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Dry granulite mineral assemblages in the contact aureoles of the Nain complex,Labrador
Authors:Jonathan H Berg
Institution:(1) Department of Geology, Northern Illinois University, 60115 DeKalb, Illinois, USA
Abstract:Thermal aureoles surrounding intrusions of the Nain complex, Labrador, contain many unique or unusual mineral assemblages in aluminous gneisses and granulites, ironstones, and ultramafic rocks. Some of the limiting assemblages are (in addition to feldspars±pyrrhotite±ilmenite±graphite ±biotite±magnetite): Ga-Ol-Hy-Sp, Ga-Cd-Hy-Sp, Ga-Hy-Ol-Qz, Cd-Hy-Os-Qz, Ga-Cd-Sp-Si, Cd-Sp-Co-Si, Ga-Ol-Hy-Sp, Ga-Cd-Hy-Sp, Hy-Ol-Qz-Aug, and Ol-Hy-Sp(±Chl±Ca-amph±Aug). On the basis of some of these assemblages are (in addition to feldspars±pyrrhotite±ilmenite±graphite from 3.7–6.6 kbar and temperatures from 645–915 ° C. The paucity of hydrous phases, the preponderance of Ksp-Plag-Qz or even Cd-Ksp-Qz without evidence of a melt at these temperatures, the stable occurrence of osumilite, and the common presence of graphite suggest that 
$$P_{{\text{H}}_{\text{2}} {\text{O}}}$$
was extremely low. The presence of graphite-pyrrhotite, the compositions of ilmenites, the compositions of coexisting Fe-Ti oxides, and other mineralogical data indicate the 
$$f_{{\text{O}}_{\text{2}} }$$
was relatively low and, despite the wide range in bulk compositions and rock types, may have followed an approximately buffered trend. It is possible that the magmas of the Nain complex may have acted as an ldquoexternalrdquo 
$$f_{{\text{O}}_{\text{2}} }$$
buffer for the aureole rocks. The unique nature of these mineral assemblages appears to be a function of the extremely low 
$$P_{{\text{H}}_{\text{2}} {\text{O}}}$$
.
Keywords:
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