Collisional excitation of metastable oxygen O(D) atoms through the B∑u channel of O2

Pectroscopic data on the shifts and widths of the energy levels of molecular oxygen have been used in the empirical construction of a diabatic potential matrix that characterizes the interactions of the B³∑⁻_u state with the ⁵Π_u, 2³∑⁺_u, ³Π_u and ¹Π_u states. The diabatic potential matrix is u theory formulation to calculate the cross-sections for the excitation of O(¹D) atoms in collisions of two O(³P) atoms. Total cross-sections are obtained by adding the excitation from the ³Π_g, channel. The rate coefficient for quenching of O(¹D) by O(³P) is evaluated as a function of temperature. The values conflict with a recent analysis of the emission of the oxygen red line in the upper atmosphere.