An interpretation of the rotational temperature of the airglow hydroxyl emissions

The rotational temperature of the airglow hydroxyl emissions arising from various schemes of vibrational transitions was obtained by using spectroscopic data from six observational sources. The rotational temperature was found to depend systematically on the quantum number (ν') of the upper vibrational level from which the relevant band originates. It has a doubly degrading characteristic with respect to ν' taking maximal values at ν' = 6 and 9, which exceed considerably the atmospheric temperature. It drops off quickly as ν' decreases from 9 to 7, and then from 6 to 3 after making an abrupt rise at ν' = 6. This ν'-dependence of the rotational temperature is in favor of the hypothesis that there are two routes of excitation of the hydroxyl airglow: O₃ + H = OH(ν ? 9) + O₂, and HO₂ + O = OH(ν ? 6) + O₂. The present result implies also that the relaxation time of rotation of OH in the upper mesosphere is as long as 0.1 sec; a value an order of magnitude larger than that inferred in earlier laboratory experiments.