Ubiquitous low-FeO relict grains in type II chondrules and limited overgrowths on phenocrysts following the final melting event

Type II porphyritic chondrules commonly contain several large (>40 μm) olivine phenocrysts; furnace-based cooling rates based on the assumption that these phenocrysts grew in a single-stage melting-cooling event yield chondrule cooling-rate estimates of 0.01-1 K s⁻¹. Because other evidence indicates much higher cooling rates, we examined type II chondrules in the CO3.0 chondrites that have experienced only minimal parent-body alteration. We discovered three kinds of evidence indicating that only minor (4-10 μm) olivine growth occurred after the final melting event: (1) Nearly all (>90%) type II chondrules in CO3.0 chondrites contain low-FeO relict grains; overgrowths on these relicts are narrow, in the range of 2-12 μm. (2) Most type II chondrules contain some FeO-rich olivine grains with decurved surfaces and acute angles between faces indicating that the grains are fragments from an earlier generation of chondrules; the limited overgrowth thicknesses following the last melting event are too thin to disguise the shard-like nature of these grains. (3) Most type II chondrules contain many small (<20 μm) euhedral or subhedral phenocrysts with central compositions that are much more ferroan than the centers of the large phenocrysts; their small sizes document the small amount of growth that occurred after the final melting event. If overgrowth thicknesses were small (4-10 μm) after the final melting event, it follows that large fractions of coarse (>40 μm) high-FeO phenocrysts are relicts from earlier generations of chondrules, and that cooling rates after the last melting event were much more rapid than indicated by models based on a single melting event. These observations are thus inconsistent with the “classic” igneous model of formation of type II porphyritic chondrules by near-total melting of a precursor mix followed by olivine nucleation on a very limited number of nuclei (say, ≤10) and by growth to produce the large phenocrysts during a period of monotonic (and roughly linear) cooling. Our observations that recycled chondrule materials constitute a large component of the phenocrysts of type II chondrules also imply that this kind of chondrule formed relatively late during the chondrule-forming period.