Fractals,fault-gouge,and friction

The particle-size distribution of a natural fault-gouge has been determined over the range from 5 m to 40 cm. The gouge is self-similar over the range from 5 m to 1 cm having a fractal dimension of 2.60±0.11. The lower and upper fractal limits were also determined. The lower fractal limit occurs at a dimension of about 1–10 m where mineral cleavage and intergranular porosity dominate the cataclasis. The upper fractal limit occurs at particle sizes on the order of 1 cm where the scaled particle density decreases abruptly by a factor of about three. By analogy to soil-mechanics shear box tests and laboratory rock friction experiments, it is argued that the upper fractal limit of the gouge determines the characteristic displacement parameter in stick-slip friction models. A characteristic displacement on the order of 1 cm is consistent with estimates based on numerical simulations of faulting.     

Sun, climate, hunger, and mass migration

Paleoclimatic studies indicate four epochs of global cooling during the last 4 000 years, i. e. during the few centuries before and after 2000 BC, 800 BC, 400 AD, and 1 600 AD; the quasiperiodicity corresponds to cyclic variation of solar activity. Global temperature changes influenced regional precipitation patterns: Northern Europe was wetter while the middle- and low-latitude lands were more arid during colder epochs. Both sets of cold climatical conditions were unfavorable for agricultural production. Historical records show that large demographic movements in history took place because of crop failures and mass starvation, rather than escaping from war zones. The “wandering” of the Germanic tribes during the first two or three centuries of the Christian Era is one example. Whereas the accelerated release of carbon dioxide from the burning of fossil fuels is ultimately to cause global warming, historical evidence indicates, however, that global warming has been on the whole a blessing to mankind. Global cooling, on the other hand, has curtailed agricultural production and has led to famines and mass migrations of people. Perhaps the most important task at the present is not so much computer-modelling of greenhouse effect on global climate, but water-management and agricultural researches to insure food-supply for an everincreasing world population.     

Coincidence and spatial variability of geology,soils, and vegetation,mill run watershed,Virginia

The Mill Run watershed is a structurally-controlled synclinal basin on the eastern limb of the Massanutten Mountain complex of northwestern Virginia. Bedrock contacts are obscured by coarse sandstone debris from exposures near basin divides. Colluvium blankets more than half the basin, masking geomorphic surfaces, affecting vegetation patterns, and contributing to the convexity of the alluvial, terrace, pediment and erosion surfaces. Examination of the bedrock geology, geomorphology, soils and vegetation shows distinct distributional correspondences. Vegetation is strongly interdependent with geomorphology, bedrock geology, and soils. On convex colluvial slopes, mixed hardwood forests are most common. In concave coves and deep gorges, mixed hardwoods are replaced by conifers. In thin colluvium, in poorly developed soils, and on blockfields, chestnut oak is singularly prevalent. Conifers dominate shaley bedrock areas. Soils and surficial sediments have a major effect on near-surface hydrology. During wet seasons, cemented horizons in the subsurface cause temporary saturation in the superjacent horizons; lateral movement of soil-water effectively eliminates a vertical component of ground-water recharge. Vegetation is strongly dependent on water availability and thus reflects the distribution of subsurface barriers and sediment-soil fades changes.     

Modelling and inversion -progress,problems, and challenges

Researchers in the field of electromagnetic modelling and inversion have taken advantage of the impressive improvements of new computer hardware to explore exciting new initiatives and solid extensions of older ideas. Finite-difference time-stepping methods have been successfully applied to full-domain 3D models. Another new method combines time-stepping with spatial frequency solutions. The 2D model 3D source (2.5D) problem is also receiving fresh attention both for continental and sea floor applications.The 3D inversion problem is being attacked by several researchers using distorted Born approximation methods. Q-domain inversions using transformation to pseudo-wave field and travel time tomography have also been successfully tested for low contrast problems. Subspace methods have been successful in dramatically reducing the computational burden of the under-determined style of inversion. Static magnetic field interpretation methods are proving useful for delineating the position of closely-spaced multiple targets.Novel (appeals to nature) methods are also being investigated. Neural net algorithms have been tested for determining the depth and offset of buried pipes from EM ellipticity data. Genetic algorithms and simulated annealing have been tested for extremal model construction.The failure of researchers to take adequate account of the properties of the mathematical transformation from algorithms to the number domain represented by the computing process remains a major stumbling block. Structured programming, functional languages, and other software tools and methods are presented as an essential part of the serial process leading from EM theory to geological interpretation.     

