Internally consistent calibrations for geothermobarometry of high-grade Mg-Al rich rocks in the system MgO-Al2O3-SiO2 and their application to sapphirine-spinel granulites of Eastern Ghats, India and Enderby Land, Antarctica |
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Authors: | R K Lal |
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Institution: | (1) Department of Geology, Banaras Hindu University, 221 005 Varanasi, India |
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Abstract: | Sixty-three internally consistent geothermobarometers for mineral equilibria involving sapphirine (2:2:1 and 7:9:3), pyrope,
cordierite, enstatite, Mg-tschermak orthopyroxene, quartz, spinel and sillimanite have been calibrated in the MAS system.
The updated thermodynamic data of these minerals are consistent, within limits of error, with highP-T experiments on several mineral equilibria and calorimetric data. TheP-T conditions of the granulite facies metamorphism, spanning a range of 700 to more than 1000°C and 4 to more than 10 kbar,
can be estimated simultaneously from these geothermobarometers andP-T-t trajectories can be deduced from the reaction coronas well preserved in these rocks because of the refractory nature of aluminous
phases.
The geothermobarometers have been applied to sapphirine-spinel granulites of Eastern Ghats and Enderby Land. TheP-T conditions of metamorphism (a-prograde/thermal peak and b-retrograde isothermal/isobaric decompression/cooling) estimated
for these granulites are: (1) Eastern Ghats (Visakhapatnam): Paderu- (a) 900°C/8.3kbar, (b-1) 900°C/6.8kbar and (b-2) 740°C/5.4
kbar; Anantgiri- (a) prograde anticlockwise 930°C/6.2 kbar and (b) 870°C/6.8 kbar, 820°C/6.1 kbar; Anakapalle- (b) 845°C/8.5-6.2
kbar; and Araku- (b) 840°C/6.2 kbar to 795°C/5.9 kbar. Enderby Land (Napier complex): Spot height 945, Tula Mts.- (a) 970°C/9.1
± 0.6 kbar, isobaric cooling (b) 885°C/ 7.75 kbar, isothermal decompression (b) 880°C/6.85 kbar; Mt. Hardy, Tula Mts.- (b)
885°C/6.75 kbar; Mt. Riiser-Larsen, Amundsen bay- (a) 1000°C/7.0 kbar prograde anticlockwise; Mt. Sones- (b) 920°C/ 6.8 kbar;
Forefinger Point, SW Enderby Land- (b) 840°C/6.7 kbar, 810°C/6.5 kbar and 775°C/5.0 kbar. The estimatedP-T andP-T-t are mostly consistent with those inferred from the granulites of these areas. |
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Keywords: | Geothermobarometry P-T-t trajectory sapphirine-spinel granulites mineral equilibria calorimetry |
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