Mass flow and the validity of ionization equilibrium on the Sun

Ionization equilibrium is a useful assumption which allows temperatures and other plasma properties to be deduced from spectral observations. Inherent to this assumption is the premise that the ion stage densities are determined solely by atomic processes which are local functions of the plasma temperature and electron density. However, if the time scale of plasma flow through a temperature gradient is less than the characteristic time scale for an important atomic process, deviations from the ionization stage densities expected for equilibrium will occur which could introduce serious errors into subsequent analyses. In the past few years, significant flow velocities in the upper solar atmosphere have been inferred from observations of emission lines originaing in the transition region (about 10⁴–10⁶ K) and corona. In this paper, three models of the solar atmosphere (quiet Sun, coronal hole, and a network model) are examined to determine if the emission expected from these model atmospheres could be produced from equilibrium ion populations when steady flows of several kilometers per second are assumed. If the flows are quasi-periodic instead of steady, spatial and temporal averaging inherent in the observations may allow for the construction of satisfactory models based on the assumption of ionization equilibrium. Representative emission lines are analysed for the following ions: C iii, iv, O iv, v, vi, Ne vii, viii, Mg ix, x, Si xii, and Fe ix–xiv. Two principle conclusions are drawn. First, only the iron ions are generally in equilibrium for steady flows of 20 km s^–1. For carbon and oxygen, ionization equilibrium is not a valid assumption for steady flows as small as 1 km s^–1. Second, the three models representing different solar conditions behave in a qualitatively similar manner, implying that these results are not particularly model dependent over the range of temperature gradients and electron densities thus far inferred for the Sun. In view of the flow velocities which have been reported for the Sun, our results strongly suggest caution in using the assumption of ionization equilibrium for interpreting spectral lines produced in the transition region.The National Center for Atmospheric Research is sponsored by the National Science Foundation.