tantalum (LCT) type pegmatites define discontinuous belts that reach several thousand kilometers length. Mineralization along these belts is irregularly distributed, diachronous, and occurs in different tectonic settings on both sides of major sutures. Although these deposits formed during late magmatic differentiation processes, magmatism may be related to different geodynamic settings, in particular subduction, continental collision, and anorogenic extension. Here we test the hypothesis that the formation of these belts is explained by a generic process, involving three independent steps as prerequisite for the development of deposits: (i) intense chemical weathering of sedimentary rocks on a stable continent resulting in the enrichment of Sn and W in the protoliths, (ii) sedimentary—followed by tectonic—accumulation of the enriched debris at continent margins, and (iii) heating of the voluminous sedimentary protoliths generating Sn and/or W enriched melts. The Sn and/or W belts reflect the spatial distribution of enriched protoliths, whereas the discontinuous distribution of Sn and W mineralization within the belts reflects both, the locally extreme sedimentary and tectonic accumulation and the distribution of heat sources.

• (i)Intense chemical weathering results in the preferential loss of most feldspar-bound elements (e.g., Na, Ca, Sr, and Pb) and the residual enrichment of elements incorporated in or adsorbed on clay minerals (e.g., Li, K, Rb, Cs, Sn, and W), i.e., produces some of the hallmark geochemical signatures of tin granites that also are obtained by extreme magmatic fractionation of granitic melts. Intense chemical weathering occurs in tectonically stable areas with limited topography and may be particularly pronounced in the interior of large continental masses, such as late Proterozoic Rodinia, late Proterozoic to Cambrian Gondwana, and late Paleozoic to early Mesozoic Pangea.
• (ii)Sedimentary accumulation occurs when these blankets of chemically intensely weathered sediments are redistributed from the continent interior to the margins of the continent. This fluviatile redistribution is typically related to the fragmentation of megacontinents or supercontinents. Tectonic accumulation may occur when passive-margin sedimentary packages later are reworked in an active margin setting.
• (iii)The nature of the heat source controls type of mineralization and its relation to plate boundaries. Internal heating in orogenically thickened crust generates minimum-temperature melts that mobilize elements hosted in feldspar and muscovite and may generate granites and pegmatites with LCT-type signature. The formation of Sn and W mineralization requires higher temperatures to consume biotite. Such temperatures require heat advection from the mantle by (a) mantle-derived melts in subduction setting, (b) emplacement of ultrahigh-temperature metamorphic rocks that had been subducted to mantle depth during continental collision, or (c) mantle-derived melts in extensional settings. The age of mineralization within belt reflects the event of heat input.

The distribution of Sn and W mineralization within belts is the superposition of processes at the passive margin and processes at the active margin. Source enrichment and distribution is related to megacontinents (chemical weathering) and their fragmentation (sedimentary accumulation at the margin of fragments from a megacontinent). Therefore, Sn and W belts generally border to fragments of former megacontinents. Metal mobilization from the source rocks is controlled by the distribution of the heat sources and, thus, by processes at an active margin. The generic model explains both the arrangement of Sn and W mineralization in belts and their distribution with the belts. It allows for recurrent formation of mineralization within a single belt in contrasting tectonic settings and to both sides of major sutures. With source enrichment and source accumulation being necessary requirements of mineralization, the generic model also explains unmineralized gaps within Sn and W belts and why there are unmineralized magmatic belts of comparable setting and with granitic rocks of comparable magmatic development. Areas without voluminous packages of enriched protoliths or without ample heat sources to mobilize the ore elements from the protoliths have a low potential for hosting Sn and W mineralization.     

