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Partitioning of Pb between volcanic glass and coexisting sanidine and plagioclase feldspars
Authors:William P. Leeman
Affiliation:Geology Department, Rice University, Houston, TX 77001, U.S.A.
Abstract:Pb contents were determined by isotope dilution in separated glass, sanidine, and plagioclase from 18 rocks ranging in composition from basalt to rhyolite. These data indicate that Pb is partitioned into silicate melt relative to plagioclase, but is equally distributed between melt and sanidine. Plagioclase/glass distribution coefficients increase from 0.1 to 0.7 in going from basalt to rhyolite. This relationship suggests that the distribution coefficient is dependent upon bulk composition, temperature, or both. Sanidine/glass distribution coefficients are close to unity in rocks ranging in composition from quartz latite to rhyolite. The variation in Pb contents in a natural magma series from Craters of the Moon National Monument, Idaho, indicates that minerals (olivine, plagioclase, magnetite, apatite and clinopyroxene) fractionated from these magmas all have very low crystal/liquid distribution coefficients for Pb.
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