Removal of heavy metal ions from drinking water by alginate-immobilised Chlorella sorokiniana

This paper investigates the potential of alginate-immobilised Chlorella sorokiniana for removing Cu²⁺, Ni²⁺ and Cd²⁺ ions from drinking water solutions. The effects of initial metal concentrations, contact times and temperatures on the biosorptions and removal efficiencies of the tested metals were investigated at initial pH values of 5, and pH effects were studied within the range of 3–7. When studying the effects of initial metal concentrations, the highest experimental removal yields achieved for Cu²⁺, Ni²⁺ and Cd²⁺ ions were 97.10, 50.94 and 64.61 %, respectively. The maximum biosorption capacities obtained by the Langmuir isotherm model for the biosorptions of Cu²⁺, Ni²⁺ and Cd²⁺ ions by alginate-immobilised C. sorokiniana were found to be 179.90, 86.49 and 164.50 mg/g biosorbent, respectively. The experimental data followed pseudo-second-order kinetics. At an initial metal concentration of 25 mg/L, immobilised algae could be used in at least 5 successive biosorption–desorption cycles. SEM and EDS analyses revealed that the metals bonded to the biosorbent. Bi- and multi-metal systems of Cu²⁺, Ni²⁺ and Cd²⁺ were investigated at initial metal concentrations of 30, 50 and 100 mg/L. The removal of Cd²⁺ as well as Ni²⁺ in such systems was negatively affected by the presence of Cu²⁺. The removal efficiency for Cu²⁺ in multi-metal systems decreased by 5–7 %, whilst in the cases of Cd²⁺ and Ni²⁺ the efficiencies decreased by up to 30 %. Nevertheless, the results obtained show that alginate-immobilised C. sorokiniana can efficiently remove the metals tested from polluted drinking water sources.