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Structural characteristics of zeolite/TiO-2 composite and photocatalysis of toluene degradation
引用本文:明彩兵,吴平霄. Structural characteristics of zeolite/TiO-2 composite and photocatalysis of toluene degradation[J]. 中国地球化学学报, 2005, 0(4)
作者姓名:明彩兵  吴平霄
作者单位:College of Automotive Engineering,South China University of Technology,Guangzhou 510640,China,College of Environmental Science and Engineering,South China University of Technology,Guangzhou 510640,China
基金项目:TheprojectwassupportedbytheNationalNaturalScienceFoundationofChina(GrantNo.40202007)andtheGuangdongProvincialScienceFoundation(GrantNos.04020017,020938and000623).
摘    要:1Introduction Researchontheapplicationofnaturalminerals(zeolite,montmorillonite,etc.)inenvironmentalpro tectionisattractinggreatattentionofmoreandmorere searchers(WuPingxiaoetal.,2001;Suhasetal.,2000).Asthenaturalmineralshavelargenumbersof micro poresandbigsurfaceareas,thezeolite/TiO2compositephotocatalystcanbepreparedbycombining TiO2withzeolite.Nucleus formationfreeenergyof TiO2crystaldecreasesinamulti phasesystemofzeo lite,whichhelpsformnanometerTiO2crystalanden richstructuralhydroxyl;op…


Structural characteristics of zeolite/TiO-2 composite and photocatalysis of toluene degradation
MING Caibing and WU Pingxiao College of Automotive Engineering,South China University of Technology,Guangzhou ,China College of Environmental Science and Engineering,South China University of Technology,Guangzhou ,China. Structural characteristics of zeolite/TiO-2 composite and photocatalysis of toluene degradation[J]. Chinese Journal of Geochemistry, 2005, 0(4)
Authors:MING Caibing   WU Pingxiao College of Automotive Engineering  South China University of Technology  Guangzhou   China College of Environmental Science  Engineering  South China University of Technology  Guangzhou   China
Affiliation:MING Caibing 1 and WU Pingxiao 21 College of Automotive Engineering,South China University of Technology,Guangzhou 510640,China2 College of Environmental Science and Engineering,South China University of Technology,Guangzhou 510640,China
Abstract:Zeolite/TiO-2 composite photocatalysts were prepared by adding a certain amount of mordenite in TiO-2, and degradation experiments on toluene through photocatalytic reactions were implemented. In this paper, these photocatalysts were characterized by using SEM, IR, RAMAN, XRD and UV-Vis to shed light on the microstructure and photocatalytic performance of the composite photocatalysts. The results indicated that the structural hydroxy of zeolite can participate in bonding reaction with TiO-2, the addition of zeolite can greatly reduce the diameter of nanometer TiO-2 particles in the composite photocatalysts, and enhance the ultraviolet light absorptance of the composite photocatalysts. When the percentage content of zeolite reached 20%, the photocatalytic performance of this catalyst would be highest, with the toluene conversion rate up to {94.58%}.
Keywords:zeolite/TiO-2 composite  photocatalysis  toluene  structure
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