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A climatic control on the accretion of meteoric and super-chondritic iridium–platinum to the Antarctic ice cap
Authors:Paolo Gabrielli  John MC Plane  Claude F Boutron  Sungmin Hong  Giulio Cozzi  Paolo Cescon  Christophe Ferrari  Paul J Crutzen  Jean Robert Petit  Vladimir Y Lipenkov  Carlo Barbante  
Institution:

aInstitute for the Dynamics of Environmental Processes-CNR, 30123 Venice, Italy

bLaboratoire de Glaciologie et Géophysique de l'Environnement (UMR CNRS/Université Joseph Fourier 5183), 38402 St Martin d'Heres cedex, France

cSchool of Chemistry, University of Leeds, Leeds LS2 9JT, UK

dUnité de Formation et de Recherche de Physique et Observatoire des Sciences de l'Univers (Institut Universitaire de France), Université Joseph Fourier, Domaine Universitaire, 38041 Grenoble, France

eKorea Polar Research Institute, Korea Ocean Research and Development Institute, Ansan, Seoul 425-600, South Korea

fDepartment of Environmental Sciences, University of Venice, Ca' Foscari, 30123 Venice, Italy

gPolytech Grenoble (Institut Universitaire de France), Université Joseph Fourier, 28 avenue Benoît Frachon, B. P. 53, 38041 Grenoble, France

hMax Planck Institute for Chemistry, Atmospheric Division, Joh.-J.-Becher-Weg 27, 55128 Mainz, Germany

iArctic and Antarctic Research Institute, Beringa Street 38, 199397, St Petersburg, Russia

Abstract:Meteoric smoke particles (MSPs) form through the vaporization of meteoroids and the subsequent re-condensation of metallic species in the mesosphere. Recently, iridium and platinum enrichments have been identified in Greenland ice layers and attributed to the fallout of MSPs supplying polar latitudes with cosmic matter during the Holocene. However, the MSP fallout to Antarctica during the Earth's climatic history remains essentially unknown.

We have determined iridium and platinum in deep Antarctic ice from Dome C and Vostok dated back to 240 kyrs BP. We find high super-chondritic fluxes during warm periods and low meteoric accretion during glacial times, a pattern that is opposite to any known climatic variation in dust fallout to polar regions. The proposed explanation of this accretion regime is a weaker polar vortex during warm periods, allowing peripheral air masses enriched in volcanic iridium and platinum to penetrate inland to Antarctica. The MSP signal emerges only during cold phases and is four times lower than in the Greenland ice cap where more snow accumulates. This suggests that wet deposition is an important route of cosmic material to the Earth's surface.

Keywords:iridium  platinum  meteoric smoke  ice  Antarctica  climate
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