Age, geology, geophysics, and geochemistry of Mahukona Volcano, Hawai`i

The size, shape, and magmatic history of the most recently discovered shield volcano in the Hawaiian Islands, Mahukona, have been controversial. Mahukona corresponds to what was thought to be a gap in the paired sequence (Loa and Kea trends) of younger Hawaiian volcanoes (<4?Ma). Here, we present the results of marine expeditions to Mahukona where new bathymetry, sidescan sonar, gravity data, and lava samples were collected to address these controversies. Modeling of bathymetric and gravity data indicate that Mahukona is one of the smallest Hawaiian volcanoes (～6,000?km³) and that its magmatic system was not focused in a long-lived central reservoir like most other Hawaiian volcanoes. This lack of a long-lived magmatic reservoir is reflected by the absence of a central residual gravity high and the random distribution of cones on Mahukona Volcano. Our reconstructed subsidence history for Mahukona suggests it grew to at least ～270?m below sea level but probably did not form an island. New ⁴⁰Ar–³⁹Ar plateau ages range from 350 to 654?ka providing temporal constraints for Mahukona’s post-shield and shield stages of volcanism, which ended prematurely. Mahukona post-shield lavas have high ³He/⁴He ratios (16–21?Ra), which have not been observed in post-shield lavas from other Hawaiian volcanoes. Lava compositions range widely at Mahukona, including Pb isotopic values that straddle the boundary between Kea and Loa sequences of volcanoes. The compositional diversity of Mahukona lavas may be related to its relatively small size (less extensive melting) and the absence of a central magma reservoir where magmas would have been homogenized.     

Transitional, entraining, cloudy, and coastal boundary layers

Atmospheric boundary layers are marvelously varied and complex. Recent research has examined some of that variety. Boundary layers over land undergo drastic changes throughout the day as the sun rises and sets, and as clouds form and dissipate. Air is entrained at the top of the boundary layer at varying rates. As air moves over the coast, the boundary layer reacts to changes in surface forcing. All of these changes affect pollutant transport and weather formation. In this paper, research attempting to understand transitional, cloud-topped, and coastal boundary layers, and boundary-layer top entrainment, is reviewed.     

Dynamics of dissolved major (Na,K, Ca,Mg, and Si) and trace (Al,Fe, Mn,Zn, Cu,and Cr) elements along the lower Orinoco River

This study addresses the changes in dissolved major and trace element concentrations along the Orinoco River, including the mixing zone between the Orinoco and Apure Rivers. Water samples from the Apure and Orinoco Rivers were collected monthly in four sectors over a period of 15 months. Auxiliary parameters (pH, dissolved oxygen, conductivity, and temperature), total suspended sediments, dissolved organic carbon (DOC), and major (Na, K, Ca, Mg, and Si) and trace (Al, Fe, Mn, Zn, Cu, and Cr) element concentrations were measured in all sectors. The relative contribution of both rivers after the Apure–Orinoco confluence was determined using Ca as a tracer. Moreover, a mixing model was developed to determine whether dissolved species exhibit a conservative behavior during mixing. The results indicate that DOC is removed from waters during the Apure–Orinoco mixing, probably due to absorption of DOC on mineral phases supplied by the Apure River. Dissolved Na, Ca, and Mg behave conservatively during the mixing processes, and their concentrations are controlled by a dilution process. The anomaly in the temporal pattern of K in the Orinoco is caused by the input of biogenic K originating from the Apure River during the high‐water stage. The loss of dissolved Si during the low‐water stage can be explained by the uptake of Si by diatoms. Dissolved Mn, Zn, Al, and Fe showed a non‐conservative behavior during the Apure–Orinoco mixing. The removal of Mn and Zn from the dissolved phase can be explained by the formation of Mn‐oxyhydroxides and the scavenging of Zn onto Mn oxides. Dissolved Fe is controlled by redox processes, although the removals of Fe and Al due to the preferential adsorption of large organometallic complexes by mineral surfaces after the Apure–Orinoco confluence can affect the mobility of both elements during transport. The conservative behavior shown by Cu and Cr can be related to the tendency of both elements to be complexed with small organic colloids, which are not preferentially adsorbed by clays.     

