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A review on the Huoqiu banded iron formation (BIF), southeast margin of the North China Craton: Genesis of iron deposits and implications for exploration
Institution:1. CAS Key Laboratory of Crust–Mantle Materials and Environments, School of Earth and Space Sciences, University of Science and Technology of China, Hefei 230026, China;2. School of Earth and Environmental Sciences, Seoul National University, Seoul 151-742, Republic of Korea;3. No. 313 Geological Team, Bureau of Geology and Exploration of Anhui, Liu''an 236000, China;4. Key Laboratory for Mineralogy and Metallogeny, Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangzhou 510640, China;1. Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;2. School of Earth Sciences and Resources, China University of Geosciences Beijing, 29 Xueyuan Road, Beijing 100083, China;3. State Key Laboratory of Lithospheric Evolution, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;1. Key Laboratory of Mineral Resources, Institute of Geology and Geophysics, Chinese Academy of Sciences, Beijing 100029, China;2. University of Chinese Academy of Sciences, Beijing 100049, China;3. Guangzhou Institute of Geochemistry, Chinese Academy of Sciences, Guangdong, Guangzhou 510640, China
Abstract:The Huoqiu iron ore field in northwest Anhui Province is located in the North China Craton (NCC). As a large banded iron formation (BIF) iron ore field, ore bodies occur in a middle-high grade of Neoarchean metamorphic formation, forming a banded silicon–iron series from north to south. The main ore bodies can be divided into two sub-belts from bottom to upper layers, i.e. the A + B ore belt consisting of leptynite–schist–magnetite–quartz formation, and the D ore belt consisting of schist–marble–hematite–quartz formation. Based on a dataset from geological settings, geophysical and geochemical exploration, ore-forming conditions and structural analysis of the iron deposit, we discuss structural types, sedimentary environments, deep tectonic and ore-controlling factors as well as characteristics and distribution of this colossal BIF ore field in the Huoqiu region.Using LA-ICP-MS techniques, we obtained the oldest U–Pb age of ca. 2.7 Ga for plagioclase amphibolite as its original rock, and 1.8 Ga for magmatic granite in the Huoqiu Group. The Hf isotopes of zircon were also determined, resulting in the oldest Hf model age of 3.5 Ga.Geochemical data indicate that the protolithes of amphibolites belong to a series of subalkaline rocks with enrichments of large ion lithophile elements and depletions of high field strength elements, which are typical volcanic arc rocks. The amphibolites have low K2O concentrations with low ratios of Ti/V (22.7 to 25.9 averaging 24.5), similar to island arc tholeiite. This suggests that the iron deposit and BIF are of the Superior type in the Huoqiu region.
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