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Raman characteristics of hydrocarbon and hydrocarbon inclusions
作者单位:ZHANG Nai(Research Institute of Petroleum Exploration and Development, Beijing 100083, China) ;TIAN ZuoJi(Research Institute of Petroleum Exploration and Development, Beijing 100083, China) ;LENG YingYing(Zhengyuan Geology Exploration Company of China Metallurgical Geology Bureau, Shandong, Jinan 250014, China) ;WANG HuiTong(Research Institute of Petroleum Exploration and Development, Beijing 100083, China) ;SONG FuQing(Research Institute of Petroleum Exploration and Development, Beijing 100083, China) ;MENG JianHua(Research Institute of Petroleum Exploration and Development, Beijing 100083, China) ;
摘    要:The Raman spectrograms of hydrocarbon standard samples show that: (1) the Raman spectrogram of normal paraffin has very strong peaks of methyl and methylene (from 2700 cm-1 to 2970 cm-1); (2) branch methyl has the particular peak of 748 cm-1±; (3) six cyclic has the particular peak of 804 cm-1±; (4) phenyl has two particular peaks of 988 cm-1± and 3058 cm-1± and the 988 cm-1± peak is stronger than the 3058 cm-1± peak; and (5) hexene has three alkenyl spectrum peaks of 1294 cm-1±, 1635 cm-1± and 2996 cm-1±, with the 1635 cm-1± peak being the strongest, showing that the number of carbon in hy-drocarbon does not affect its Raman spectrogram, and the hydrocarbon molecular structure and base groups affect its Raman spectrogram, the same hydrocarbons (such as normal paraffin) have the same Raman spectrogram; the types (such as CH4, C2H6, C3H8) and the content of hydrocarbon in oil inclu-sions are not estimated by their characteristic Raman peaks. According to the Raman spectrograms of hydrocarbon compositions, the Raman spectrogram of hydrocarbon inclusion can be divided into five types: saturated hydrocarbon Raman spectrogram, fluoresce Raman spectrogram, saturated hydro-carbon bitumen Raman spectrogram, bitumen Raman spectrogram, and ethane Raman spectrogram. And according to the characteristics of Raman spectrogram, hydrocarbon inclusions can be divided into five types: saturated hydrocarbon inclusion, less saturated hydrocarbon (oil or gas) inclusion, saturated hydrocarbon bitumen inclusion, bitumen inclusion, and methane water inclusion.

收稿时间:2007-01-04
修稿时间:2007-03-13

Raman characteristics of hydrocarbon and hydrocarbon inclusions
Zhang Nai,Tian ZuoJi,Leng YingYing,Wang HuiTong,Song FuQing,Meng JianHua. Raman characteristics of hydrocarbon and hydrocarbon inclusions[J]. Science in China(Earth Sciences), 2007, 50(8): 1171-1178. DOI: 10.1007/s11430-007-0078-9
Authors:Zhang Nai  Tian ZuoJi  Leng YingYing  Wang HuiTong  Song FuQing  Meng JianHua
Affiliation:1. Research Institute of Petroleum Exploration and Development, Beijing 100083, China
2. Zhengyuan Geology Exploration Company of China Metallurgical Geology Bureau, Shandong, Jinan 250014, China
Abstract:The Raman spectrograms of hydrocarbon standard samples show that: (1) the Raman spectrogram of normal paraffin has very strong peaks of methyl and methylene (from 2700 cm−1 to 2970 cm−1); (2) branch methyl has the particular peak of 748 cm−1±; (3) six cyclic has the particular peak of 804 cm−1±; (4) phenyl has two particular peaks of 988 cm−1± and 3058 cm−1± and the 988 cm−1± peak is stronger than the 3058 cm−1± peak; and (5) hexene has three alkenyl spectrum peaks of 1294 cm−1±, 1635 cm−1± and 2996 cm−1±, with the 1635 cm−1± peak being the strongest, showing that the number of carbon in hydrocarbon does not affect its Raman spectrogram, and the hydrocarbon molecular structure and base groups affect its Raman spectrogram, the same hydrocarbons (such as normal paraffin) have the same Raman spectrogram; the types (such as CH4, C2H6, C3H8) and the content of hydrocarbon in oil inclusions are not estimated by their characteristic Raman peaks. According to the Raman spectrograms of hydrocarbon compositions, the Raman spectrogram of hydrocarbon inclusion can be divided into five types: saturated hydrocarbon Raman spectrogram, fluoresce Raman spectrogram, saturated hydrocarbon bitumen Raman spectrogram, bitumen Raman spectrogram, and ethane Raman spectrogram. And according to the characteristics of Raman spectrogram, hydrocarbon inclusions can be divided into five types: saturated hydrocarbon inclusion, less saturated hydrocarbon (oil or gas) inclusion, saturated hydrocarbon bitumen inclusion, bitumen inclusion, and methane water inclusion.
Keywords:Raman  Raman spectrogram  oil  hydrocarbon inclusion
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