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Dimethylsulfide in coastal zone of the East China Sea
Authors:Naoaki Uzuka  Shuichi Watanabe  Shizuo Tsunogai
Affiliation:(1) Department of Chemistry, Graduate School of Fisheries Sciences, Hokkaido University, 041 Hakodate, Japan;(2) Laboratory of Marine and Atmospheric Geochemistry, Graduate School of Environmental Earth Science, Hokkaido University, 060 Sapporo, Japan
Abstract:Dimethylsulfide (DMS) in seawater were observed four times from February 1993 to August 1994 along a fixed section (PN line) in the East China Sea. The DMS concentrations showed remarkable temporal and spatial variations. The DMS concentrations were generally higher in the upper euphotic layer of the continental shelf zone in summer. The spatial variation, however, was more pronounced even in well mixed winter water, where the concentration of DMS varied widely from 3 to 106 ng-S/l in the continental shelf zone while the salinity was vertically almost uniform. This means that DMS in seawater is rapidly produced and decomposed with a time scale less than one month in the water column. The largest value of 376 ng-S/l was obtained at 5 m depth near the mouth of Changjiang River in August 1994. The mean concentrations in the surface 30 m layer in the continental shelf zone were 21, 54, 126 and 57 ng-S/l in February, October, June and August, respectively, which were about twice as large as those in the Kuroshio region. The mean fluxes of DMS from the East China Sea to the atmosphere are estimated to be 49 mgrg-S/m2/day in winter and 194 mgrg-S/m2/day in summer in the continental shelf zone, and to be 32 and 107 mgrg-S/m2/day in the Kuroshio region.
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