Applications of computer modeling to the study of the genesis of stratiform sulfide deposits

Stratiform sulfide deposits are considered to have formed at or near the discharge vents of submarine hydrothermal systems. Such deposits constitute an important source of zinc, lead, copper, silver, and gold. They are often divided on the basis of the dominant host-rock lithology into volcanogenic and sediment-hosted types. In terms of their economic base metal contents, volcanogenic deposits contain either Cu and Zn or Zn, Pb, and Cu, whereas sediment-hosted deposits usually contain predominantly Zn and Pb. Mathematical models of the chemical characteristics of stratiform sulfide deposits are based on a program (B)which allows the calculation of the equilibrium distribution of aqueous species in a hydrothermal solution. Program B is front-ended by Program A, which defines the components of the chemical system, and back-ended by Program C, which controls the mode of output of the calculated results. Programs A and C are tailored to the specific problem under investigation. Results of chemical modeling of the two chemically active zones of the hydrothermal system (1. the hydrothermal reservoir in which the ore-forming solutions are generated and, 2. the site of ore deposition)suggest explanations of various characteristics of stratiform sulfide deposits, and include

1. The consistency of the metal associations and metal ratios suggest that ore-forming hydrothermal solutions are saturated with respect to the major metals in the reservoir zone. The chemistry of the solutions is determined mainly by temperature and chemical equilibrium between the hydrothermal solution and the rock-forming minerals of the reservoir.
2. Metal associations and metal ratios corroborate isotopic and other evidence that volcanogenic deposits were formed from hotter hydrothermal systems (> 200°Capprox.)than sediment-hosted (< 200°Capprox.)Metal ratios suggest that the hydrothermal reservoirs were contained in mafic rocks (ferromagnesian-feldspar mineral assemblages)for the Cu-Zn association; in felsic rocks and/or sediments (feldspar-mica; clay mineral assemblages)for the Zn-Pb-Cu association: and in sediments (dominated by clay mineral assemblages)for the Zn-Pb association.
3. Chemical zonation patterns and ore textures characteristics of volcanogenic deposits are explained by rapid cooling of the hydrothermal solution immediately above its discharge vent.
4. Chemical zonation patterns and the fine laminations of sediment-hosted deposits are explained by the comparatively slow degeneration of hydrothermal solutions that have collected as a brine pool on the ocean floor.