洞穴石笋初始234U/238U值变化的古气候记录意义

通过对我国西南地区3个洞穴9根大型石笋272个初始234U/238U数据的分析研究,发现石笋初始234U/238U值长尺度变化与海洋沉积SPECMAP曲线δ18O记录有一定的正相关关系,与北纬25°夏季太阳辐射能量变化曲线呈一定的负相关关系,石笋初始234U/238U值的变化在冰期时波动强烈,而在间冰期波动相对平缓,在间冰期和冰期(间冰阶和冰阶)转化阶段该值呈跳跃状态变化。末次冰期及全新世阶段石笋初始234U/238U变化记录了该时段内的BA暖期和YD突变冷事件;全新世8200 a BP、7200 a BP、5200 a BP、4200 a BP、2800 a BP、1400 a BP 发生的几次较强冷事件在石笋初始234U/238U值都有相应记录,并且和长尺度的变化规律一致,冷事件发生时石笋初始234U/238U值偏重,暖期偏轻。封闭系统形成的洞穴石笋初始234U/238U变化类似于同地区洞穴石笋的δ18O对气候变化的记录特征,在我国西南地区两者与夏季风变化的强弱呈现一种负相关的关系,洞穴石笋初始234U/238U值可以作为一个有用的古气候替代指标来研究古降水的变化。     

中国南方石笋氧同位素记录的重要意义

中国南部石笋氧同位素记录记载了重要的气候变化信息。应用石笋氧同位素记录时首先需要考虑检验石笋的平衡结晶生长,特别是重复性检验,以排除可能的偶然性或地方因素。中国南部重复性很好的南京葫芦洞和贵州董歌洞石笋氧同位素记录主要代表了当时的降水氧同位素信息。两洞的记录都显示,在冰期或冰段时期降水的氧同位素比间冰期或间冰段时期明显偏重。受夏季风强弱变化的控制,与目前亚洲季风降水氧同位素的季节变化相对应,在间冰期或间冰段时,ITCZ偏北,降水以夏季风的大规模大气环流下的对流降水为主,其氧同位素较轻;相反地,在冰期或冰段时,ITCZ偏南,降水以夏季风爆发前的锋面降水为主,其氧同位素较重。虽然尚有其他许多影响因素,亚洲季风的变化应是影响中国南部石笋氧同位素在冰期/间冰期或冰段/间冰段的尺度上变化的主导因素。但在更小的尺度上(例如小冰期),石笋氧同位素记录的解释则需要谨慎。虽然下最终结论为时尚早,但作为亚洲季风的两个组成部分的东亚季风和印度季风很可能是同步的,至少在冰期/间冰期或冰段/间冰段的尺度上是如此。基于上述研究,进一步提出亚洲夏季风强段/弱段的概念(AsianSummerMonsoonInterstadial/stadial,或ASMI/ASMS),其在上个冰期中与格陵兰冰芯间冰段/冰段一一对应     

更新世冰盖与大洋碳储库相互作用的箱式模型模拟

全球大洋深海有孔虫碳同位素(δ13C)记录中广泛发现40万年周期,这一周期可能与偏心率长周期的轨道驱动有关.1.6 Ma以来,δ13C的这一长周期拉长到50万年,且重值期不再与偏心率低值对应.目前对δ13C 40万年周期的成因及其周期拉长的机制还不明确.这里使用了包含9个箱体的箱式模型,用于研究热带过程与冰盖相互作用及其对大洋碳循环的影响.模拟结果显示当北半球高纬海区海冰迅速增大时冰盖迅速融化,进入冰消期,而当海冰快速消失后,冰盖则重新缓慢增长.冰盖变化具有冰期长,间冰期短的非对称形态.在季节性太阳辐射量的驱动下冰盖变化具有10万年冰期-间冰期旋回.当冰盖融化速率受北半球高纬夏季太阳辐射量控制时,冰盖变化的岁差周期明显加强,相位与地质记录一致,说明轨道驱动可以通过非线性相位锁定机制使冰盖变化与其在相位上保持一致.海冰的阻隔效应使大气中CO₂在冰消期时增多.冰期时大洋环流减弱使大气中CO₂逐渐减少.当模型只有ETP驱动的风化作用而不考虑冰盖变化时,模拟的δ13C记录显示极强的40万年周期,体现了大洋碳储库对热带风化过程的响应.当同时考虑冰盖变化和风化作用时,模拟的δ13C结果中40万年周期减弱而10万年周期加强,并且40万年周期上碳储库与偏心率的相位与不考虑冰盖变化时的相位也存在差异,反映了冰盖变化引起的洋流改组压制了大洋碳循环对热带过程的响应.      

