Volatiles from Hawaiian submarine basalts determined by dynamic high temperature mass spectrometry

Quantitative measurements of volatiles from Hawaiian submarine basalts have been made using a Knudsen cell dynamic-mass spectrometer system. The principal advantage of the technique is the ability to determine simultaneously the absolute amounts of more than one volatile released from the same sample.From mass pyrograms it was observed that the release of water was bimodal, with the major release occurring above 600°C. Water released below this temperature is believed not to have been present in the magma at the time of extrusion. Sulfur dioxide was evolved only after the bulk of the water was released and coincided with the general expansion and melting of the sample. Sulfur and carbon- containing gases which were released in surges (above 1000°C) correspond to the bursting of bubbles from the softened basalt.The molar amounts of vesicle gases were plotted as a function of extrusion depth. A change in the slope of the resulting linear curve indicates saturation of the basalt with respect to water.