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吸附–解吸状态下煤层气运移机制
引用本文:刘永茜, 张书林, 舒龙勇. 吸附–解吸状态下煤层气运移机制[J]. 煤田地质与勘探, 2019, 47(4): 12-18. DOI: 10.3969/j.issn.1001-1986.2019.04.003
作者姓名:刘永茜  张书林  舒龙勇
作者单位:1.1. 煤炭科学技术研究院有限公司安全分院,北京 100013
基金项目:国家科技重大专项任务(2016ZX05045-002-006);国家自然科学基金青年基金项目(51504137,51704164)
摘    要:带吸附作用的煤层气运移规律一直是煤层气地质学界关注的焦点问题之一。为研究吸附-解吸状态下的煤层气运移机制,推导了气体吸附-解吸方程并分析了多孔介质扩散-渗流理论,开展了煤层气运移实验并对实验结果进行了分析。研究结果发现:煤体孔隙结构对煤层气运移具有

关 键 词:煤层气运移机制  吸附-解吸  容阻效应  动力吸附  双重介质  分子极性
收稿时间:2019-01-15

Coalbed methane migration mechanism under adsorption-desorption condition in coal
LIU Yongqian, ZHANG Shulin, SHU Longyong. Coalbed methane migration mechanism under adsorption-desorption condition in coal[J]. COAL GEOLOGY & EXPLORATION, 2019, 47(4): 12-18. DOI: 10.3969/j.issn.1001-1986.2019.04.003
Authors:LIU Yongqian  ZHANG Shulin  SHU Longyong
Affiliation:1.1. Mine Safety Technology Branch, China Coal Research Institute, Beijing 100013, China
Abstract:The migration law of coalbed methane(CBM) with adsorption has always been the focus of attention in the field of coalbed methane geology. In order to study the mechanism of CBM migration under adsorption-desorption state, the deduction of gas adsorption-desorption equation and theoretical analysis of gas diffusion-seepage in porous media were carried out, and new viewpoints were put forward by means of experimental analysis of CBM migration. The results identified that:(1) for the CBM migration, pore structure of coal body has the storage-resistance effect, the dual functions of gas storage and gas pressure drop form the basic feature of coal matrix, (2) adsorption reaction time, adsorption rate, growth rate, adsorption equilibrium time and the maximum adsorption capacity are 4 key indexes of the different gases, (3) diffusion and seepage coexist in the process of CBM migration. When the gas pressure in fracture and macropore is higher than that in medium-micropore system, the gas migration velocity is dominated by seepage, otherwise diffusion is dominant. 
Keywords:the migration mechanism of CBM  adsorption and desorption  capacitive resistance effect  dynamic adsorption  binary medium  molecular polarity
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