岩溶洞穴次生碳酸盐沉积铀及其同位素组成古气候环境研究进展

洞穴沉积铀含量及其同位素初始234U/238U[（234U/238U)0]变化均与过去气候环境变化关系密切。文章分别对石笋中U含量和(234U/238U)0的气候意义进行统计分析发现,多数研究认为洞穴沉积U含量和(234U/238U)0可能指示土壤湿度和有效降水变化。然而,不管是对洞穴沉积的U含量还是(234U/238U)0,其气候环境意义解读还存在两种观点。但无论如何,这些研究成果都显示了洞穴沉积的U含量和(234U/238U)0是研究过去气候环境变化的重要替代指标。在未来的研究中,除了土壤环境和过程,还应关注U来源的相对贡献变化和其他微量元素与U元素的关系。这一指标可能在对东亚地区的大气粉尘活动和冬季风演化、地表生物量的变化研究等方面发挥重要作用。      

近2 Ma BP以来地球轨道参数周期上全球海平面变化机制

海平面的变化往往对区域生态环境、社会经济造成严重影响.通过对全球相对海平面变化(relative sea level,简称RSL)记录的再分析结果,合成了近2 Ma BP以来的全球RSL变化记录,分析了合成RSL记录对原始RSL记录数理特征的继承性,并基于频谱、滤波等数理分析验证了合成RSL记录的合理性.在此基础上,讨论了合成RSL与大气CO₂浓度、中高纬度海域表层海水温度(sea surface temperature,简称SST)、全球大洋底栖氧同位素(δ18O_B)等参数指标间的相关性,结果显示:(1) 合成RSL不仅与原始RSL记录的变化趋势基本一致,继承了原始RSL记录对全球气候变化的响应特征,而且显示出合成RSL记录对地球轨道参数周期变化响应明显;(2) 近2 Ma BP以来,在冰期-间冰期旋回中,合成RSL与δ18O_B变化呈良好的负相关,相关系数r平均值可以达到约0.81,高于合成RSL与大气CO₂浓度及中高纬度海域SST变化的相关系数;(3) 在地球轨道参数周期上,合成RSL与极地冰盖体积(δ18O_B)的变化几乎同时,在偏心率周期上,合成RSL落后于SST和大气CO₂浓度变化;在斜率周期上,合成RSL落后于SST变化而领先于大气CO₂浓度变化.推测这些变化的诱导因素可能是在太阳辐射量改变的前提下,大气CO₂浓度及大洋SST变化对极地冰盖体积产生了差异影响,进而引起海平面发生变化.      

临夏黄土记录的26万年来季风快速变化

黄土高原西部高分辨率黄土序列开展的多代用指标研究,有助于揭示轨道-亚轨道尺度上东亚冬、夏季风的变化特征及动力机制。但针对同一地质记录提取冬、夏季风多代用指标进行对比和敏感性分析的工作尚不多见,因此制约了对季风快速变化特征和机理的理解。本文利用甘肃临夏85 m黄土岩芯开展高分辨率的粒度、磁化率和元素扫描分析,发现在轨道尺度上粒度和Zr/Rb比值显示的大幅冰期-间冰期波动与深海氧同位素记录有很好的对应关系,表明东亚冬季风的波动响应于北半球高纬冰量的变化。但在千年尺度上,粒度能更敏感地响应冬季风的快速变化;Rb/Sr比值和磁化率均能很好记录轨道尺度上的东亚夏季风波动,但在亚轨道尺度上Rb/Sr的敏感性明显高于磁化率。粒度、Zr/Rb和Rb/Sr所指示的东亚季风快速变化表现出较强的岁差信号,与石笋和北纬65°夏季太阳辐射有较好的对应关系,表明东亚季风变化也受到岁差直接驱动的夏季太阳辐射变的控制。在最后两个冰期-间冰期旋回中(即末期冰期旋回和倒数第二次冰期旋回)Rb/Sr及Zr/Rb比值和粒度记录分别可以辨别出与石笋相同数量级的变暖事件,但粒度记录的暖事件明显要多于Rb/Sr及Zr/Rb比值,且这些暖事件并不能一一对应。粒度及元素比值记录显著变冷的千年尺度的Heinrich(H)事件与石笋记录的夏季风明显减弱的事件有很好的对应关系,但其发生频率明显高于海洋记录。这些指标记录的千年尺度上波动信号的不一致性主要归因指标对不同气候要素敏感性的差异。未来需要进一步开展高分辨率多代用指标敏感性分析,选取对季风快速变化的敏感指标,有助于我们理解季风快速变化的特征(如周期和幅度等)和分析季风快速变化的时空差异性。     

