Application of enzyme leach soil analysis for epithermal gold exploration in the Andes of Ecuador

Enzyme Leach^SM (EL) soil surveys were undertaken over known epithermal Au mineralisation at El Mozo and Llano Largo, Azuay, Ecuador to assess the utility of the technique for identifying such deposits in the Ecuadorian Andes. The results indicate the development of both apical- and oxidation-type EL anomalies over auriferous structures at the two sites, the former systematically incorporating Au, and the latter Cl and Br. The spectrum of elements responsive to mineralisation at El Mozo (Cl, Br, I, La, Ce, Nd, Cu, Pb, Au, As, Sb, Ag, Zr, Sr) was found to be considerably greater than at Llano Largo (Cl, Br, Au, As, Sb, Ag, Zn), probably reflecting the contrasting high- and low-sulphidation assemblages of the two prospects. Ratios of EL versus aqua-regia extractable trace element concentrations ranged from 1:<100 for Mn to 1:>400 for chalcophile elements such as Pb, Sb, As, Bi and Ag. Strong correlations between the concentrations of several analytes (including Mn, Sr, Cu, Co, As) extracted by the two procedures indicate, however, that EL datasets are extensively influenced by bulk matrix composition. Spatial variations of EL extractable Mn were found to exert no major influence on apical or oxidation suite anomaly patterns at El Mozo. However, Mn-normalisation of halogen data for Llano Largo elucidated otherwise obscure oxidation features, potentially related to Au mineralisation. Ratios between elements subject to apical enrichment and those of the oxidation suite (e.g. Cl/Au and Bi/Br) were found to highlight known Au targets with improved clarity. The formation mechanism of the recorded Au anomalies is uncertain, but may involve physical enrichment of Au in the soil during pedogenesis with subsequent in-situ formation of (EL soluble) Au halide complexes. The strength of such apical features is, in part, probably a function of the minimal depths to mineralisation which characterise El Mozo and Llano Largo. Oxidation halos formed by volatile non-metallic elements such as Cl and Br may, therefore, provide more valuable EL pathfinders for more deeply concealed epithermal targets.