Geochemistry of mafic rocks and melt inclusions and their implications for the heat source of the 14.0°S hydrothermal field,South Mid-Atlantic Ridge

Fresh rocks sampled from the 14.0°S hydrothermal field of the South Atlantic Ridge can be divided into two categories： olivine-gabbro and basalt. The olivine-gabbro is composed mainly of three types of minerals： olivine, clinopyroxene and plagioclase, while a multitude of melt inclusions occur in the plagioclase phenocrysts of the basalts. We analyzed the whole-rock, major and trace elements contents of the basaks, the mineral chemistry of phenocrysts and melt inclusions in the basalts, and the mineral chemistry of olivine-clinopyroxene-plagioclase in the olivine-gabbro, then simulated magma evolution within the crust using the COMAGMAT program. The whole-rock geochemistry shows that all the basalts exhibit typical N-MORB characteristics. In addition, the mineral chemistry characteristics of the olivine-gabbro （low-Fo olivine, low-Mg# clinopyroxene, high-TiO2 clinopyroxene, low-An plagioclase）, show that strong magma differentiation occurred within the crust. Nevertheless, significant discrepancies between those minerals and phenocrysts in the basalts （high-Fo olivine, high-An plagioclase） reflect the heterogeneity of magma differentiation. High Mg# （-~0.72） melt inclusions isobaric partial crystallization simulations suggest that the magma differentiation occurred at the depth shallower than 13.03 km below the seafloor, and both the vertical differentiation column shows distinct discrepancies from that of a steady-state magma chamber. Instead, a series of independent magma intrusions probably occurred within the crust, and their corresponding crystallized bodies, as the primary high-temperature thermal anomalies within the off-axis crust, probably act as the heat source for the development of the 14.0°S hydrothermal system.     

Landscape features and potential heat hazard threat: a spatial–temporal analysis of two urban universities

Urban universities are a microcosm of urban built-up areas, such as cities, but with a much smaller scale of spatial resolution. Within universities, there are many types of landscape features exhibiting different heat absorption and transmission capacities. These landscape features generate spatial–temporal heat signatures, and the knowledge about landscape features and urban heat hazard on university campuses is limited. The objective of this research is an assessment of landscape features and the potential heat hazard threats of two urban universities in ASEAN, located in the centre of the equatorial region. The focus of this research is on urban heat hazards in two urban universities in ASEAN, the University of Malaysia in Kuala Lumpur and the University of Indonesia in Jakarta, within the context of the spatial–temporal behaviour of urban heat and the urban heat effects on the environment and human well-being on campuses. The spatial and temporal analysis used to answer the objective of this research via data-gathering methods from image satellite, ground trough, and human perception study. The UM campus and UI campus, both urban campuses, had similar landscape features but had different total percentage areas of these features. The UM campus was 59.1% covered by the densely vegetated surface landscape feature, a percentage lower than that of the UI campus, which was 65.3% vegetation covered. The temporal results for the UHS of the UM campus in 2013–2016 show a maximum temperature of 39 °C. Therefore, the UHS of the UI campus demonstrated temporal behaviour in 2013–2016, with a maximum temperature of 38 °C. The UHS behaviour of the UM campus and UI campus had an air surface temperature with a maximum average temperature of 33 °C. The air surface temperatures exceeding 32 °C at the UM campus (12 pm until 6 pm?=?5 h) lasted for a longer time than those at the UI campus (12 pm until 3 pm?=?3 h). This study showed that, based on the perceptions on both campuses, if temperatures exceeded 30 °C, respondents were very hot and very uncomfortable, which will impact health and decrease work or academic achievements, as perceptions of heat intensity impact human well-being. Students perceived that heat intensity impacted their health and they reported becoming tired and lethargic under maximum temperatures and were very hot and very uncomfortable, and this condition impacted their work activity. These results indicated that, at both the UM and UI campuses, heat intensity impacts human well-being, with risks associated with hot temperatures. These two urban campuses are significant for ASEAN university awareness of the urban heat hazard of the equatorial area.     

