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Heterogeneously depleted Precambrian lithosphere deduced from mantle peridotites and associated chromitite deposits of Al'Ays ophiolite,Northwestern Arabian Shield,Saudi Arabia
Affiliation:1. Faculty of Earth Sciences, King Abdulaziz University, Jeddah, Saudi Arabia;2. Geology Department, Faculty of Science, Helwan University, Cairo, Egypt;1. Development Research Centre, China Geological Survey, Beijing 100037, PR China;2. School of Earth Science and Mineral Resources, China University of Geosciences, Beijing 100083, PR China;1. Department of Geological Engineering, Karadeniz Technical University, 61080 Trabzon, Turkey;2. Department of Geological Engineering, Bülent Ecevit University, 67100 Zonguldak, Turkey;3. School of Earth Science and Geological Engineering, Sun Yat-sen University, Guangzhou, PR China;1. Department of Earth Sciences, The University of Hong Kong, Hong Kong, China;2. State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing, China;3. State Key Laboratory of Geological Processes and Mineral Resources, China University of Geosciences, Wuhan, China;4. Institute of Geology, Chinese Academy of Geological Sciences, Beijing, China
Abstract:The mantle section of Al'Ays ophiolite consists of heterogeneously depleted harzburgites, dunites and large-sized chromitite pods. Two chromitite-bearing sites (Site1 and Site2), about 10 km apart horizontally from one another, were examined for their upper mantle rocks. Cr-spinels from the two sites have different chemistry; Cr-rich in Site1 and Al-rich in Site2. The average Cr-ratio = (Cr/(Cr + Al) atomic ratio) of Cr-spinels in harzburgites, dunites and chromitites is remarkably high 0.78, 0.77 and 0.87, respectively, in Site1, compared with those of Site2 which have intermediate ratio averages 0.5, 0.56 and 0.6, respectively. The platinum-group elements (PGE) in chromitites also show contrasting patterns from Site1 to Site2; having elevated IPGE (Os, Ir, Ru) and strongly depleted in PPGE (Rh, Pt, Pd) with steep negative slopes in the former, and gentle negative slopes in the latter. The oxygen fugacity (Δlog fO2) values deduced from harzburgites and dunites of Site1 show a wide variation under reducing conditions, mostly below the FMQ buffer. The Site2 harzburgites and dunites, on the other hand are mostly above the FMQ buffer. Two magmatic stages are suggested for the lithospheric evolution of Al'Ays ophiolite in response to a switch of tectonic setting. The first stage produced a peridotites–chromitites suite with Al-rich Cr-spinels, possibly beneath a mid-ocean ridge setting, or most likely in back-arc rift of a supra-subduction zone setting. The second stage involved higher degrees of partial melting, produced a peridotites–chromitites suite with Cr-rich Cr-spinels, possibly in a fore-arc setting. The coexistence of compositionally different mantle suites with different melting histories in a restricted area of an ophiolite complex may be attributable to a mechanically juxtaposed by mantle convection during recycling. The mantle harzburgites and dunites are apt to be compositionally modified during recycling process; being highly depleted (Site1 case) than their original composition (Site2 case).
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