Scattering of Light by Composite Particles in a Planetary Surface

It has been proposed that composite particles containing internal scatterers may provide the explanation for the fact that most photometric studies of planetary surfaces based on Hapke's model of bidirectional reflectance have found the planetary particles to exhibit moderately backscattering phase functions. However, an implicit assumption made in this explanation is that the scattering by composite particles containing multiple internal inclusions in a planetary surface can still be adequately computed using standard radiative transfer theory assuming the composite particles to be the fundamental individual scatterers even though such particles are necessarily in close proximity to each other. In this paper, this assumption is explored by examining the effects of close packing on the light scattering by spherical particles containing isotropic internal scatterers using a Monte Carlo routine. As expected, classical radiative transfer (assuming a random distribution of scattering particles) coupled with the assumption that the composite particle is the fundamental scatterer provides a good approximation in the high porosity limit. However, even for porosities as high as 90% the effects of close packing are clearly seen with the radiative transfer calculation underestimating the scattering by ∼10% at high incidence, emission, and phase angles. As the porosity is lowered further, the discrepancy becomes more severe and can reach 50% or more. In contrast, assuming the individual scatterer properties in the radiative transfer calculation leads to a substantial overestimate of the scattering even for porosities as low as 27.5%. This suggests that parameters derived using the classical radiative transfer theory will yield results intermediate between those of the composite as a whole and those of the internal scatterers. Thus, one should exercise caution in interpreting the results of models based on classical radiative transfer theory in terms of the physical properties of the surface particles and, where possible, the bidirectional reflectance of densely packed composite particles should be computed using more accurate methods such as the stochastic radiative transfer theory.