Spherical harmonic analysis of earth’s conductive heat flow

A reappraisal of the international heat flow database has been carried out and the corrected data set was employed in spherical harmonic analysis of the conductive component of global heat flow. Procedures used prior to harmonic analysis include analysis of the heat flow data and determination of representative mean values for a set of discretized area elements of the surface of the earth. Estimated heat flow values were assigned to area elements for which experimental data are not available. However, no corrections were made to account for the hypothetical effects of regional-scale convection heat transfer in areas of oceanic crust. New sets of coefficients for 12° spherical harmonic expansion were calculated on the basis of the revised and homogenized data set. Maps derived on the basis of these coefficients reveal several new features in the global heat flow distribution. The magnitudes of heat flow anomalies of the ocean ridge segments are found to have mean values of less than 150 mW/m². Also, the mean global heat flow values for the raw and binned data are found to fall in the range of 56–67 mW/m², down by nearly 25% compared to the previous estimate of 1993, but similar to earlier assessments based on raw data alone. To improve the spatial resolution of the heat flow anomalies, the spherical harmonic expansions have been extended to higher degrees. Maps derived using coefficients for 36° harmonic expansion have allowed identification of new features in regional heat flow fields of several oceanic and continental segments. For example, lateral extensions of heat flow anomalies of active spreading centers have been outlined with better resolution than was possible in earlier studies. Also, the characteristics of heat flow variations in oceanic crust away from ridge systems are found to be typical of conductive cooling of the lithosphere, there being little need to invoke the hypothesis of unconfined hydrothermal circulation on regional scales. Calculations of global conductive heat loss, compatible with the observational data set, are found to fall in the range of 29–34 TW, nearly 25% less than the 1993 estimate, which rely on one-dimensional conductive cooling models.     

The response of the Gulf of Mexico to wind and heat flux forcing: What has been learned in recent years?

The Loop Current and its shed eddies dominate the circulation and dynamics of the Gulf of Mexico (GoM) basin. Those eddies are strongly energetic and are the cause of intense currents that may penetrate several hundred meters deep. However, there are regions in the GoM and periods of time in which the local atmospheric forcing plays an important role in its dynamics and thermodynamics. The circulation on the shelves, and particularly on the inner shelf, is mainly wind-driven with seasonality, changing direction during the year with periods of favorable upwelling/downwelling conditions. The wind-driven circulation is associated with the transport of waters with different temperature and salinity characteristics from one region to another. The interannual variability of the circulation on the shelves is linked to the atmospheric variability. Intraseasonal variability of the wind patterns considerably affects the likelihood and magnitude of upwelling and downwelling. The geometry of the GoM is such that large-scale winds may drive opposing upcoast/downcoast currents along different parts of the curving coast, resulting in convergence or divergence zones. The width of the shelves in the GoM is variable;while the West Florida Shelf, the Texas-Louisiana shelf and the Campeche Bank are more than 200 km wide, they are narrower near Veracruz and Tabasco. Another consequence of the GoM physiography and the wind forcing is the development of cross-shelf transports in the southern Bay of Campeche, the southern Texas shelf and southeast of the Mississippi river, which in turn vary during the year. During autumn-winter (from September to April), the GoM is affected by cold fronts coming from the northwest United States, which are associated with strong, dry, and cold winds that mix its waters and generate large sensible and latent heat fluxes from the ocean to the atmosphere. These frontal passages also cool the GoM surface waters due to mixing with lower temperature subsurface waters. During summer, tropical cyclones crossing the GoM can dramatically affect circulation and coastal upwelling.     

Thermodynamic mixing behavior of synthetic Ca-Tschermak–diopside pyroxene solid solutions: III. An analysis of IR line broadening and heat of mixing behavior

A series of synthetic Ca-Tschermak–diopside (CaAlAlSiO₆–CaMgSi₂O₆) clinopyroxenes were investigated by powder infrared spectroscopy at room temperature in the wavenumber range 80–2,000 cm⁻¹. Measurable local structural heterogeneities in the crystals are suggested by the line broadening parameter, Δcorr that are observed for intermediate solid-solution compositions. The broadening is most pronounced in the high wavenumber region of the IR spectra that contains stretching modes involving the TO₄ polyhedra. The effective line widths for three selected wavenumber regions deviate positively from linear behavior. This is also observed for the enthalpy of mixing of this solid solution. The relationship between “excess Δcorr”, δΔcorr, and heat of mixing, ΔH _mix, behavior was investigated for this clinopyroxene series and for several other binary silicate solid solutions. The ΔH _mix versus δΔcorr slope values show a linear relationship with respect to the integrated excess volume of the various solid solutions.     

