西秦岭礼岷金矿带李坝群含金浊积岩建造地球化学特征

本文通过对李坝群含金浊积岩建造中金及其它微量元素的分布、地球化学特征及与金矿成因的关系研究，结果表明，李坝群含金浊积岩建造明显富集Ａｕ、Ａｓ、Ｓｂ、Ｂｉ和铁族元素Ｃｏ、Ｎｉ、Ｃｒ、Ｖ，且具有较高的ＡＵ/Ａｇ比值。李坝群含金浊积岩建造是衍生含金建造，对于金成矿来说，并非是主要的矿源层，而是赋矿岩系。     

吉林白山(浑江)金矿床岩石地球化学特征

白山金矿是近年来在吉林南部地区发现的一种重要类型金矿床--微细浸染型金矿床,矿床赋存在活泼性较高的元古庙老岭群珍珠门组大理岩中.吉南元古庙分布区Au、Zn、Sb、Cd、Sn、As、Hg等元素丰度具有显著偏高特征,白山金矿区Au、Ag、W、Bi、Sb、As等元素具有浓集系数高、变异系数大、多元素套合叠加异常等特点.异常带沿构造带分布并具有明显分带现象,元素组合为Au-Sn-Zn-Ag-Cd.     

招远大尹格庄金矿床微量元素特征及其意义

该文以山东招远大尹格庄金矿床中微量元素为研究对象,通过对矿床围岩、矿石等微量元素的研究,表明大尹格庄金矿围岩中微量元素以富含 Bi,Au,Pb,W,Ag,Sn 为特点,矿体和矿化体中元素组合为 Au,Ag,As,Sb,Hg,B, Cu,Zn,Bi,Mo,Mn,Co,Ni,W。在5个成矿阶段中,第二阶段与第三阶段微量元素的富集程度较明显,表现为 Au, Ag,As,Co,Bi,Cu,Pb,Zn 等的富集,成矿元素可分为2个分带序列,主成矿元素为 Au Ag Cu Pb Zn Bi 组合、头晕元素 As Sb Hg 组合和尾晕元素 Co Ni 组合。     

Physicochemical modeling of formation of Ag–Au–Hg solid solutions: Kyuchyus deposit (Yakutia,Russia) as an example

The «Selektor-C» software package and standard thermodynamic functions of ternary Ag–Au–Hg solid solutions were used for developing physicochemical models in natural processes with participation of gold, silver and mercury. On the example of the Kyuchyus Au–Sb–Hg deposit we have worked out hypogene and hypergene models of formation of native gold, including mercuric gold. We obtained thermodynamic evidence that the Kyuchyus deposit ores formed with the origin of electrum at the early main productive quartz–sulfide stage and ternary Au–Ag–Hg solid solutions at the late non-substantive Au-bearing stages.     

西藏浪卡子县也金嘎波金矿岩石地球化学特征

也金嘎波金矿位于冈底斯成矿带上,是对区域化探发现的Au、As多元素组合异常进行追踪发现的,属于热液型金矿床。矿区各类岩石Au、As、Sb、W、Hg、Ag、Bi、Pb元素平均值高于中国丰度值数倍以上,表明矿区具有丰富的物质来源基础。岩石地球化学研究证明,矿床地表发育Au、As、Sb等10多个元素组合异常。其中Au是成矿指示元素,As、Sb、W是密切伴生元素,Bi、Ag、Pb、Hg是一般的伴生元素。多元素组合异常浓度带发育,浓集中心互相套合叠置部位指示金矿(化)体位置。矿体指示元素(Au、As、Sb、W、Hg、Bi、Ag、Pb)异常分布在岩体、地层接触带和构造交汇处,显示金矿与岩浆活动、热液作用和断裂构造相关,属多次构造作用、岩浆热液叠加富集而成。该金矿床处在冈底斯成矿带内,此研究对该成矿带金异常的识别和查证,寻找新的金矿具有借鉴意义。     

