OGO-4 observations of the ultraviolet auroral spectrum

Auroral ultraviolet spectra in the range 1200–3200 A have been obtained by the spectrometer onboard the OGO-4 satellite. Emissions of N₂, H, O and N are readily identified. Atomic and molecular intensities are deduced from the comparison with a synthetic spectrum and compare reasonably well with some previous measurements and calculations. A feature at 2150 A is assigned to the (1-0) NO γ band. Taking into consideration the various excitation mechanisms of NO(A²σ) we propose that the energy transfer from N₂ metastable molecules to oxygen accounts for the excitation of the NO γ bands. In particular, we suggest that the resonant reaction between O₂ and highly metastable N₂(W³Δ) molecules may be a major source of NO(A²σ).