Chemical fractionation of metals in freshly deposited marine estuarine sediments of sundarban ecosystem,India

Sediment metal profiles were carefully examined for their distribution, chemical fractions, and mobility in three major marine-estuarine transects in the world’s largest mangrove (Sundarban) ecosystem because anthropogenic influences had been very often noticed. The level of pollutants was determined by CF and PLI. Metal contents in the freshly deposited sediment of Hugli transect were relatively high (Pb, Fe, Zn, Mn, Ni, and Co) in comparison to Matla and Saptamukhi due to lithogenic contribution from large catchments area (8 × 10⁵ km²). Principal component analysis and correlation coefficient revealed that the concentrations of metals were mainly governed by the variability of the sediment properties. Sediment was subjected to sequential chemical extractions to delineate metal fractions, namely exchangeable, carbonate, Fe–Mn oxide, organic, and residual. This indicated a valuable insight into the geochemical mode of the metal retention and their environmental behavior. Single extraction did not help significantly to explain the metal profiling.