甘肃北山金、铜矿床红沙的植物地球化学特征及其找矿意义

北山地区植被属戈壁荒漠植被类型，主要植物群落为红沙，红沙中多数元素特别是成矿元素及其伴生元素的含量和变化系数矿区大于背景区，元素含量背景区呈对数正态分布，矿区呈偏对数正态或多峰分布，红沙中的元素组合分类背景区为Au,Cu,Pb,Zn,As,Sb,Mo,V,Mn和Ag,Sn,Sr,Ba及Ti,Cr,Co,Ni,金矿区为Au,Ag,As,Sb,Mo,Mn,Sr和Cu,Pb,Zn,Sn,Ba及Co,Ni,Ti,V,Cr,铜矿区为Cu,Pb,Zn,Mo,Au,Ag,Ba和As,Sb,Sn,Mn及Ti,V,Cr,Co,Ni,Sr，矿区红沙中浓集系数较大的元素多数在矿区岩石中的浓集系统亦较大，金，铜矿床红沙和岩石中的特征元素分别都有Au,Ag,Ag,Sb,Mo,(Mn)和Cu,Pb,(Ba,Ti,Cr)。在金，铜矿床（体上方分别发育有良好的Au和Cu的生物地球化学异常和元素组合及分带，根据红沙的地球化学特征能，判断金或铜矿种类型，并能对掩埋，隐伏金，铜矿床（体）进行定位预测。     

陕西铧厂沟金矿南矿带构造叠加晕特征及深部找矿方向

陕西略阳铧厂沟金矿Au Ⅰ矿体主要赋存于泥盆系三河口群第一岩性段第二岩性层中-薄层状微晶灰岩、泥质灰岩、中-厚层状结晶灰岩中。Au Ⅰ矿体作为矿山目前的主采矿体,其深部找矿方向还需要进一步研究。为指导铧厂沟金矿南矿带Au Ⅰ矿体深部找矿工作,对Au Ⅰ矿体进行了元素相关性分析、R型聚类分析以及R型因子分析和构造叠加晕研究。结果表明,As、Sb为前缘晕元素组合,Au、Ag、Pb为近矿晕元素组合,W、Sn、Bi为尾晕元素组合。Au Ⅰ矿体原生晕轴向分带序列从上至下为Sb-Pb-Co-Ag-As-Au。结合成矿元素空间分布特征,认为Au Ⅰ矿体在48线—96线深部存在头尾晕叠加特征,据此提出铧厂沟金矿南矿带Au Ⅰ矿体下一步找矿方向为96线—112线深部。     

Gold potential of massive sulfide ores in the Kamennoozero structural unit,Eastern Karelia

Two types of massive sulfide ores have been identified in the Kamennoozero segment of the green-stone belt: (1) hydrothermal volcanic-sedimentary strata-bound ores with massive, banded, and disseminated structures and (2) massive, brecciated, and stringer-disseminated Au-bearing base-metal ores, crosscutting the rocks of the Vozhmozero Group. The strata-bound, slightly metamorphosed orebodies are located at several levels along the contact between the Kamennoozero and Kumbuksa groups in the deep fault zones of the same names. These ores are composed of pyrite and pyrrhotite, small amounts of chalcopyrite and sphalerite, and distinguished by low grades of base metals and not higher than 0.06 g/t Au. In the Lebyazhino and Svetloozero areas, close to the sulfide Cu-Ni ore hosted in ultramafic rocks, the strata-bound bodies contain pentlandite and are enriched in Co, Ni, Cu, Zn, and up to 2.0–9.2 g/t Au. Brecciated and recrystallized pyrite ores contain up to 0.08–0.4% Sb and As, and up to 0.6–1 g/t Au in the Kumbuksa Fault Zone near Zolotye Porogi. The North Vozhma and Upper Vozhma base-metal massive sulfide occurrences, composed of pyrite, chalcopyrite, sphalerite, pyrrhotite, galena, bornite, and chalcocite, are considered to be promising Au-bearing prospects. Some samples from the North Vozhma occurrence contain up to 1.2–2.8 g/t Au and up to 167 g/t Ag. A gold grade of up to 20 g/t has been detected in the Upper Vozhma occurrence. The potential gold resources of the North Vozhma occurrence are estimated at about 600 kg.     

壤塘地区新都桥组含金浊积岩建造地球化学特征

通过对壤塘地区上三叠统新都桥组合金浊积岩建造中金及其它微量元素的分布、地球化学特征及金矿成因关系的研究。表明新都桥组含金浊积岩建造明显富集Ａｕ、Ａｓ、Ｓｂ、Ｃｕ、Ｚｎ、Ｎｉ、Ｃｏ、Ｃｒ、Ｖ,是本区金矿的主要矿源层。     

