Petrochemical variations among mildly peralkaline (comendite) obsidians from the oceans and continents

Eleven new analyses and modes of comendite obsidians are presented, and compared with all available data on similar rocks. Most specimens are aphyric or contain only sparse phenocrysts, most commonly alkali feldspar. The oxides SiO₂, Al₂O₃, Na₂O and K₂O total over ninety percent by weight in all analyses. Iron, as FeO, is the only other constituent rising above one percent by weight. When the analyses are projected into the system Na₂O-K₂O-Al₂O₃-SiO₂, oceanic and continental samples group differently. Oceanic specimens have a compositional spread ranging from trachytic to the quartz-feldspar cotectic zone, consistent with derivation through a trachyte magma stem. Continental comendites show a strong correlation with the experimentally determined quartz-feldspar minima along a path of increasing peralkalinity. These differences presumably reflect the contrasting environments of magma generation, and suggest an origin by partial melting within the continental crust for the continental comendite obsidians.