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三元体系MgSO_4─CH_3CONHCONH_2─H_2O及Mg(NO_3)-
引用本文:崔斌,张逢星,张军,宗建华,郭志箴. 三元体系MgSO_4─CH_3CONHCONH_2─H_2O及Mg(NO_3)-[J]. 盐湖研究, 1995, 0(3)
作者姓名:崔斌  张逢星  张军  宗建华  郭志箴
作者单位:西北大学化学系
基金项目:陕西省教育委员会专项科研基金
摘    要:本文研究了三元体系MgSO4—CH3CONHCONH2—H2O(Ⅰ)和Mg(NO3)2─CH3CONHCONH2—H2O(Ⅱ)在30℃的相平衡,测定了饱和溶液溶解度及其折光指数,绘制了相应的溶度图和折光指数─组成关系图。两个体系均为简单共饱型。溶度曲线及折光指数曲线均由两支组成,分别与MgSO4·7H2O(Ⅰ)或Mg(NO2)2·6H2O(Ⅱ)和CH2CONHCONH2相对应。共饱点的组成分别为(Ⅰ)中MgSo427.35%,CH3CONHCONH2 4.7%;(Ⅰ)中Mg(NO3)242.75%,CH3CONHCONH212.24%。这项工作对开发缓释肥料具有重要意义。

关 键 词:三元体系,相平衡,缓释肥料,乙酰脲,硝酸镁,硫酸镁

Study on the Ternary Systems MgSO_4-CH_3CONHCONH_2-H_2O and Mg(NO_3)_2-CH_3CONHCONH_2-H_2O
Cui Bin,Zhang FongxingZhang Jun,Zhong Jianhu,Guo Zhizhen. Study on the Ternary Systems MgSO_4-CH_3CONHCONH_2-H_2O and Mg(NO_3)_2-CH_3CONHCONH_2-H_2O[J]. Journal of Salt Lake Research, 1995, 0(3)
Authors:Cui Bin  Zhang FongxingZhang Jun  Zhong Jianhu  Guo Zhizhen
Abstract:The solubilities and refractive indices of saturated solution of the systems MgSO4-CH3CONHCONH2-H2O(Ⅰ) and Mg(NO3)2-CH3CONHCONH2-H2O(Ⅱ) at 30℃ have been investigated. The System(Ⅰ) or (Ⅱ) are simple eutonic type, their solubility curve and refractiv index curve are consisting of two branches, corresponding to the hydrate salt [MgSO4·7H2O(Ⅰ) and Mg(NO3)2·6H2O(Ⅱ)] and CH3CONHCONH2; the composistions of the eutonic points are: MgSO4 27. 35%, CH3CONHCONH2 4. 70%(Ⅰ); Mg(NO3)2 42. 75%, CH3CONHCONH2 12. 24%(Ⅰ). This work is ofinterest for developing controlled release fertilizers.
Keywords:Ternary system  phase equlilibrium  Controlled release fertilizers  Aceturea  Magnesium sulphate  Magnesium nitrate.  
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