Salinity and redox alternations in the northwestern Baltic proper during the late Holocene

Selected geochemical parameters and siliceous microfossil assemblages in Baltic Sea sediments are presented which reflect past variations in redox conditions, salinity and primary production. The sediments were deposited during the freshwater Ancylus Lake (9500-8000 ¹⁴C BP) and brackish Litorina Sea (8000-3000 BP) stages of the Baltic. The diatom record shows that surface-water salinity increased further at c . 7000-6500 BP, although smaller amounts of brackish water entered the basin from c . 8000 BP onwards. Attempts to use exchangeable Mg as a palaeosalinity indictor were not applicable. Gross primary productivity increased along with salinity, which has been interpreted as an effect of nutrient enrichment in the photic zone. This led between c . 6500 and 4500 BP to a high accumulation of organic carbon, anoxic or nearly anoxic bottom conditions and formation of laminated deposits. Certain laminae consist of alternating layers of organic and minerogenic material and were probably formed annually, i.e. in the manner of varves. The laminated successions are distinguished by enrichments of V, Cu and especially Mo. The highest Mo content occurs in the core from the greatest water depth, an effect of anoxic conditions during deposition. The Fe/Mn ratio was shown to be ambiguous as an indicator of past redox conditions. Since biogenic silica shows large variablity in contemporaneously deposited sediments, this parameter cannot be used as a proxy for the past production of siliceous algae in the Baltic Sea.