Excitation processes of infrared atmospheric emissions

Excitation rates of the infrared emissions which are likely to occur in the mesosphere and thermosphere are quantitatively evaluated. They include the 9.6 μm band of O₃, the 15 and 4.3 μm bands of CO₂ and the 5.3 and 2.8 μm bands of NO. These emissions may be excited through nonthermal processes such as chemiluminescent reactions and resonant fluorescence in the thermosphere, whereas they are of thermal origin in the stratosphere and mesosphere. Increase of the non-thermal excitation rate caused by precipitating electrons could be responsible for the enhancement of the 4.3 μm band of CO₂, and the 5.3 and 2.8 μm bands of NO observed in the auroral thermosphere.