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Manganese pyroxenoids and carbonates: Critical phase relations in metamorphic assemblages from the Alps
Authors:Tj Peters  V Trommsdorff  J Sommerauer
Institution:(1) Mineralogisch-Petrographisches Institut, Universität Bern, Sahlistraße 6, CH-3012 Bern;(2) Institut für Kristallographie und Petrographie, ETH-Zentrum, CH-8092 Zürich
Abstract:The compositions of coexisting pyroxmangites, rhodonites, rhodochrosites and manganese calcites in regional metamorphosed manganese cale-silicate marbles from Val Scerscen and Alagna were analysed by microprobe and permit definition of critical tie lines at metamorphic grades appropriate to temperatures between 400 and 450 °C.Variations in composition of coexisting mineral pairs in one and the same locality are attributed to variations in 
$$f_{{\text{CO}}_{\text{2}} }$$
and not to metamorphic temperatures. From the analysed assemblages isothermal 
$$f_{{\text{CO}}_{\text{2}} }  - X_{{\text{Ca/Ca + Mn}}}$$
plots (with SiO2 as excess component) were constructed for the system CaO-MnO-SiO2-CO2.
Keywords:
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