Anorthite,andesine, wollastonite,diopside, cordierite and pyrope: thermodynamics of melting,glass transitions,and properties of the amorphous phases

Drop calorimetry measurements between 900 and 1850 K are reported for amorphous anorthite, andesine, wollastonite, diopside, cordierite and pyrope. The isobaric heat capacities of the glassy and liquid phases of these materials, and the enthalpies of fusion of the minerals have been derived. The calorimetric entropies of fusion of these substances and of other oxide minerals are generally consistent with the calculated volume changes on melting and with the observed pressure dependences of the melting points. The thermodynamics of mixing of liquid plagioclases have been examined, and it is concluded that their enthalpies of mixing are markedly different from the values derived directly from solution calorimetry measurements at 985 K.     

Ridge subduction,magmatism, and metallogenesis

Modern oceans contain large bathymetric highs(spreading oceanic ridges, aseismic ridges or oceanic plateaus and inactive arc ridges) that, in total, constitute more than 20–30% of the total area of the world's ocean floor. These bathymetric highs may be subducted, and such processes are commonly referred to as ridge subduction. Such ridge subduction events are not only very common and important geodynamic processes in modern oceanic plate tectonics, they also play an important role in the generation of arc magmatism, material recycling, the growth and evolution of continental crust, the deformation and modification of the overlying plates, and metallogenesis at convergent plate boundaries. Therefore, these events have attracted widespread attention. The perpendicular or high-angle subduction of mid-ocean spreading ridges is commonly characterized by the occurrence of a slab window, and the formation of a distinctive adakite–high-Mg andesite–Nb-enriched basalt-oceanic island basalt(OIB) or a mid-oceanic ridge basalt(MORB)-type rock suite, and is closely associated with Au mineralization. Aseismic ridges or oceanic plateaus are traditionally considered to be difficult to subduct, to typically collide with arcs or continents or to induce flat subduction(low angle of less than 10°) due to the thickness of their underlying normal oceanic crust(6–7 km) and high topography. However, the subduction of aseismic ridges and oceanic plateaus occurred on both the western and eastern sides of the Pacific Ocean during the Cenozoic. On the eastern side of the Pacific Ocean, aseismic ridges or oceanic plateaus are being subducted flatly or at low angles beneath South and Central American continents, which may cause a magmatic gap. But slab melting can occur and adakites, or an adakite–high-Mg andesite–adakitic andesite–Nb-enriched basalt suite may be formed during the slab rollback or tearing. Cu-Au mineralization is commonly associated with such flat subduction events. On the western side of the Pacific Ocean, however, aseismic ridges and oceanic plateaus are subducted at relatively high angles(30°).These subduction processes can generate large scale eruptions of basalts, basaltic andesites and andesites, which may be derived from fractional crystallization of magmas originating from the subduction zone fluid-metasomatized mantle wedge. In addition,some inactive arc ridges are subducted beneath Southwest Japan, and these subduction processes are commonly associated with the production of basalts, high-Mg andesites and adakites and Au mineralization. Besides magmatism and Cu-Au mineralization,ridge subduction may also trigger subduction erosion in subduction zones. Future frontiers of research will include characterizing the spatial and temporal patterns of ridge subduction events, clarifying the associated geodynamic mechanisms, quantifying subduction zone material recycling, establishing the associated deep crustal and mantle events that generate or influence magmatism and Cu-Au mineralization, establishing criteria to recognize pre-Cenozoic ridge subduction, the onset of modernstyle plate tectonics and the growth mechanisms for Archean continental crust.     