文石-方解石石笋U/Th体系的封闭性判断及意义

湖南省龙山县莲花洞两根大型石笋LLl(文石-方解石型)和LL5(文石型)ICP-MS230Th结果表明,82个年龄数据并不完全符合石笋生长层序律.根据U/Th同位素比值、沉积和矿物学特征,分析了同位素体系开放度对建立石笋正确年代学模式的影响.莲花洞LLl石笋全新世以来234U/238U对230Th/238U的比值具有谐和性特征并且230Th年龄层序正常,说明文石矿物基本接近U/Th同位素封闭系统,实测年龄基本可靠.10～40 ka期间234U/238U与230Th/238U离散度较大和矿物具有溶蚀、风化现象,表明体系发生U加入/流失作用.LL5石笋60～80 ka期间封闭性较好,实测年龄可信.上述结果表明,同一洞穴中文石石笋U/Th同位素体系开放度与时间的关系并不是线性关系,沉积时水文和物理化学性质以及随后的保存状况是决定洞穴文石石笋同位素封闭性的关键因素.     

神农架三宝洞倒数第二次冰期高分辨率石笋δ13C记录

基于神农架三宝洞两支石笋24个230Th年龄以及637个δ13C测试数据,建立了倒数第二次冰期191±1.8～133±0.6kaB.P.时段洞穴石笋高分辨率δ13C的时间序列.在冰期/间冰期尺度上,δ13C值振幅达4.5％,整体变化趋势与全球冰量曲线类似.在倒数第二次冰期,石笋δ13C记录揭示出一系列较大振荡幅度的千年...     

我国西北地区盐湖中的铀234U/238U比值示踪研究

内蒙古二连盆地、鄂尔多斯盆地典型含铀碳酸型盐湖水、岩两相234U/238U综合分析表明,碳酸型盐湖铀来源于大气降水和潜水对盐湖盆地周围中生代到现代富铀沉积物的溶滤、浸出,具有快速、近源物质来源特点。盐湖卤水和对应沉积物234U/238U值一般为0.8～1.2,湖卤水和潜卤水（晶间卤水）-岩两相中的铀处于沉积平衡状态。早白垩世～上新世含膏盐地层对比研究证实了富铀岩层234U/238U值随铀含量增大而减小,并趋近于1。室内盐湖水蒸发模拟实验发现残余卤水、沉积物234U/238U具有随蒸发程度增大逐渐减小的变化特征。盐湖现代沉积物物相研究发现铀主要以碳酸铀酰和吸附形式赋存在富含有机物和碎屑成分的含盐粘土沉积中,铀在盐类晶体中含量极少,仅存在于封闭水和结晶水中。卤水和沉积物ARu值是盐湖铀源及铀含量水平的指示标志之一。     

234U/238U法测定石笋年龄

<正> 应用230Th/234U法研究洞穴沉积物年代已取得可靠结果,成功的为距今35万年以来的洞穴沉积物标上时标。近十几年来,为了开展老于35万年洞穴沉积物年代学研究,曾探讨应用234U/238U法和ESR法研究碳酸钙沉积物年代。目前已在234U/238U法研究洞穴沉积物年代方面取得成果。然而,由于样品条件不适合,洞穴采样困难以及样品初始234U/238U放射性比值确定存在问题和争论,这方面的研究尚待进一步深入。本文报道一个石笋五个不同生长层样品的234U/238U年代测定结果。试图对老于35万年的洞穴沉积物年龄研究,提供一个可用方法。并对相应时期的古气候环境进行探讨。      

