Ce-anomalous lavas from Rabaul caldera,Papua New Guinea

REE abundances for a suite of Rabaul caldera lavas ranging from basalt to dacite are reported. Three of the lavas contain negative Ce anomalies. These ‘anomalous’ lavas are older and have a geochemistry different from the younger lavas which form the main Rabaul caldera. The consistent geochemical differences between the two groups of lavas suggest that the Ce anomaly is inherited from the source material from which the magmas were derived and is not due to differences in crystallization or fractionation paths. Ocean floor lavas containing zeolite assemblages have been shown to possess a Ce anomaly and it is concluded that those lavas having a Ce anomaly were derived from lithosphere which had been depleted in Ce during weathering and hydrothermal processes.