金属元素形成原生晕能力定量评价--以青海省扎家同哪金矿为例

在进行原生晕元素分带研究时,所选元素多未进行筛选,不利于正确认识分带规律及指导矿产预测。本文基于扎家同哪金矿2779个钻孔样品数据,拟通过定量评价不同金属元素在围岩、矿化围岩、矿石等中的富集程度,研究不同元素在矿化过程中形成原生晕的能力差异。研究发现,扎家同哪金矿Au、As、Sb、Hg、W、Ag在围岩、矿化围岩和矿石中富集程度递增,易形成原生晕,Zn仅在矿石中富集,成晕规模有限,Mo、Cu、Pb、Sn富集微弱或表现为亏损,较难形成原生晕;扎家同哪金矿不同位置与成矿有关的富集元素为Au、As、Sb(围岩)—Au、As、Sb、W、Hg(Ag)(矿化围岩)—Au、As、Ag、Sb、W、Hg、Zn(矿石),成矿过程中元素在矿化围岩中富集的权重由大至小为As、Hg、Au、Sb、W、Mo、Sn、Pb、Zn、Cu、Ag,进入围岩能力总体表现为低—高—中温元素递减的趋势。对于扎家同哪金矿,在研究原生晕分带特征、指导进一步找矿时,宜优先选用As、Hg、Au、Sb和W等元素。     

河南省庙岭金矿床地球化学特征

熊耳山地区庙岭金矿床是大型构造蚀变岩型金矿, 在该区发育有与金矿关系密切的地球化学异常, Au及相关元素的丰度由区域→矿区→构造岩→矿体呈几何级数递增, 示矿元素主要有Au、Ag、Hg、As、Sb、V、S、Se、Te、W、B、Pb、Zn、Cu等, Hg、As、Sb、Ag等为中、低温远程指示元素。     

湘西沃溪钨锑金矿床超纯自然金

湘西沃溪钨锑金矿床产有自然界中十分罕见的超纯自然金。超纯自然金的Au含量在99 %以上 ,Fisher成色接近1000。自然金中含有Ag、Pb、Zn、Cu、As、Sb、Hg、Bi等显微化学组分。与一般自然金相比 ,超纯自然金的Ag 含量显著偏低 ,而Pb、Zn、As、Sb、Hg、Bi等显微化学组分含量趋于偏高 ,且较稳定。理论分析表明 ,超纯自然金的形成与强氧化性的酸性成矿流体有关。流体中金、银主要以MeCl2-(Me=Au或Ag)的络合物形式迁移。推断矿床成矿可能与区域中酸性岩浆活动有成因联系。     

玲珑金矿田东山矿床矿体空间分带模型及应用

根据玲珑金矿田东山矿床地表及浅部勘查工程与采矿资料, 确定了成矿成晕元素种类。对成晕元素侧向分带特征和垂向分带规律的研究结果表明, 矿体上盘晕元素异常组合为Cu-As-Ag, 下盘晕元素异常组合为Cu-Te-As, 由此确定Au /As、Au /Pb、Au /Ag、Ag/Pb比值具有成矿判别意义, 即判别式Y₁ = 0.000 5 Au /As + 0.037 6 Au /Ag + 0.085 7 Au /Pb - 0.045 4 Ag/Pb > 0.009 2时指示含矿, 否则不含矿; 同时建立了基于Sb /As比值和Au、Ag、As、Sb 含量特征的见矿深度估计模型(H₁ = 1.104 9 + 79.63 k ( Sb /As) ×102 ) , 并对东山矿床主要矿体的可能成矿地段、见矿部位做出预测评价, 提出东山矿床9号、18号、47号、50号和52号支脉在175～ - 70 m标高范围内赋存金矿化或工业矿体。     

The behavior of ore elements in oxidized heterophase chloride and carbonate–chloride–sulfate fluids of porphyry Cu–Mo(Au) deposits (from experimental data)

