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Precise Determination of Rubidium in Geological Reference Materials by ID-TIMS and WD-XRF: A Discussion for the Basalt BIR-1
Authors:Claire Bollinger  Joël Etoubleau
Institution:UMR 6538, Centre National pour la Recherche Scientifique, B.P. 70, 29280 Plouzané, France;Département Géosciences Marines, Institut Français pour la Recherche et l'Exploitation de la Mer, B.P. 70, 29280 Plouzané, France.
Abstract:Data were obtained for rubidium in six geological reference materials by isotopic dilution thermal ionisation mass spectrometry (ID-TIMS) and wavelength dispersive X-ray fluorescence spectrometry (WD-XRF). The results found by one technique compare very well with the other within the respective analytical uncertainties and are also in good agreement with data from previously published values. The particular case of low Rb determinations in reference sample BIR-1 is discussed.
Keywords:rubidium  reference materials  BIR-1  ID-TIMS  WD-XRF
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