Inorganic ions and trace metals bulk deposition at an Atlantic Coastal European region |
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| Authors: | Jorge Moreda-Piñeiro Elia Alonso-Rodríguez Isabel Turnes-Carou Carmen Moscoso-Pérez Gustavo Blanco-Heras Loreto Gómez Tellado Purificación López-Mahía Soledad Muniategui-Lorenzo Darío Prada-Rodríguez |
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| Affiliation: | 1.Grupo Química Analítica Aplicada (QANAP), University Institute of Research in Environmental Studies (IUMA), Centro de Investigaciones Científicas Avanzadas (CICA), Department of Analytical Chemistry, Faculty of Sciences,University of A Coru?a,A Coru?a,Spain;2.Laboratorio de Medio Ambiente de Galicia, Consellería de Medio Ambiente, Territorio e Infraestructuras,A Coru?a,Spain |
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| Abstract: | The inorganic chemical composition (major ions and trace metals) of bulk deposition samples collected monthly with bulk collectors at seven Atlantic Coastal European cities (Galicia, Northwest of Spain) during wet season (September 2011 to March 2012) has been assessed and compared. Trace metals (Al, As, Ba, Co, Cr, Cu, Fe, Mn, Ni, Pb, Sr, V and Zn) were analysed in soluble fraction and non-soluble fraction (after acid extraction) of the bulk deposition by inductively coupled plasma-mass spectrometry. Major inorganic ions (Cl?, NO3 ?, SO4 2?, Na+, K+, Ca2+, Mg2+ and NH4 +) were analysed in the soluble fraction of the bulk deposition by capillary zone electrophoresis. Univariate analysis (ANOVA and Multiple Range Test) according to the location of each sampling site was performed. Results also suggest a great influence of cleaner Atlantic air masses. After partition coefficients and enrichment factor estimation, similar sources could be assigned for the ionic and metal composition of bulk deposition at seven urban sites. |
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