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Methods for reactive oxygen species (ROS) detection in aqueous environments
Authors:Justina M Burns  William J Cooper  John L Ferry  D Whitney King  Brian P DiMento  Kristopher McNeill  Christopher J Miller  William L Miller  Barrie M Peake  Steven A Rusak  Andrew L Rose  T David Waite
Institution:1. Department of Chemistry and Biochemistry, University of South Carolina, Columbia, SC, 29229, USA
2. Department of Civil and Environmental Engineering, University of California, Irvine, Irvine, CA, 92697, USA
3. Department of Chemistry, Colby College, Waterville, ME, 04901, USA
4. Institute of Biogeochemistry and Pollutant Dynamics, ETH Zurich, 8092, Zurich, Switzerland
5. Civil and Environmental Engineering, University of New South Wales, Sydney, NSW, 2052, Australia
6. Department of Marine Sciences, University of Georgia, Athens, GA, 30602, USA
7. Chemistry Department, University of Otago, Dunedin, 9054, New Zealand
8. Southern Cross GeoScience, Southern Cross University, Lismore, 2480, Australia
Abstract:This review summarizes direct and indirect analytical methods for the detection and quantification of the reactive oxygen species (ROS): 1O2, O 2 ·? /HOO·, H2O2, HO·, and CO 3 ·? in aqueous solution. Each section briefly describes the chemical properties of a specific ROS followed by a table (organized alphabetically by detection method, i.e., absorbance, chemiluminescence, etc.) summarizing the nature of the observable (associated analytical signal) for each method, limit of detection, application notes, and reaction of the probe molecule with the particular ROS.
Keywords:
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