Application of magnetic adsorbent with silicate and phenyl polymers to adsorb Rhodamine B |
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| Authors: | C.-S. Chiou H.-W. Chen Z.-T. Chen |
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| Affiliation: | 1.Department of Environmental Engineering,National Ilan University,Yilan,Taiwan;2.Department of Chemical and Materials Engineering,National Ilan University,Yilan,Taiwan |
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| Abstract: | The extensive use of Rhodamine B (RhB) for textile, paper, pigment, food, cosmetic, and drug manufacturing and its indiscriminate disposal leads to serious human, biological, and environmental hazards. A magnetic adsorbent with silicate and phenyl polymers (Ph/SiO2/Fe3O4) has been prepared to absorb RhB. The morphology and structure of the adsorbents have been characterized by TGA, XRD, FTIR, and adsorption–desorption measurement. The results revealed that Ph/SiO2/Fe3O4 exhibited a paramagnetic behavior and could easily and quickly be separated from a suspension. The RhB adsorption behavior was almost pH independent due to the adsorption between the phenyl ring of Ph/SiO2/Fe3O4 and RhB by π–π electron-donor–acceptor interactions. The adsorption behavior of RhB adsorption was in good agreement with the Langmuir adsorption isotherm, and the maximum adsorption capacity was 142.186 mg g?1. Good desorption performance of Ph/SiO2/Fe3O4 showed that this novel magnetic adsorbent cannot only be activated by ethanol extraction process but also reuse by the recovery of magnetic force. |
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