Potassium and sodium self-diffusion in alkali feldspar |
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Authors: | T. -H. Lin R. A. Yund |
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Affiliation: | (1) Department of Geological Sciences, Brown University, 02912 Providence, Rhode Island |
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Abstract: | The rate of potassium self-diffusion in pure microcline was measured between 600° and 800° C using K40 as a tracer. Transport of K40 by processes other than volume diffusion was insignificant or minimal. Isotropic diffusion coefficients were calculated assuming spherical grains. The data are well fit by the Arrhenius relation and yield a pre-exponential factor (D0) of 133.8 cm2/sec and an activation energy (Q) of 70 kcal/mole. Similar experiments on the self-diffusion of Na22 in a pure low-albite (exchanged microcline) yield D0 of 2.31×10–6 cm2/sec and Q of approximately 19 kcal/mole for the temperature interval from 200° to 600° C. The large difference in these activation energies suggests that the atomic mechanisms for sodium and potassium diffusion are different. |
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