Helium isotopes and mantle volatiles in Loihi Seamount and Hawaiian Island basalts and xenoliths

We examine in this paper the use of helium isotope ratios for the study of hotspot volcanism along age-progressive island volcanic chains. The Hawaiian Islands are the original “high ³He” hotspot, with ³He/⁴He ratios as high as 32 × the atmospheric ratio; in the Pacific they stand out against the surrounding sea of MORB (rather uniformly 8 × atmospheric) which fills the entire Pacific with the exception of the Macdonald-Mehetia-Samoa axis in the South Pacific. The recent availability of a variety of alkalic and tholeiitic glasses from the U.S. Geological Survey and our own dredge hauls has prompted us to look first at isotopic variability within a single fresh and new volcano which is probably sitting directly atop a mantle plume. Thus we have looked in some detail at the total helium in glass pillow rims, at He in the enclosed vesicles, and at He in the glass itself, in both tholeiitic and alkalic lavas, and also at helium in associated phenocrysts and xenoliths. The measured ³He/⁴He ratios range from atmospheric to 30 × atmospheric, but we see clear evidence that the highly vesiculated lavas suffer exchange of He between the thin glass walls of vesicles and ambient seawater, so that we observe a post-eruptive isotopic disequilibrium between glass and gas phases. The primary effect is the very large loss of initial He content during eruptive vesiculation, which results in quite large isotopic effects from small additions of ambient He (of the order of 0.02 μcc He per gram of basalt; corresponding to a “water/rock ratio” of 0.5). Phenocrystic He in olivines verifies that the gas-phase He is not affected by vesicularities up to about 5%. Alkali basalt He appears to be independent of vesicularity up to values as high as 35%; this He is somewhat lower in ³He/⁴He ratio, but matches precisely the associated xenolithic He. However, from the present data we cannot exclude the possibility that diffusive exchange with seawater has affected the He ratio in alkalic vesicles.On the large scale, along the 10% of the Hawaiian chain available for subaerial sampling, we find high ³He/⁴He ratios (24 × atmospheric) in 5.5 × 10⁶-year-old lavas on Kauai. Maximum values of the ratio so far observed are in the pre-erosional Kula basalts on Maui, confirming the previous results of Kaneoka and Takaoka. Hawaii, where these high values were first observed is now seen to range from MORB ratios at Mauna Loa to only 15 × R_A at Kilauea fumaroles. Most xenolithic He so far measured is MORB He, but Loihi xenoliths have high values and are quite different in this respect. Finally, we discuss also the hydrogen and carbon isotope results on Loihi lavas, and show that these elements resemble MORB and appear not to show a distinctive plume signature.