The spatial coexistence and synchronous formation of magmatogene porphyry Cu–Mo mineralization and epithermal gold mineralization are due to the genetic relationship between their formation processes. This relationship might be due to the generation of metal-bearing fluids of different geochemical compositions by the porphyry ore-magmatic system, which then participate in the formation of magmatogene porphyry Cu–Mo(Au) and associated epithermal gold deposits. Synthesis of fluid inclusions in quartz was performed for experimental study of the behavior of Cu, Mo, W, Sn, Au, As, Sb, Te, Ag, and Bi in heterophase fluids similar in composition and aggregate state to natural ore-forming fluids of porphyry Cu–Mo(Au) deposits. We have established that at 700 °C, a pressure decrease from 117 to 106 MPa leads to a significant enrichment of the gas phase of heterophase chloride fluid with Au, As, Sb, and Bi. The heterophase state of carbonate–chloride–sulfate fluids is observed at 600 °C and 100–90 MPa. It characterizes the highly concentrated liquid carbonate–sulfide phase–liquid chloride phase–low-density gas phase equilibrium. A decrease in the pressure of heterophase carbonate–chloride–sulfate fluid leads to a noticeable enrichment of its chloride phase with Cu, Mo, Fe, W, Ag, Sn, Sb, and Zn relative to the carbonate–sulfate phase. The processes of redistribution of ore elements between the phases of heterophase fluids can be considered a model of generation of metal-bearing chloride fluids, which occurs in nature during the formation of porphyry Cu–Mo(Au) deposits, as well as a model of generation of gas fluids supplying Au, Te, As, and other ore elements to the place of formation of epithermal Au–Cu and Au–Ag mineralization.© 2015, V.S. Sobolev IGM, Siberian Branch of the RAS. Published by Elsevier B.V. All rights reserved.     

石英脉型钨矿原生晕特征及深部成矿定位预测——以赣南淘锡坑钨矿11号脉为例

以往对金、银、铜、铅、锌等矿床的原生晕研究较多,而对钨矿床原生晕的研究很少。为了探求新的钨矿找矿思路,更快速有效地圈定预测靶区、进而发现隐伏矿体,本文以原生晕轴向分带理论为指导,对赣南淘锡坑钨矿11号脉6个中段内沿脉所采的样品选取W、Zn、Au、Ag、Co、Mn、As、Sb及Ce、Hf、Lu和Yb来分析钨矿原生晕的结构,建立了该矿脉的原生晕叠加模型,继而预测靶区。结果表明,Zn、Au、Ag、Co、Mn、Ce、Hf、Lu和Yb异常晕与矿体中心的距离在50m范围内,为近矿晕指示元素;As、Sb异常晕发育于钨矿体前缘,与矿体中心相距200～250m,为前缘晕指示元素;根据该矿脉原生晕模型特征,预测了56m标高的3个靶位和-144m标高的3个靶位,其中靶位1和靶位2最具找矿潜力。     

西天山吐拉苏火山盆地金矿成矿系列围岩蚀变地球化学

形成于西天山晚古生代吐拉苏火山盆地的伊尔曼得金矿、阿希金矿和塔吾尔别克金矿等3种不同类型金矿,其围岩蚀变及微量元素具有不同的特征.伊尔曼得等金矿类型的围岩蚀变为硅化、高岭石化、重晶石化和地开石化,As、Sb、Hg、Cu与Au含量呈正相关关系.塔吾尔别克金矿类型围岩蚀变为硅化、绢云母化、绿泥石化、碳酸盐化.蚀变围岩的As值增高,Au和Ag的含量明显增高.阿希金矿类型围岩蚀变主要有绢云母化、冰长石化、碳酸盐化、硅化、伊利石化,蚀变岩石的Se和As含量与Au、Ag含量基本呈正相关关系.     

金矿床中毒砂标型特征及金的赋存状态——以湖南金矿床为例

湖南含砷金矿资源储量大,分布广,类型多.矿床中的砷矿物主要为毒砂,几乎所有金矿床中的毒砂都含Au（一般120×10^-6~250×10^-6）,且比共生的黄铁矿含Au量高2~5倍,甚至1个数量级以上.毒砂中金的分布率高达64.3%~94.05%.毒砂的生成期有早、晚2期.化学成分为富S亏As型,并以富含微量元素Sb（Se）、Ni、Co而贫Mn及晶胞参数a₀值增大等为标型特征.大多数含Au毒砂均含有相当数量的“不可见金”,即使利用电子探针也难以发现.初步认为毒砂中的“不可见金”多呈纳米级微细粒状存在.     

Geochemical Studies on Au Distribution and Mineralization in the Northwest Jiangxi Terrain

The Middle Proterozoic Jiuling Group,one of the most important geologic unit in the Northwest Jiangxi Terrain,is a kind of Au-bearing formation with a Au-Ag-As association,and its geotectonic setting belongs to the ACM area.Granitification can supply Au with favorable complexing agents.Later granitification os of much more significance in mineralization.Regional Aumineralization includes two types;metamorphic hydrothermal solo-Au mineralization in the northern part and magma gydrothermal superimposed polymetallic mineralization with Au,Ag,etc,being dominant in the southern part.Regional exploration should center aroud the Jiujing Group,small granite bodies of later periods and fault structures,while paying attention to the anomalies of trace elements such as Au,Ag,As,Pb,Zn,etc.