未来百年全球气候变化分析

未来百年全球气候变化的影响是当前学术界激烈争议的议题,深入探讨全球气候变化的驱动机理才能正确认识全球气候变化。持续生长的青藏高原吸收了巨量的CO₂,导致大气中CO₂浓度大幅下降,使地球从温室气候进入到以冰期、间冰期交替出现为特征的冰室气候,青藏高原成为新生碳储库。在间冰期,青藏高原和蒙古高原将淡水输送到中低纬度内陆区(以下简称内陆区),导致内陆区的硅酸岩化学风化强烈,植被和湖相沉积发育,吸收了巨量大气CO₂,是碳汇; 在冰期,青藏高原、蒙古高原将内陆区表层淡水与尘埃最终输送到高纬度地区,导致内陆区荒漠化,对大气CO₂的吸收量远小于其自身的排放量,内陆区成为碳源,使大气CO₂浓度上升。这是中新世以来大气CO₂浓度维持低浓度、准动态平衡的机理。地表平均温度的变化驱动了淡水在高、低纬度地区之间循环。人类巨量碳排放使全球大气CO₂浓度暂时快速上扬,全球变暖,淡水回到内陆区,导致内陆区变绿,硅酸岩化学风化作用增强,吸收大气CO₂的能力大幅提高,内陆区又变成碳汇,抑制大气CO₂浓度的进一步上升; 初步测算,最早2050年、最迟2090年,当大气CO₂浓度达到(510±40)×10^-6时,其快速上升的趋势将得到抑制; 未来百年尺度的全球气候变化受地球和太阳内部的构造活动所驱动,是周期性变化的、是可预测。     

Direct effect of ice sheets on terrestrial bicarbonate, sulphate and base cation fluxes during the last glacial cycle: minimal impact on atmospheric CO2 concentrations

Chemical erosion in glacial environments is normally a consequence of chemical weathering reactions dominated by sulphide oxidation linked to carbonate dissolution and the carbonation of carbonates and silicates. Solute fluxes from small valley glaciers are usually a linear function of discharge. Representative glacial solute concentrations can be derived from the linear association of solute flux with discharge. These representative glacial concentrations of the major ions are 25% of those in global river water. A 3-D thermomechanically coupled model of the growth and decay of the Northern Hemisphere ice sheets was used to simulate glacial runoff at 100-year time steps during the last glacial cycle (130 ka to the present). The glacially derived fluxes of major cations, anions and Si over the glaciation were estimated from the product of the glacial runoff and the representative glacial concentration. A second estimate was obtained from the product of the glacial runoff and a realistic upper limit for glacial solute concentrations derived from theoretical considerations. The fluxes over the last glacial cycle are usually less than a few percent of current riverine solute fluxes to the oceans. The glacial fluxes were used to provide input to an oceanic carbon cycling model that also calculates changes in atmospheric CO₂. The potential change in atmospheric CO₂ concentrations over the last glacial cycle that arise from perturbations in glacial solute fluxes are insignificant, being <1 ppm.     

Late Quaternary glaciation of Tibet and the bordering mountains: a review

Abundant glacial geologic evidence present throughout Tibet and the bordering mountains shows that glaciers have oscillated many times throughout the late Quaternary. Yet the timing and extent of glacial advances is still highly debated. Recent studies, however, suggest that glaciation was most extensive prior to the last glacial cycle. Furthermore, these studies show that in many regions of Tibet and the Himalaya glaciation was generally more extensive during the earlier part of the last glacial cycle and was limited in extent during the global Last Glacial Maximum (marine oxygen isotope stage 2). Holocene glacial advances were also limited in extent, with glaciers advancing just a few kilometers from their present ice margins. In the monsoon-influenced regions, glaciation appears to be strongly controlled by changes in insolation that govern the geographical extent of the monsoon and consequently precipitation distribution. Monsoonal precipitation distribution strongly influences glacier mass balances, allowing glaciers in high altitude regions to advance during times of increased precipitation, which are associated with insolation maxima during glacial times. Furthermore, there are strong topographic controls on glaciation, particular in regions where there are rainshadow effects. It is likely that glaciers, influenced by the different climatic systems, behaved differently at different times. However, more detailed geomorphic and geochronological studies are needed to fully explore regional variations. Changes in glacial ice volume in Tibet and the bordering mountains were relatively small after the global LGM as compared to the Northern Hemisphere ice sheets. It is therefore unlikely that meltwater draining from Tibet and the bordering mountains during the Lateglacial and early Holocene would have been sufficient to affect oceanic circulation. However, changes in surface albedo may have influenced the dynamics of monsoonal systems and this may have important implications for global climate change. Drainage development, including lake level changes on the Tibetan plateau and adjacent regions has been strongly controlled by climatic oscillations on centennial, decadal and especially millennial timescales. Since the Little Ice Age, and particularly during this century, glaciers have been progressively retreating. This pattern is likely to continue throughout the 21st century, exacerbated by human-induced global warming.     

