Preparation of strontium ferrite from strontium residue |
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Authors: | Chenglun Liu Longjun Xu Xueyan Yang Tiefeng Peng Jianjun Ren |
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Affiliation: | 1. College of Chemistry and Chemical Engineering, Chongqing University, Chongqing, 400044, China 2. State Key Laboratory of Coal Mine Disaster Dynamics and Control, Chongqing University, Chongqing, 400044, China 3. Department of Engineering Technology, Guizhou Vocational Technical Institute, Guiyang, 550004, China
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Abstract: | Strontium ferrite was prepared from Strontium Waste Residue (SWR) as a material. Strontium chloride was obtained by leaching SWR with ammonia chloride, and then SrCl2 was converted to SrCO3. Strontium ferrite (SrFe12O19) was formed by roasting the mixture of SrCO3 and FeCl3 in a proper proportion. The structure and magnetic susceptibility of strontium ferrite were investigated. The results showed that strontium conversion ratio increased with decreasing SWR grain diameter. The largest ratio was presented when n(NH4Cl/Sr) was 3.6. What is more, the conversion process coincided with the kinetic characteristics of fractal reaction. The magnetic susceptibility of strontium ferrite decreased with increasing Fe3+/Sr2+ mole ratio and pH. SrFe12O19 exhibited face-centered and cubic closely-packed hexagonal structures. There were the strong diffraction peaks of Fe2O3 in the X-ray diffractogram of strontium ferrite. Strontium recovery ratio was 87.0%. |
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Keywords: | strontium residue strontium ferrite magnetic susceptibility X-ray diffraction fractal reaction |
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