The treatment of smelter fume prior to segregation roasting |
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Authors: | I.J. Bear J.F. Moresby L.M. Curnick |
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Affiliation: | CSIRO Division of Mineral Chemistry, P.O. Box 124, Port Melbourne, Vic. 3207 Australia |
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Abstract: | A method is described whereby smelter fume, containing lead and zinc as major components and copper as a valuable impurity, may be pretreated so that subsequently 80–90% of the lead can be segregated and separated as PbS on char, with 92–98% of the zinc and 80–85% of the copper remaining in the residue in a form that can be treated by processes such as the commercial Jarosite process for treating zinc residues.The pretreatment involves selective sulphate roasting of the fume, premixed with an iron-containing additive, substantially all lead compounds in the fume are converted to lead sulphate and all zinc and copper complexed as ferrites. Depending on the nature of the iron-containing additive, the sulphate-roasting atmosphere can be provided by feeding SO2 and O2 or air mixtures to the roaster, or it can be generated internally by the oxidation and/or decomposition of sulphur compounds in the fume—iron-additive mixture. In either case, 800°C is the optimum sulphate-roast temperature. The distribution of impurities in the fume is discussed. |
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