Fracture mechanism of rock collapse in the freeze–thaw zone of the eastern Sichuan–Tibet Mountains under seasonal fluctuating combinations of water and heat

Natural Hazards - In the freeze–thaw zone of the eastern Sichuan–Tibet Mountains, the phases of water in cracks show strong seasonal variations, which significantly affect the stability...     

Model or measurements? A discussion of the key issue in Chapman and Pollack’s critique of Hamza et al.’s re-evaluation of oceanic heat flux and the global power

Chapman and Pollack (C and P)[2007, Int J Earth Sci] criticize Hamza et al. [2007, Int J Earth Sci] for using actual heat flux measurements in young oceanic crust instead of values from 1-D cooling models. The rationalization of C and P and previous authors is that hydrothermal circulation causes the discrepancy between model and measurement. However, the discrepancy between model values and measured heat flux exists over the entire ocean floor and is opposite to the perturbations that hydrothermal circulation would superimpose on a conductive system [Hofmeister and Criss (2005) Tectonophysics 409:199–203]. The error lies in force-fitting a 1-D cooling model to the 3-D oceanic crust [Hofmeister and Criss (2005) Tectonophysics 395:159–177]. Shortcomings of the 1-D model include mathematical errors, such as use of volumetric rather than linear thermal expansivity to describe contraction which, by assumption, is limited only to the Z -direction [Hofmeister and Criss (2006) Tectonophysics]. This 3× error, traceable to McKenzie and Sclater [1969, Bull Vocanol 33–1:101–118], accidentally provides good agreement of model values with globally averaged seafloor depths for young, but not old ages, and is the sole rationale for using the simplistic cooling model. There is no justification for selective substitution of erroneous 1-D model values for measurements only for the younger half of the 3-D oceanic crust, as stridently and arbitrarily promoted by C and P. Hamza et al. [2007, Int J Earth Sci], in contrast, use the scientific method, which calls for discarding models that do not well describe physical phenomena. The remainder of this report summarizes the shortcomings of cooling models, particularly the half-space cooling (HSC) model touted by C and P, and explains how hydrothermal circulation affects heat flux. We focus on the basics, as these have been misunderstood. With the key issues of C and P being erroneous, it is not necessary to address their remaining comments, many of which enumerate the vote for an imagined, gargantuan circulation of hot fluid through oceanic basins that is somehow warmed without removing heat from the rocks. The use of “consensus” to belittle valid challenge is the enemy of the scientific method.     

Diurnal variability of upper ocean temperature and heat budget in the southern Bay of Bengal during October–November, 1998 (BOBMEX-Pilot)