Spatial distribution,source apportionment,and associated risks of trace metals (As,Pb, Cr,Cd, and Hg) from a subtropical river,Gomti, Bangladesh

Sediment samples from the Gomti River basin were investigated to determine and evaluate trace metal concentrations,their biological effect,and potential ecological and human health risks for adults and children.The mean concentrations of trace metals were organized in the descending order of mercury(Hg)(0.08 mg/kg)>chromium(Cr)(0.06 mg/kg)>lead(Pb)(0.05 mg/kg)>arsenic(As)(0.02 mg/kg)>cadmium(Cd)(0.01 mg/kg).The current study illustrated that metals were attributed to the area from natural sources and different anthropogenic sources especially from industries.However,the concentration levels were lower than the sediment quality guidelines(SQGs)based on the effect-range classifications of threshold effect concentration(TEC)and probable effect concentration(PEC).Therefore,the concentration of the elements showed no adverse biological effects on aquatic organisms.The evaluated potential ecological risk index also revealed the low toxicity to the aquatic environment.Moreover,the applied sediment quality indices,geo-accumulation index(Igeo),contamination factor(CF),and contamination severity index(CSI)suggested that the contamination levels of the elements were in the acceptable range,and the contamination had not notably impacted on the sediment quality.The risk index(HI)concerning age groups was significantly less than the threshold limit of 1 indicating that the contamination had no non-carcinogenic risk effect.The total carcinogenic risk(TCR)was less than a risk value of 1×10⁴.Hence,the current study suggests that immediate remediation is not required due to an absence of alarming conditions in the study area.Proper monitoring of the attribution of the metal elements should be done for the betterment of human and environmental health。     

Volcanoes, the stratosphere, and climate

A list of volcanic eruption plumes observed to ascend into or near the stratosphere since 1883 shows that the volcanoes divide readily into two groups, one at low and one at higher latitudes. A model for the rise of a buoyant volcanic plume rise as applied to volcanic eruptions is corrected for realistic temperature profiles and for the finite vertical extent of the resultant debris clouds. The utility of the model can be questioned, however, owing to the highly uncertain and variable nature of the efficiency of use of heat energy of buoyant rise. The observed correlation of stratospheric plumes with climatic effects indicates that those plumes nearer the equator have the largest impact on surface temperatures. Analysis of the observations also suggests that injection of debris into the stratosphere is more important in determining the effect on climate than either the total volcanic explosivity of the eruption or the actual height reached within the stratosphere.     

Cadmium,zinc, copper,and barium in foraminifera tests

The concentrations of cadmium, zinc, copper and barium have been determined on 2-mg samples of single-species foraminifera populations. Cleaning techniques were tested using North Atlantic core tops, and followed by a detailed downcore study for the last 30,000 years in South Atlantic core V22-174. Raw foram tests cleaned by crushing followed by ultrasonic removal of fine-grained material, and dissolved in a pH 5.5 acetate buffer, contain appreciable amounts of trace elements associated with ferromanganese and alumino-silicate contaminants. A reductive/complexing cleaning treatment reduces ferromanganese contamination by 1–2 orders of magnitude. Acetate buffers at pH 5.5 complex iron and raise the solubility of ferromanganese oxides; these buffers are unsuitable for separating carbonate lattice-bound trace elements from the fraction associated with ferromanganese phases. Improved mechanical and ultrasonic reductive cleaning combined with a mild dissolution in distilled water under 1 atm.P_CO2 reduces contaminant levels another order of magnitude. The Cd and Zn concentrations (order 10^?8 mole Cd/mole Ca and 10^?5 mole Zn/mole Ca) of species with low surface area show an increase with decreasing isotopic temperatures. This increase is consistent with the increasing concentrations of these metals from low values in surface waters to higher values at depth. The variance of Cd and Zn over the last 30,000 years in the central South Atlantic is consistent with the probable variability of the dissolved trace elements at the calcification levels of the species analyzed. Cu and Ba are irreproducible and probably sensitive to residual contaminant phases. The trace element content of the tests differs from levels observed in a recent coprecipitation study. Foraminifera may be a significant vector in zinc cycling in the ocean.     

