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The ZONMET thermodynamic and kinetic model of metal condensation |
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| Authors: | Michail I Petaev John A Wood Alexander N Krot |
| Affiliation: | 1 Harvard-Smithsonian Center for Astrophysics, 60 Garden St., Cambridge, MA 02138, USA 2 Department of Earth and Planetary Sciences, Harvard University, 20 Oxford St., Cambridge, MA 02128, USA 3 Geological and Environmental Sciences, Stanford University, 320 Lomita Mall, Stanford, CA 94305, USA 4 Hawaii Institute of Geophysics and Planetology, School of Ocean and Earth Science and Technology, University of Hawaii at Manoa, Honolulu, HI 96822, USA |
| Abstract: | The ZONMET model of metal condensation is a FORTRAN computer code that calculates condensation with partial isolation-type equilibrium partitioning of the 19 most abundant elements among 203 gaseous and 488 condensed phases and growth in the nebula of a zoned metal grain by condensation from the nebular gas accompanied by diffusional redistribution of Ni, Co, and Cr. Of five input parameters of the ZONMET model (chemical composition of the system expressed as the dust/gas [D/G] ratio, nebular pressure [Ptot], isolation degree [ξ], cooling rate (CR), and seed size), only two—the D/G ratio and the CR of the nebular source region of a zoned Fe,Ni grain—are important in determining the grain radius and Ni, Co, and Cr zoning profiles. We found no evidence for the supercooling during condensation of Fe,Ni metal that is predicted by the homogeneous nucleation theory. The model allows estimates to be made of physicochemical parameters in the CH chondrite nebular source regions.Modeling growth and simultaneous diffusional redistribution of Ni, Co, and Cr in the zoned metal grains of CH chondrites reveals that the condensation zoning profiles were substantially modified by diffusion while the grains were growing in the nebula. This means that previous estimates of the physicochemical conditions in the nebular source regions of CH and CB chondrites, based on measured zoning profiles of Ni, Co, Cr, and platinum group elements in Fe,Ni metal grains, need to be corrected.The two zoned metal grains in the PAT 91456 and NWA 470 CH chondrites studied so far require nebular source regions with different chemical compositions (D/G = 1 and D/G = 4, respectively) and thermal histories characterized by variable cooling rates (CR = 0.011 + 0.0022 × ΔT K/h and CR = 0.05 + 0.0035 × ΔT K/h, respectively). It appears that the metal grains of the CH chondrites were formed in multiple nebular source regions or in different events within the same source region as the CB chondrite metal grains were formed. |
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