Time-series data on upper-ocean temperature, Vessel-Mounted Acoustic Doppler Current Profiler (VM-ADCP) measured currents and surface meteorological parameters have been obtained for the first time in the southern Bay of Bengal at 7‡N, 10‡N, and 13‡N locations along 87‡E during October–November, 1998 under BOBMEX-Pilot programme. These data have been analysed to examine the diurnal variability of upper oceanic heat budget and to estimate the eddy diffusivity coefficient of heat in the upper layer. Diurnal variation of near-surface temperature is typical at northern location (13‡N) with a range of 0.5‡C while the diurnal range of temperature is enhanced to 0.8‡C at the central location (10‡N) due to intense solar radiation (1050 W/m²), clear skies and low wind speeds. At the southern location (7‡N), the diurnal variation of temperature is atypical with the minimum temperature occurring at 2000 hrs instead of at early morning hours. In general, the diurnal curve of temperature penetrated up to 15 to 20 m with decreasing diurnal range with depth. The VM-ADCP measured horizontal currents in the upper ocean were predominantly easterly/northeasterly at southern location, north/northerly at central location and northwesterly at northern location, thus describing a large-scale cyclonic gyre with the northward meridional flow along 87‡E. The magnitudes of heat loss at the surface due to air-sea heat exchanges and in the upper 50 m layer due to vertical diffusion of heat are highest at the southern location where intense convective activity followed by overcast skies and synoptic disturbance prevailed in the lower atmosphere. This and the estimated higher value (0.0235 m²/s) of eddy diffusivity coefficient of heat in the upper ocean (0–50 m depth) suggest that 1-D processes controlled the upper layer heat budget at the southern location. On the other hand, during the fair weather conditions, at the central and northern locations, the upper layer gained heat energy, while the sea surface lost (gained) heat energy at northern (central) location. This and lower values of eddy diffusivity coefficient of heat (0.0045 and 0.0150 m²/s) and the northward intensification of horizontal currents at these locations suggest the greater role of horizontal heat advection over the 1-D processes in the upper ocean heat budget at these two locations.     

Heat flow–heat production relationship not found: what drives heat flow variability of the Western Canadian foreland basin?

International Journal of Earth Sciences - Heat flow high −80 ± 10 mW/m2 in the northern western parts of the Western Canadian foreland basin is in large...     

Crystallochemical effects of heat treatment on Fe-dominant tourmalines from Dolní Bory (Czech Republic) and Vlachovo (Slovakia)

Heat treatment was performed on selected Fe-dominant tourmalines to establish the nature of any change in optical properties. Two tourmaline samples from Dolní Bory, Czech Republic (TDB) and Vlachovo, Slovakia (TVL) were heated at 450, 700 and 900°C at 0.1 mPa and ambient oxidation conditions for 8 h. EMPA study shows that tourmaline from Vlachovo has schorlitic composition and tourmaline from Dolní Bory is alkali-depleted schorl to foitite. Although the black colour remained unchanged after heating at 450°C, it changed to brown at 700°C and reddish brown at 900°C. No significant changes of chemical composition were observed during heating. X-ray diffraction, infrared and Mössbauer study showed negligible oxidation of tourmaline heated at 450°C, but a significant change in iron valency state and deprotonization at 700°C. The oxidation of Fe is the main cause of tourmaline colour change, and the substitution vector for oxidation of Fe is Fe³⁺OFe _?1 ²⁺ (OH)_?1. The predicted deprotonization of OH was confirmed by infrared spectroscopy, which documented a decrease in OH groups in both samples, mainly at the V site. The oxidation of Fe is mostly significant in the Y site as documented on the compression of the Y-site octahedra and subsequent decrease in the a lattice parameter. This feature is consistent with lattice dimensions in the transition from schorl and foitite dimensions to those consistent with fluor-buergerite. The Z-site octahedra did not compressed and were not affected by heating-induced Fe oxidation, which indicates only negligible content of ^Z Fe²⁺ in original samples. After heating at 900°C, the tourmaline structure collapsed likely due to the thermally induced weakening of bonds in Y and Z octahedra, which results in amorphization of tourmaline. Subsequently, breakdown products including Fe-oxides and mullite replaced alkali-depleted amorphized tourmaline.     

