Structural phase transition in titanite,CaTiSiO5: A ramanspectroscopic study

The structural phase transition in titanite is correlated with a strong temperature dependence of Raman scattering cross sections and, to a somewhat lesser extent, with shifts of the phonon frequencies. Their quantitative temperature evolution in the low-symmetry phase (P2₁/a) is compatible with a nearly 2D Ising behaviour with β≈0.12 and T _c = 497 K. At temperatures above 860 K, the phonon signals agree with A 2/a symmetry but not in the temperature interval between 497 K and 860 K. In this temperature range new structural states give rise to additional phonon signals. A model based on mobile APBs between slabs of P2₁/a material, first proposed by van Heurck et al. (1991), is in qualitative agreement with our experimental observations.