Authigenic calcium carbonate flux in groundwater-controlled lakes: Implications for lacustrine paleoclimate records

Groundwater dominated lakes are an important feature of many landscapes. Their sediments are a particularly valuable source of paleoenvironmental information in semiarid regions where perennial lakes may otherwise be scarce. Where groundwater and lake composition are favorable, carbonate mineral precipitation, evaporative concentration of lake water, and microbial processes can combine to strongly deplete dissolved Ca relative to influent groundwaters. The authigenic carbonate flux (ACF) can then become limited by water column cation availability and thereby be coupled to groundwater inflow rates and aquifer recharge. Here we analyze sedimentary records from two marl-producing, groundwater-controlled lakes and demonstrate a link between one-dimensional ACF and the Palmer Drought Severity Index (PDSI), a measure of land surface wetness. In a restricted outflow lake with high-carbonate alkalinity, ACF is enhanced during historically wet climatic periods in response to increased aquifer recharge rates. ACF in this lake declines during droughts. A neighboring dilute lake with a high rate of groundwater outflow shows comparatively weak coupling between ACF and PDSI history. Ionic chemistry, carbonate mineral equilibria, and δ¹³C patterns of dissolved inorganic carbon show that the sensitivity of the ACF signal depends on the degree of evaporative evolution of lake water and the mineral saturation state of the water column under conditions of stratification and ice cover.