Fourier’s heat conduction equation: History, influence, and connections

The equation describing the conduction of heat in solids has, over the past two centuries, proved to be a powerful tool for analyzing the dynamic motion of heat as well as for solving an enormous array of diffusion-type problems in physical sciences, biological sciences, earth sciences, and social sciences. This equation was formulated at the beginning of the nineteenth century by one of the most gifted scholars of modern science, Joseph Fourier of France. A study of the historical context in which Fourier made his remarkable contribution and the subsequent impact his work has had on the development of modern science is as fascinating as it is educational. This paper is an attempt to present a picture of how certain ideas initially led to Fourier’s development of the heat equation and how, subsequently, Fourier’s work directly influenced and inspired others to use the heat diffusion model to describe other dynamic physical systems. Conversely, others concerned with the study of random processes found that the equations governing such random processes reduced, in the limit, to Fourier’s equation of heat diffusion. In the process of developing the flow of ideas, the paper also presents, to the extent possible, an account of the history and personalities involved. Reprinted by permission from theAmerican Geophysical Union, @ 1999. Originally published inReviews of Geophysics as “Fourier’s Heat Conduction Equation: History, Influence and Connections,” Vol. 37, issue 1, pages 151–172, February 1999. Appended here are eight figures of historical importance.     

Hydrologic and hydraulic characteristics of the Yellow River and impact of flow and sediment diversion

In the history, the Yellow River nurtured Chinese civilization. It is respected as the ＂ancestor of the four large rivers in China＂ and praised as ＂the mother river of China＂. At the same time, the Yellow River is regarded as ＂the misery of China＂ and considered as the most complex river hard to control in the world. Today, the Yellow River is also one large river greatly influenced by human activities in the world. The safety of the Yellow River, particularly flood control, is always the most important issue for governing and developing the country. Great achievements have been made after many years of efforts for controlling the Yellow River. However, since the nineties of 20 century, some new problems occurred, such as sharp reduction of flux to sea, dry rivercourse, worsen environment, etc. Rapidly shrinking riverbed and two-level perched stream are disadvantageous to flood safety especially. The new concepts and new practices are urgently needed to control the river. Therefore, the Yellow River Conservancy Committee of Ministry of Water Resources had continuously carded out flow and sediment diversion each year from 2002 to 2005. To timely probe into the new issues produced after flow and sediment diversion, and in order to deepen the understanding of rules for the Yellow River＇s water and sediment and provide reference and experience to the researchers for other large rivers, five hydrologic and hydraulic characteristics of the Yellow River, such as lack of water, much of sediment, different resources of water and sediment, inconsistency between water and sediment and frequency of sink switching and route changing, are described. Flow and sediment diversion of the Yellow River is also reviewed. Under flow and sediment diversion,     

Cascaded Evolution of Mantle Plumes and Metallogenesis of Core- and Mantle-derived Elements

Mineral deposits are unevenly distributed in the Earth's crust, which is closely related to the formation and evolution of the Earth. In the early history of the Earth, controlled by the gravitational contraction and thermal expansion, lighter elements, such as radioactive, halogen-family, rare and rare earth elements and alkali metals, migrated upwards; whereas heavier elements, such as iron-family and platinum-family elements, base metals and noble metals, had a tendency of sinking to the Earth's core, so that the elements iron, nickel, gold and silver are mainly concentrated in the Earth's core. However, during the formation of the stratified structure of the Earth, the existence of temperature, pressure and viscosity differences inside and outside the Earth resulted in vertical material movement manifested mainly by cascaded evolution of mantle plumes in the Earth. The stratifications and vertical movement of the Earth were interdependent and constituted the motive force of the mantle-core movement.     

Geological Characteristics and Manifestations of Geological Processes of Sequence Boundaries and Their Vicinities

This paper discusses the geological characteristics and architectures of sequence boundaries and their vicinities and has proposed a classification scheme for the sequence boundaries, which can thus be grouped into three types and eight categories: type I includes exposed truncated surface, palaeosol surface, palaeokarst surface and exposed surface; type Ⅱ boundaries include structural transitional surface during sea-level fall and transgressive onlap surface; and type Ⅲ includes submarine erosional diagenetic diastem and event surface. A study has been made for the three major boundaries lying between the Permian and pre-Permian, the Permian and Triassic, and the Middle and Lower Triassic respectively in terms of multiple disciplines such as lithostratigraphy, biostratigraphy, magnetostratigraphy and carbon and oxygen isotopic geology. These three boundaries are ascribed to type I , typeⅡ and typeⅢ, respectively.