Oceanic Loading and Local Distortions at the Baksan,Russia, and Gran Sasso,Italy, Strain Stations

Reliable use of strain data in geophysical studies requires their preliminary correction for ocean loading and various local distortions. These effects, in turn, can be estimated from the tidal records which are contributed by solid and oceanic loading. In this work, we estimate the oceanic tidal loading at two European strain stations (Baksan, Russia, and Gran Sasso, Italy) by analyzing the results obtained with the different Earth and ocean models. The influence of local distortions on the strain measurements at the two stations is estimated.     

Organic and inorganic matter in Louisiana coastal waters: Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi regions

Chromophoric dissolved organic matter (CDOM) spectral absorption, dissolved organic carbon (DOC) concentration, and the particulate fraction of inorganic (PIM) and organic matter (POM) were measured in Louisiana coastal waters at Vermilion, Atchafalaya, Terrebonne, Barataria, and Mississippi River locations, in 2007-2008. The range of CDOM was 0.092 m⁻¹ at Barataria in June 2008 to 11.225 m⁻¹ at Mississippi in February 2008. An indicator of organic matter quality was predicted by the spectral slope of absorption coefficients from 350 to 412 nm which was between 0.0087 m⁻¹ at Mississippi in May 2008 and 0.0261 m⁻¹ at Barataria in June 2008. CDOM was the dominant component of light attenuation at Terrebonne and Barataria. Detritus and CDOM were the primary components of light attenuation at Vermilion, Atchafalaya, and Mississippi. DOC ranged between 65 and 1235 μM. PIM ranged between 1.1 and 426.3 mg L⁻¹ and POM was between 0.3 and 49.6 mg L⁻¹.     

Physical properties,vitrinite reflectance,and microstructure of coal,Taiyuan Formation,Qinshui Basin,China

In this study, we experimentally established the relationship between physical properties, vitrinite reflectance, and microstructure of coal, Taiyuan Formation, Qinshui Basin, China using representative coal samples collected from three different mines via the rock mechanics testing system (MTS). We analyzed the organic macerals, vitrinite reflectance, and microstructure of 11 coal samples using petrography and scanning electron microscopy (SEM). The experimental results suggest that (1) the elastic parameters can be described by linear equations, (2) both P-and S-wave velocities display anisotropy, (3) the anisotropy negatively correlates with vitrinite reflectance, and (4) the acoustic velocities and Young’s modulus are negatively correlated with the volume of micropores. The derived empirical equations can be used in the forward modeling and seismic inversion of physical properties of coal for improving the coal-bed methane (CBM) reservoir characterization.     

Volume averaging,probabilistic averaging,and ergodicity

The relationship between probabilistic averaging and volume averaging is analyzed in a rigorous setting. The question of ergodicity is shown to be inappropriate for multiphase averaging techniques. The correct question to ask is whether or not the underlying probability space exists.     

Precipitation,dynamical intermittency,and sporadic randomness

While rainfall intermittency is a dynamical phenomenon, little progress has been made in the literature on the link between rainfall intermittency and atmospheric dynamics. We present the basic dynamical models of intermittency that are phenomenologically most similar to rainfall: Pomeau–Manneville Type-III and On–Off. We then illustrate each type with both a 1-D iterative map and a corresponding stochastic process stressing the appearance of these dynamics in high-dimensional (stochastic) systems as opposed to low-dimensional chaotic systems. We show that the pdf of rainfall intensities, the pdf of “laminar phases” (periods of zero rainfall intensity), and the spectrum of the rainfall series all have power-law behavior that is broadly consistent with intermittency in the classic types. Using a seasonal analysis, we find that summer convective rainfall at daily and sub-daily scales seems consistent with features of Type-III intermittency. The correspondence with Type-III intermittency and a preliminary entropic analysis further suggest that rainfall may be an example of sporadic randomness, blending deterministic and stochastic components.