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Stereoisomers of isovaline in the Murchison meteorite
Authors:Glenn E Pollock  C-N Cheng  Sonja E Cronin  Keith A Kvenvolden
Institution:Planetary Biology Division, Ames Research Center, NASA, Moffett Field, California 94035, U.S.A.
Abstract:Isovaline is present in the Murchison meteorite as a racemic mixture (about equal concentrations of the R and S enantiomers). Since isovaline does not have a hydrogen atom on its asymmetric α-carbon atom, the racemic mixture could not have formed by commonly accepted mechanisms of racemization. Thus, isovaline in the meteorite most probably was synthesized as a racemic mixture and is not the result of the racemization of either the R or S enantiomer. Other chiral amino acids in the meteorite are present as racemic mixtures, and were probably synthesized in a similar manner by abiotic, extraterrestrial processes.
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