TIMS测定铀矿石样品中^234U/^238U、^230Th/^232Th、^228Ra/^226Ra的方法研究

研究了TIMS测定铀矿石样品中234U/238U、230Th/232Th、228Ra/226Ra的方法。建立了铀矿石密闭混酸一次溶样的方法和采用阴离子、阳离子和Sr特效树脂逐级离子交换分离纯化U、Th和Ra的流程,满足了TIMS测量要求。测定结果表明：100～1000 ng的天然铀中234U/238U,其测量精密度从静态多接收的2.34%提高到动态多接收的0.47%;对230Th与232Th丰度接近、质量为1μg左右的钍,采用三带点样技术和法拉第多接收技术测定230Th/232Th,其内精度平均值为0.0048%,外精度为0.028%;采用单带加钽发射剂,ETP跳峰测定50～100 fg镭-228稀释剂中的228Ra/226Ra,其内精度小于0.10%,外精度小于0.20%。比较TIMS和HR-ICP-MS、α能谱法测定234U/238U、230Th/232Th、228Ra/226Ra结果,三者结果相吻合。TIMS测量法样品用量少、快速、准确、精密度高,是U、Th、Ra同位素比值测定方法的又一补充。     

Investigating the sensitivity of the Atmospheric General Circulation Model ECHAM 3 to paleoclimatic boundary conditions

We present atmospheric simulations of three different time slices of the late Quaternary using the ECHAM 3 general circulation model in T42 resolution. In this work we describe the results of model runs for the time slices 6000 years BP (last climate optimum), 21 000 BP (last glacial maximum) and 115 000 years BP (glacial inception). Although the solar insolation is known for all time slices, a complete data set of the other boundary conditions which are necessary for running the atmospheric model exists only for the last glacial maximum in the form of the CLIMAP reconstruction. For the other two time slices, which are interglacial states like the modern climate, sea surface temperatures, land albedo and ice sheet topography are kept at modern values and only the solar insolation is changed appropriately. The response of the model to solar insolation changes is quite reasonable. The modelled anomalies are small and roughly opposite in sign for 6000 BP and 115 000 BP, respectively. In the case of last glacial maximum, the glacial ice sheet topography and ice albedo produce a much larger climate anomaly in the model. However, to enable a real test of model performance under glacial boundary conditions, the CLIMAP sea surface temperatures, which are now known to be partly inaccurate, should be replaced by an updated “state-of-the-art” reconstruction.     

冰芯记录中末次间冰期-冰期旋回气候突变事件的研究进展

冰芯记录中的气候变化是古气候研究中的重要组成部分. 极地、中低纬度和热带地区的冰芯记录表明, 在冰期间冰期旋回大尺度气候变化背景下, 全球经历了一系列数百年至千年时间尺度的快速气候突变事件, 诸如末次间冰期的干冷事件、末次冰期的DansgaardOeschger事件、 Heinrich事件和Younger Dryas事件等, 虽然这些穿插在冰阶中的暖湿气候事件、间冰阶中的干冷气候事件的成因、机制和影响范围还存在明显的不确定性. 主要介绍不同区域冰芯记录中末次间冰期冰期旋回这些气候突变事件发生的时间、过程和机制等的研究进展.     

Ice ages and orbital variations: Some simple theory and modeling

Possible physical mechanisms relating orbital-element variations (i.e., the “Milankovitch mechanism” of insolation regime changes) to Quaternary glacial/interglacial transitions are explored quantitatively. These include the seasonal cycle of albedo and the zonal distribution of thermal inertia. These mechanisms can interact with the perturbations to zonal average and seasonal average insolation caused by orbital-element variations to cause a global annual temperature residual, even though such variations can cause only a negligible change in global annual insolation.Numerical model experiments with a zonal energy balance model show that the relative interactions between insolation regime changes and seasonally and latitudinally varying albedo and latitudinally varying thermal inertia are roughly of comparable magnitude. Encouraging agreements between model experiments and data are evident, but these (and others') simulations are still a long way away from providing a satisfying explanation of the physical processes that could fully explain the apparent connections between orbital-element variations and Quaternary glaciations.It seems likely that no single physical process can be identified as predominate, and rather, the hypothesized physical connection between insolation regime changes and glacial/interglacial transitions will have to be built on the interactions of a number of processes on both short and long time scales.