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Assessment of Metals Concentration and Ecotoxicology of the Sediment Core of Rehri Creek, Karachi Coast, Pakistan
Authors:, Muhammad ZCHAUDHARY , Nasir AHMAD , Azhar MASHIATULLAH , Sajjad MUNIR , Tariq JAVED
Institution:1. Isotope Application Division, Pakistan Institute of Nuclear Science and Technology(PINSTECH), Nilore Islamabad, Pakistan
2. Institute of Geology, University of the Punjab, Lahore, Pakistan
3. Department of Earth & Environmental Sciences, Bahria University Islamanad, Pakistan
Abstract:Trace metal concentrations were investigated in a recent sediment core collected from the Rehri Creek area of the Karachi coast, Sindh ‐ Pakistan. The core was sliced horizontally at 2.5‐cm intervals to determine grain size, sediment composition, pH, organic matter, and acid‐leach able trace metals: cadmium, chromium, copper, lead, and zinc. The trace metals were analyzed by ICP. To separate anthropogenic from geogenic input, several approaches were made, including comparison with sediment quality guidelines—ecotoxicological sense of heavy metal contamination and classification by quantitative indexes. Grain‐size analysis and sediment composition of core sample show a sandy nature with neutral pH. Elemental sequence (ES) of the trace metals is in the order of Zn (19.2–109.56 ppm) > Si (66.46–101.71 ppm) > Ba (12.05–26.86 ppm) > As (8.18–17.36 ppm) > Ni (4.2–14.69 ppm) > Cr (3.02–9.62 ppm) > Pb (2.79–6.83 ppm) > Cu (2.2–5.29 ppm) > Co (0.9–2.05 ppm). Thus it is likely that the area may face a serious threat of metal pollution with the present deposition rates unless stringent pollution control norms are adopted. The Sediment Geo‐accumulation Index shows that there is no Cr, Cu, Ni, Pb, Zn, or Fe pollution; however, the former index and the Pollution Load Index indicate arsenic pollution in the sediments.
Keywords:trace elements  lake sedimentation  sediment quality guidelines  pollution  shale values
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